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2
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33947085597
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Bursten, B.E.1
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4
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0030755578
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Evans, W. J.; Forrestal, K. J.; Ziller, J. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 774.
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5
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0345104549
-
-
The term "early actinide metal" is defined herein as Th, Pa, or U
-
The term "early actinide metal" is defined herein as Th, Pa, or U.
-
-
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6
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0042693472
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Billiau, F.; Folcher, G.; Marquet-Ellis, H.; Rigny, P.; Saito, E. J. Am. Chem. Soc. 1981, 103, 5603.
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Billiau, F.1
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0004686503
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Eisenberg, D.C.1
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Kot, W.K.3
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8
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0000256494
-
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and references therein
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Boussie, T. R.; Eisenberg, D. C.; Rigsbee, J.; Streitwieser, A., Jr.; Zalkin, A. Organometallics 1991, 10, 1922 and references therein.
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Boussie, T.R.1
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10
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37049068597
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Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Zhang, H. M. J. Chem. Soc., Chem. Commun. 1986, 1148.
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Blake, P.C.1
Lappert, M.F.2
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Zhang, H.M.4
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11
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0001098855
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Edwards, P. G.; Andersen, R. A.; Zalkin, A. Organometallics 1984, 3, 293.
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Edwards, P.G.1
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Dolg, M.; Fulde, P.; Stoll, H.; Preuss, H.; Chang, A.; Pitzer, R. M. Chem. Phys 1995, 195, 71.
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Dolg, M.1
Fulde, P.2
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0001547033
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Boeerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys 1988, 122, 357.
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Boeerrigter, P.M.1
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Snijders, J.G.3
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14
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0000643275
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Brennan, J. G.; Green, J. C., Redfern, C. M. J. Am. Chem. Soc. 1989, 111, 2373.
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Brennan, J.G.1
Green, J.C.2
Redfern, C.M.3
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15
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-
0011044582
-
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2u separation. See, for example: Rosch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195.
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(1978)
J. Organomet. Chem.
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, pp. 195
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Rosch, N.1
Streitwieser A., Jr.2
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17
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0347673576
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Arliguie, T.; Lance, M.; Nierlich, M.; Vigner, J.; Ephritikhine, M. J. Chem. Soc., Chem. Commun 1995, 183.
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Arliguie, T.1
Lance, M.2
Nierlich, M.3
Vigner, J.4
Ephritikhine, M.5
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18
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0030879550
-
-
Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1997, 119, 9021. Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456.
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Li, J.1
Bursten, B.E.2
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19
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0032508867
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Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1997, 119, 9021. Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456.
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Li, J.1
Bursten, B.E.2
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20
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0031802414
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Gourier, D.; Caurant, D.; Arliguie, T.; Ephritikhine, M. J. Am. Chem. Soc. 1998, 120, 6084.
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Gourier, D.1
Caurant, D.2
Arliguie, T.3
Ephritikhine, M.4
-
22
-
-
4544244598
-
-
and references therein
-
The π-acceptor properties of silyl substituents on arene rings are well documented, for example see: Jia, L.; Yang, X.; Stern, C. L.; Marks, T. J. Organometallics 1997, 16, 842 and references therein.
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(1997)
Organometallics
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Jia, L.1
Yang, X.2
Stern, C.L.3
Marks, T.J.4
-
23
-
-
0000443715
-
-
Kot, W. K.; Shalimoff, G. V.; Edelstein, N. M.; Lappert, M. F. J. Am. Chem. Soc. 1988, 110, 986. Bursten, B. E.; Rhodes, L. F.; Stritmatter, R. J. J. Am. Chem. Soc. 1989, 111, 2756.
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Kot, W.K.1
Shalimoff, G.V.2
Edelstein, N.M.3
Lappert, M.F.4
-
24
-
-
0000632462
-
-
Kot, W. K.; Shalimoff, G. V.; Edelstein, N. M.; Lappert, M. F. J. Am. Chem. Soc. 1988, 110, 986. Bursten, B. E.; Rhodes, L. F.; Stritmatter, R. J. J. Am. Chem. Soc. 1989, 111, 2756.
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-
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Bursten, B.E.1
Rhodes, L.F.2
Stritmatter, R.J.3
-
25
-
-
0344242278
-
-
This ligand was prepared by a modification to the route for the 1,4-bis(trimethylsilyl)cycloocta-1,3,5-triene. See Experimental Section
-
This ligand was prepared by a modification to the route for the 1,4-bis(trimethylsilyl)cycloocta-1,3,5-triene. See Experimental Section.
-
-
-
-
26
-
-
0344673701
-
-
See Experimental Section
-
See Experimental Section.
-
-
-
-
27
-
-
0345535965
-
-
Argon impurities rated to <0.5 ppm
-
Argon impurities rated to <0.5 ppm.
-
-
-
-
28
-
-
0344673700
-
-
The nature of the coordinated ether is important. When the reaction is performed in THF or 18-crown-6 is added to the product from DME, only green oils are isolated
-
The nature of the coordinated ether is important. When the reaction is performed in THF or 18-crown-6 is added to the product from DME, only green oils are isolated.
-
-
-
-
29
-
-
0345505532
-
-
note
-
A classical explanation for this, treating the electron as a standing wave, is that f-orbitals have more angular nodes than d orbitals and hence a shorter wavelength. By the deBroglie relationship, ρ = 1/λ, hence f orbitals have a greater orbital angular momentum than d orbitals, increasing the magnitude of the spin-orbit coupling constant. This leads to faster electronic relaxation by spin-orbit coupling mechanisms.
-
-
-
-
30
-
-
0039168373
-
-
Gourier, D.; Samuel, E.; Teuben, J. H. Inorg. Chem. 1989, 28, 4663.
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(1989)
Inorg. Chem.
, vol.28
, pp. 4663
-
-
Gourier, D.1
Samuel, E.2
Teuben, J.H.3
-
31
-
-
0345535964
-
-
2Si groups is linear
-
2Si groups is linear.
-
-
-
-
32
-
-
0344673697
-
-
Hermann, J. A.; Suttle, J. F.; Hoekstra, H. R. Inorg. Synth. 1974, 15, 243.
-
(1974)
Inorg. Synth.
, vol.15
, pp. 243
-
-
Hermann, J.A.1
Suttle, J.F.2
Hoekstra, H.R.3
-
33
-
-
0029714831
-
-
3- Unfortunately, the crystal structure of the latter has not been published. See: Lukens, W. W.; Blosch, L. L.; Andersen, R. A. J. Am. Chem. Soc. 1996, 118, 901. Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Zhang, H. M. J. Chem. Soc., Chem. Commun. 1986, 1148.
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J. Am. Chem. Soc.
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, pp. 901
-
-
Lukens, W.W.1
Blosch, L.L.2
Andersen, R.A.3
-
34
-
-
37049068597
-
-
3- Unfortunately, the crystal structure of the latter has not been published. See: Lukens, W. W.; Blosch, L. L.; Andersen, R. A. J. Am. Chem. Soc. 1996, 118, 901. Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Zhang, H. M. J. Chem. Soc., Chem. Commun. 1986, 1148.
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(1986)
J. Chem. Soc., Chem. Commun.
, pp. 1148
-
-
Blake, P.C.1
Lappert, M.F.2
Atwood, J.L.3
Zhang, H.M.4
-
35
-
-
0002345908
-
-
Burton, N.; Cloke, F. G. N.; Joseph, S. C. P.; Karamallakis, H.; Sameh, A. A. J. Organomet. Chem 1993, 462, 39.
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(1993)
J. Organomet. Chem
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Burton, N.1
Cloke, F.G.N.2
Joseph, S.C.P.3
Karamallakis, H.4
Sameh, A.A.5
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