Synthesis of the first tris(pentamethylcyclopentadienyl) hydride complex, (C5Me5)3ThH

Organometallics

Volumn 20, Issue 25, 2001, Pages 5489-5491

  Evans, Williams J ^a   Nyce, Gregory W ^a   Ziller, Joseph W ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; THORIUM HYDRIDE; TRISPENTAMETHYLCYLOPENTADIENYL;

COMPLEXATION; HYDRIDES; MOLECULAR STRUCTURE; REDOX REACTIONS; SYNTHESIS (CHEMICAL); THORIUM;

ORGANOMETALLICS;

EID: 0035843059     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010596e     Document Type: Article

References (22)

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15. 2(DMPE) indicate that a bridged structure is also possible.
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17. 3, Z = 2. The molecule was located on a site of 6 symmetry. The hydride atom was disordered and was included with a partial site-occupancy-factor (1/6) to account for an equal distribution over two sites. At convergence, wR2 = 0.0321 and GOF = 1.174 for 54 parameters refined against 801 unique reflections (0.85 Å resolution). As a comparison for refinement against F, R1 = 0.0140 for those data, 774 data with I > 2.0σ(I).
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22. Evans, W. J.; Nyce, G. W. Unpublished results.