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Mashima, K.; Yasuda, H.; Asami, K.; Nakamura, A. Chem. Lett. 1983, 219.
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37049079072
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0000705196
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(f) Larson, E. J.; van Dort, P. C.; Lakanen, J. R.; O'Neill, D. W.; Pederson, L. M.; McCandless, J. J. Silver, M. E.; Russo, S. O.; Huffman, J. D. Organometallics 1988, 7, 1183.
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0011398456
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Vance, P. J.; Prins, T. J.; Hauger, B. E.; Silver, M. E.; Wemple, M. E.; Pederson, L. M.; Kort, D. A.; Kannisto, M. R.; Geerligs, S. J.; Kelly, R. S.; McCandless, J. J.; Huffman, J. D.; Peters, D. G. Organometallics 1991, 10, 917.
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0011449270
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The full synthetic scope and applications of the bis(2-N,N-dimethylaminoindenyl)titanium(III) template will be detailed in a separate account.
-
-
-
-
23
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0000230679
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For a comment on this problem, common to certain classes of early transition metal complexes, see the supporting material in: Carney, M. J.; Walsh, P. J.; Bergman, R. G. J. Am. Chem. Soc. 1990, 112, 6426.
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Carney, M.J.1
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26
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0011445462
-
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note
-
2 could not be determined precisely; the yield of the reaction is estimated assuming conversion to complex 5 alone, the major material isolated in this procedure. The actual yield of the reaction is lower.
-
-
-
-
27
-
-
0011464522
-
-
note
-
Preparation of cinnamyllithium: In a Schlenk flask, a THF solution (25 mL) of freshly distilled allyl benzene (5.0 mL. 37.7 mmol) was cooled to - 78 °C. η-Butyllithium (18.1 mL, 2.5 M in hexanes) was transferred via cannula into the flask, and the reaction mixture was left to stir for 1 h at - 78 °C. The reaction mixture was allowed to warm to room temperature and stirred for an additional hour. Removal of the solvent in vacuo yielded a yellow solid residue, which was washed repeatedly with hexane (4 × 25 mL) to give a brilliant yellow powder (3.98 g, 85%). This material was used without further characterization.
-
-
-
-
29
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-
0011445963
-
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note
-
Programs for diffractometer operation, data collection, data reduction and absorption correction were those supplied by Bruker.
-
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32
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37049094154
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(a) The synthesis of 2-(N,N-dimethylamino)-1-(trimethylsilyl)-indene was based on a method reported by Clark: Cardoso, A. M; Clark, R. J.; Moorhouse, S. J. J. Chem. Soc., Dalton Trans. 1980, 1156.
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Coordination of silylated cyclopentadienyl ligands to titanium: Winter, C. H.; Zhou, X.-X.; Dobbs, D. A.; Heeg, M. J. Organometallics 1991, 10, 210.
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0001826563
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0000584037
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Titanocene(III) chloride complexes typically adopt monomeric structures in the case of sterically significant ancillary ligands and chloride-bridged dimers for complexes of smaller ligands. Monomeric complexes: Pattiasina, J. W.; Heeres, H. J.; van Bolhuis, F.; Meetsma, A.; Teuben, J. H. Organometallics 1987, 6, 1004.
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Percent pyramidalization = [360 - Σcarbon-nitrogen bonds]/[360 - 328.5] × 100.
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2 to regenerate the allyltitanium(III) complex, as proposed for related propargyltitanium-(III) alkylations.
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3 in cymantrenes, ca. 1.36 Å).
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