Organic syntheses via transition metal complexes. Part 103: Pyrylium carbonylmetalates and related compounds derived from (1-alkynyl)carbene complexes (M=Cr, W)

Tetrahedron

Volumn 56, Issue 28, 2000, Pages 4935-4949

  Aumann, Rudolf ^a   Kößmeier, Michael ^a   Roths, Klaus ^a   Fröhlich, Roland ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

1 alkynyl carbene complexes; Chromium complexes; Cyclopentadienes; Enaminones; Mesoionic pyrylium compounds; Tungsten complexes

Indexed keywords

CARBONYL DERIVATIVE; METAL COMPLEX; PYRILIUM CARBONYLATE DERIVATIVE; UNCLASSIFIED DRUG;

COMPLEX FORMATION; CONFERENCE PAPER; CONFORMATIONAL TRANSITION; GERMANY; MOLECULAR INTERACTION; PRIORITY JOURNAL; SYNTHESIS;

EID: 18844476363     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(00)00208-8     Document Type: Conference Paper

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38. For a different access to pyrilium carbonylmetalates see: (a) Rees, Ch. W., von Angerer, E. J. Chem. Soc., Chem. Commun. 1972, 420. (b) Gilchrist, T. L.; Livingstone, R.; Rees, Ch. W., von Angerer, E. J. Chem. Soc., Perkin I, 1973, 2535. (c) Berke, H.; Härter, P.; Huttner, G.; Zsolnai, L. Z. Naturforsch. 1981, 36b, 929. (d) Aumann, R.; Heinen, H. Chem. Ber. 1987, 120, 537-540. (e) Adams, R. D.; Chen, L. J. Am. Chem. Soc. 1994, 116, 4467. (f) Adams, R. D.; Chen, L.; Huang, M. Organometallics 1994, 13, 2696. (g) Garlaschelli, L.; Malatesta, M. C.; Panzeri, S.; Albinati, A.; Ganazzoli, F. Organometallics 1987, 6, 63.
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53. Azzaro M., Geribaldi S., Videau B. Synthesis. 1981;880.
54. All data sets were collected with an Enraf Nonius CAD4 diffractometer, equipped with a sealed tube or rotating anode generator. Programs used: data collection EXPRESS, data reduction MolEN, structure solution SHELXS-86, structure refinement SHELXL-93 or SHELXL-97, graphics (with unsystematical numbering schemes) SCHAKAL-92. Crystallographic data (excluding structure factors) for the new structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-137 150-137 153. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +44-1223-336-033, e-mail: deposit@ccdc.cam.ac.uk].