Highly reactive uranium(III) polypyrrolide complexes: Intramolecular C-H bond activation, ligand isomerization, and solvent deoxygenation and fragmentation

Organometallics

Volumn 20, Issue 12, 2001, Pages 2552-2559

  Korobkov, Ilia ^a   Gambarotta, Sandro ^a   Yap, Glenn P A ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

DEOXYGENATION; DIMETHOXYETHANE; DINUCLEAR STRUCTURE; FRAGMENTATION; STOICHIOMETRIC RATIO; URANIUM HALIDE; URANIUM POLYPYRROLIDE COMPLEXES;

CHEMICAL BONDS; ISOMERIZATION; OXYGEN; SOLVENTS; STOICHIOMETRY; URANIUM;

ORGANOMETALLICS;

EID: 0035844928     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010166o     Document Type: Article

References (80)

1. Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070.
2. Odom, A. L.; Arnold, P. L.; Cummins, C. C. J. Am. Chem. Soc. 1998, 120, 5836.
3. (a) Julian, S. P.; Clocke, G. F. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867.
4. (b) Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Hongming, Z. J. Chem. Soc., Chem. Commun. 1986, 1148.
5. (a) Moody, D. C.; Zozulin, A. J.; Salazar, K. V. Inorg. Chem. 1982, 21, 3856.
6. (b) Moody, D. C.; Penneman, R. A.; Salazar, K. V. Inorg. Chem. 1979, 18, 208.
7. (c) Santos, I.; Marques, N.; De Matos, A. P. Inorg. Chim. Acta 1985, 110, 149.
8. (d) Cymbaluk, T. H.; Liu, J. Z.; Ernst, R. D. J. Organomet. Chem. 1983, 255, 311.
9. (e) Zozulin, A. J.: Moody, D. C.; Ryan, R. R.; Inorg. Chem. 1982, 21, 3083.
10. (f) Andersen, R. A.; Inorg. Chem. 1979, 18, 1507.
11. Avens, L. R.; Bott, S. G.; Clark, D. L.; Sattelberger, A. P.; Watkin, J. G.; Zwick, B. D. Inorg. Chem. 1994, 33, 2248.
12. Moody, D. C.; Odom, J. D. J. Inorg. Nucl. Chem. 1979, 41, 533.
13. (a) Brennan, J. G.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1986, 25, 1761.
14. (b) Blake, P. C.; Lappert, M. F.; Taylor, R. G.; Atwood, J. L.; Hunter, W. E.; Hongming, Z. J. Chem. Soc., Chem. Commun. 1986, 1394.
15. (c) Brennan, J. G.; Stults, S. D.; Andersen, R. A.; Zalkin, A. Organometallics 1988, 7, 1329.
16. (d) Zalkin, A.; Brennan, J. G.; Andersen, R. A. Acta Crystallogr., Sect. C 1988, 44, 2104.
17. (e) Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Hongming, Z. J. Chem. Soc., Chem. Commun. 1988, 1436.
18. (f) Berthet, J. C.; Lance, M.; Nierlich, M.; Vigner, J.; Ephritikhine, M. J. Organomet. Chem. 1991, 420, C9.
19. (g) Berthet, J. C.; Villiers, C.; Le Marechal, J. F.; Delavaux-Nicot, B.; Lance, M.; Nierlich, M.; Ephritikhine, M. J. Organomet. Chem. 1992, 440, 53.
20. (h) Boisson, C.; Berthet, J. C.; Ephritikhine, M.; Lance, M.; Nierlich, M. J. Organomet. Chem. 1997, 533, 7.
21. (i) Lukens, W. W.; Beshouri, S. M.; Blosch, L. L.; Andersen, R. A. J. Am. Chem. Soc. 1996, 118, 901.
22. (j) Arnaudet, L.; Charpin, P.; Folcher, G.; Lance, M.; Nierlich, M.; Vigner, D. Organometallics 1986, 5, 270.
23. (k) Schake, A. R.; Avens, L. R.; Burns, C. J.; Clark, D. L.; Sattelberger, A. P; Smith, W. H. Organometallics 1993, 12, 1497.
24. (l) Arliguie, T.; Lance, M.; Nierlich, M.; Vigner, J.; Ephritikhine, M. J. Chem. Soc., Chem. Commun. 1994, 847.
25. (m) Manriquez, J. M.; Fagan, P. J.; Marks, T. J.; Vollmer, S. H.; Day, C. S.; Day, V. W. J. Am. Chem. Soc. 1979, 101, 5075.
26. (n) Fagan, P. J.; Manriquez, J. M.; Marks, T. J.; Day, C. S.; Vollmer, S. H.; Day, V. W. Organometallics 1982, 1, 170.
27. (o) Evans, W. J.; Forrestal, K. J.; Ziller, J. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 774.
28. (p) Parry, J. S.; Carmona, E.; Coles, S.; Hursthouse, M. J. Am. Chem. Soc. 1995, 117, 2649.
29. (a) Brennan, J.; Shinomoto, R.; Zalkin, A.; Edelstein, N. Inorg. Chem. 1984, 23, 4143.
30. (b) Cotton, F. A.; Schwotzer, W.; Simpson, C. Q. Angew. Chem., Int. Ed. Engl. 1986, 25, 637.
31. (c) Mannig, D.; Noth, H. Z. Anorg. Allg. Chem. 1986, 543, 66.
32. (d) Van Der Sluys, W. G.; Burns, C. J.; Huffman, J. C.; Sattelberger, A. P. J. Am. Chem. Soc. 1988. 110, 5924.
33. (e) Maria, L.; Campello, M. P.,; Domingos, A.; Santos, I.; Andersen, R. A. J. Chem. Soc., Dalton Trans. 1999, 2015.
34. (f) Wietzke, R.; Mazzanti, M.; Latour, J. M.; Pecaut, J. J. Chem. Soc., Dalton Trans. 1998, 4087.
35. (g) De Rege, F. M.; Smith, W. H.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1998, 37, 3664.
36. (h) Boussie, T. R.; Eisenberg, D. C.; Rigsbee, J.; Streitwieser, A.; Zalkin, A. Organometallics 1991, 10, 1922.
37. (i) Avens, L. R.; Barnhart, D. M.; Burns, C. J.; McKee, S. D.; Smith, W. H. Inorg. Chem. 1994, 33, 4245.
38. (j) Yimin, S.; McDonald, R.; Takats, J.; Day, V. W.; Eberspacher, T. A. Inorg. Chem. 1994, 33, 4433.
39. (k) Roussel, P.; Hitchcock, P. B.; Tinker, N.; Scott, P. J. Chem. Soc., Chem. Commun. 1996, 2053
40. (l) Yimin, S.; Takats, J.; Eberspacher, T.; Day, V. Inorg. Chim. Acta 1995, 229, 315.
41. (m) Hitchcock, P. B.; Lappert, M. F.; Dian-Sheng, L. J. Organomet. Chem. 1995, 488, 241.
42. (n) Wasserman, H. J.; Moody, D. C.; Ryan, R. R. J. Chem. Soc., Chem. Commun. 1984, 532.
43. (o) Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275.
44. (p) Stewart, J. L.; Andersen, R. A. Polyhedron 1998, 17, 953.
45. (q) Nelson, J. E.; Clark, D. L.; Burns, C. J.; Sattelberger, A. P. Inorg. Chem. 1992, 31, 1973.
46. (r) Van Der Sluys, W. G.; Burns, C. J.; Sattelberger, A. P. Organometallics 1989, 8, 855.
47. (a) Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics, 2000, 19, 817.
48. (b) Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 121.
49. (c) Dubé, T.; Frekmann, D.; Conoci, S.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 209.
50. (a) Dubé, T.; Guan, J.; Gambarotta, S.; Yap, G. P. A. Chem. Eur. J. 2001, 7, 374.
51. (b) Dubé, T.; Mani, G.; Conoci, S.; Gambarotta, S. Yap, G. P. A. Organometallics, in press.
52. (a) Jubb, J.; Gambarotta, S. J. Am. Chem. Soc. 1994, 116, 4477.
53. (b) Dubé, T.; Conoci, S.; Gambarotta, S.; Yap, G. P. A.; Vasapollo, G. Angew. Chem., Int. Ed. 1999, 38, 3657.
54. Guan, J.; Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics, in press.
55. Dubé T.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 1999, 38, 1432.
56. Song, J. I.; Berno, P.; Gambarotta, S. Angew. Chem., Int. Ed. Engl. 1995, 34, 2141.
57. (a) Dubé, T.; Conoci, S.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 1182.
58. (b) Dubé, T.; Conoci, S.; Gambarotta, S.; Yap, G. P. A. Organometallics 2000, 19, 115.
59. Brown, W. H.; Hutchinson, B. J.; MacKinnon, M. H.; Can. J. Chem. 1971, 49, 4017.
60. Moeller, T. Inorganic Syntheses; Maple Press: York, PA, 1957; Vol. 5.
61. Mabbs, M. B.; Machin, D. Magnetism and Transition Metal Complexes; Chapman and Hall: London, 1973.
62. Foese, G.; Gorter, C. J.; Smits, L. J. Constantes Selectionnes, Diamagnetisme, Paramagnetisme, Relaxation Paramagnetique; Mason: Paris, 1957.
63. Blessing, R. Acta Crystallogr., Sect. A 1995, 51, 33.
64. Sheldrick, G. M. Bruker AXS: Madison , WI, 1997.
65. (a) Depraetere, S.; Smet, M.; Dehaen, W. Angew. Chem., Int. Ed. 1999, 38, 3359 and references therein.
66. (b) Gale, P. A.; Sessler, J. L. J. Chem. Soc., Chem. Commun. 1998, 1 and references therein.
67. (a) Sessler, J. L. Angew. Chem., Int. Ed. Engl. 1994, 33, 1348.
68. (b) Furuta, H.; Asano, T.; Ogawa, T. J. Am. Chem. Soc. 1994, 116, 767.
69. (c) Chmielewski, P. J.; Latos-Grazynski, L.; Rachlewicz, K.; Glowiak, T. Angew. Chem., Int. Ed. Engl. 1994, 33, 779.
70. (d) Liu, B. Y.; Bruckner, C.; Dolphin, D. J. J. Chem. Soc., Chem. Commun. 1996, 2141.
71. (a) Campazzi, E.; Solari, E.; Scoppellitti, R.; Floriani, C. J. Chem. Soc., Chem. Commun. 1999, 1617.
72. (b) Campazzi, E.; Solari, E.; Scoppellitti, R.; Floriani, C. Inorg. Chem. 1999, 38, 6240.
73. (a) Aspinall, H. C.; Tillotson, M. R. Inorg. Chem. 1996, 35, 2163.
74. (b) Evans, W. J.; Dominguez, R.; Hanusa, T. P. Organometallics 1986, 5, 1291.
75. (c) Jubb, J.; Gambarotta, S. Inorg. Chem. 1994, 33, 2503.
76. (d) Jubb, J.; Gambarotta, S. J. Am. Chem. Soc. 1993, 115, 10410.
77. (e) Dubé, T.; Gambarotta, S.; Yap, G. P. A. Organometallics 1998, 17, 3967.
78. (f) De Angelis, S.; Solari, E.; Floriani, C.; Chiesi-Villa, A. J. Chem. Soc., Dalton Trans. 1994, 2467.
79. (g) Ruppa, K. B.; Gambarotta, S.; Bensimon, C.; Yap, G. P. A. Inorg. Chim. Acta 1998, 280, 143.
80. Jubb, J.; Gambarotta, S.; Duchateau, R.; Teuben, J. H. J. Chem. Soc., Chem. Commun. 1994, 2641.