Electrochemical Properties of Bis(dicarbollide)uranium Dibromide

Inorganic Chemistry

Volumn 37, Issue 15, 1998, Pages 3664-3666

  De Rege, Francis M ^a   Smith, Wayne H ^a   Scott, Brian L ^a   Nielsen, Jon B ^a   Abney, Kent D ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001457769     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9712838     Document Type: Article

References (26)

1. For a compilation of early work on the dicarbollide ligand see: Hawthorne, M. F.; Young, D. C.; Andrews, T. D.; Howe, D. V.; Pilling, R. L.; Pitts, A. D.; Reintjes, M.; Warren, L. F.; Wegner, P. A. J. Am. Chem. Soc. 1968, 90, 879.
2. Hanusa, T. P. Polyhedron 1982, 1, 663.
3. For charge-compensated dicarbollides see: Kang, H. C.; Lee, S. S.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1991, 30, 2024.
4. For a review of carborane metal complexes see: Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081.
5. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
6. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
7. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
8. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
9. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
10. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
11. For some specific examples of unusual properties of the dicarbollide ligand see: (a) Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482. (b) Xie, Z.; Liu, Z.; Chiu, K.; Xue, F.; Mak, T. C. W. Organometallics 1997, 16, 2460. (c) Yoshida, M.; Crowther, D. J.; Jordan, R. F. Organometallics 1997, 16, 1349. (d) Anderson, S.; Mullica, D. F.; Sappenfield, E. L.; Stone, F. G. A. Organometallics 1996, 15, 1676. (e) Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1993, 12, 2126. (f) Kang, H. C.; Do, Y.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1988, 27, 1716. (g) Warren, L. F.; Hawthorne, M. F. J. Am. Chem. Soc. 1970, 92, 1157.
12. Three reports on uranium dicarbollide complexes precede our work: (a) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Chem. Soc., Chem. Commun. 1976, 8, 279. (b) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Am. Chem. Soc. 1977, 99, 1769. (c) Shaw, K. F.; Reid, B. D.; Welch, A. J. J. Organomet. Chem. 1994, 482, 207.
13. Three reports on uranium dicarbollide complexes precede our work: (a) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Chem. Soc., Chem. Commun. 1976, 8, 279. (b) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Am. Chem. Soc. 1977, 99, 1769. (c) Shaw, K. F.; Reid, B. D.; Welch, A. J. J. Organomet. Chem. 1994, 482, 207.
14. Three reports on uranium dicarbollide complexes precede our work: (a) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Chem. Soc., Chem. Commun. 1976, 8, 279. (b) Fronczek, F. R.; Halstead, G. W.; Raymond, K. N. J. Am. Chem. Soc. 1977, 99, 1769. (c) Shaw, K. F.; Reid, B. D.; Welch, A. J. J. Organomet. Chem. 1994, 482, 207.
15. (a) Rabinovich, D.; Haswell, C. M.; Scott, B. L.; Miller, R. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1996, 35, 1425.
16. (b) Rabinovich, D.; Chamberlin, R. M.; Scott, B. L.; Nielsen, J. B.; Abney, K. D. Inorg. Chem. 1997, 36, 4216.
17. XSCANS and SHELXTL PC are products of Siemens Analytical X-ray Instruments, Inc., 6300 Enterprise Lane, Madison, WI 53719. SHELX-93 is a program for crystal structure refinement written by G. M. Sheldrick (1993), Univ. of Göttingen, Germany.
18. 2].
19. Alkyl halides react with U(III) organometallic complexes. See: Finke, R. G.; Schiraldi, D. A.; Hirose, Y. J. Am. Chem. Soc. 1981, 103, 1876.
20. (a) Spirlet, M. R.; Rebiznat, J.; Apostolidis, C.; Kanellakopulos, B. Acta Crystallogr. C. 1992, C48, 2135.
21. (b) Pagan, P. J.; Manriquez, J. M.; Maatta, E. A.; Seyam, A. M.; Marks, T. J. J. Am. Chem. Soc. 1981, 103, 6650.
22. (c) Finke, R. G.; Gaughan, G.; Voegeli, R. J. Organomet. Chem. 1982, 229, 179.
23. 2, in agreement with ref 10c.
24. The cone angles were calculated from an average of the 5 angles made from the centroid-U-H, where the H position was calculated and given a van der Waals radius of 1 Å. The cone angles are significantly smaller than those calculated for transition metals due to the much longer actinide-centroid bond lengths. See ref 2.
25. 2 ligand is sometimes smaller in the U(IV) complex than in the U(III) complexes: Blake, P. C.; Lappert, M. F.; Atwood, J. L.; Zhang, H. J. Chem. Soc., Chem. Commun. 1988, 1436.
26. Fagan, P. J.; Manriquez, J. M.; Marks, T. J.; Day, C. S.; Vollmer, S. H.; Day, V. W. Organometallics 1982, 1, 170.