Carbenerhodium complexes of the half-sandwich-type: Synthesis, substitution, and addition reactions

Chemistry - A European Journal

Volumn 6, Issue 24, 2000, Pages 4461-4470

  Werner, Helmut ^a   Schwab, Peter ^a   Bleuel, Elke ^a   Mahr, Norbert ^a   Windmüller, Bettina ^a   Wolf, Justin ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

C C coupling; Carbene complexes; Carbonyl complexes; Cyclopentadienyl complexes; Rhodium

Indexed keywords

CARBENOID; COPPER CHLORIDE; CYCLOPENTADIENE DERIVATIVE; RHODIUM COMPLEX;

ARTICLE; COMPLEX FORMATION; MOLECULAR DYNAMICS; REACTION ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0034671277     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20001215)6:24<4461::AID-CHEM4461>3.0.CO;2-F     Document Type: Article

References (62)

1. a) Isolation: H. Werner, J. Wolf, A. Höhn, J. Organomet. Chem. 1985, 287, 395-407;
2. b) molecular structure: P. Binger, J. Haas, G. Glaser, R. Goddard, C. Krüger, Chem. Ber. 1994, 127, 1927-1929.
3. a) F. J. Garcia Alonso, A. Höhn, J. Wolf, H. Otto, H. Werner, Angew. Chem. 1985, 97, 401-402; Angew. Chem. Int. Ed. Engl. 1985, 24, 406-407;
4. a) F. J. Garcia Alonso, A. Höhn, J. Wolf, H. Otto, H. Werner, Angew. Chem. 1985, 97, 401-402; Angew. Chem. Int. Ed. Engl. 1985, 24, 406-407;
5. b) H. Werner, F. J. Garcia Alonso, H. Otto, J. Wolf, Z. Naturforsch. B 1988, 43, 722-726;
6. c) H. Werner, U. Brekau, Z. Naturforsch. B 1989, 44, 1438-1446;
7. d) H. Werner, Nachr. Chem. Tech. Lab. 1992, 40, 435-444;
8. e) H. Werner, J. Organomet. Chem. 1994, 475, 45-55.
9. H. Werner, T. Rappert, Chem. Ber. 1993, 126, 669-678;
10. b) H. Werner, T. Rappert, R. Wiedemann, J. Wolf, N. Mahr, Organometallics 1994, 13, 2721-2727;
11. c) H. Werner, Chem. Commun. 1997, 903-910;
12. d) M. Laubender, H. Werner, Chem. Eur. J. 1999, 5, 2937-2946.
13. I. Kovacik, M. Laubender, H. Werner, Organometallics 1997, 16, 5607-5609.
14. a) P. Schwab, N. Mahr, J. Wolf, H. Werner, Angew. Chem. 1993, 105, 1498-1500; Angew. Chem. Int. Ed. Engl. 1993, 32, 1480-1482;
15. a) P. Schwab, N. Mahr, J. Wolf, H. Werner, Angew. Chem. 1993, 105, 1498-1500; Angew. Chem. Int. Ed. Engl. 1993, 32, 1480-1482;
16. b) H. Werner, J. Organomet. Chem. 1995, 500, 331-336;
17. c) H. Werner, P. Schwab, E. Bleuel, N. Mahr, P. Steinert, J. Wolf, Chem. Eur. J. 1997, 3, 1375-1384.
18. a) J. Wolf, H. Werner, O. Serhadli, M. L. Ziegler, Angew. Chem. 1983, 95, 428-429; Angew. Chem. Int. Ed. Engl. 1983, 22, 414-415;
19. a) J. Wolf, H. Werner, O. Serhadli, M. L. Ziegler, Angew. Chem. 1983, 95, 428-429; Angew. Chem. Int. Ed. Engl. 1983, 22, 414-415;
20. b) H. Werner, J. Wolf, F. J. Garcia Alonso, M. L. Ziegler, O. Serhadli, J. Organomet. Chem. 1987, 336, 397-411.
21. R. Wiedemann, P. Steinert, O. Gevert, H. Werner, J. Am. Chem. Soc. 1996, 118, 2495-2496.
22. a) D. W. Macomber, R. D. Rogers, J. Organomet. Chem. 1986, 308, 353-360;
23. b) G. Erker, R. Lecht, Y.-H. Tsay, C. Krüger, Chem. Ber. 1987, 120, 1763-1765;
24. c) G. Erker, M. Mena, U. Hoffmann, B. Menjon, J. L. Petersen, Organometallics 1991, 10, 291-298.
25. P. Hofmann in Transition Metal Carbene Complexes (Eds.: K. H. Dötz, H. Fischer, P. Hofmann, F. R. Kreissl, U. Schubert, K. Weiss), Verlag Chemie, Weinheim, 1983, pp. 113-149.
26. H. Werner, U. Brekau, O. Nürnberg, B. Zeier, J. Organomet. Chem. 1992, 440, 389-399.
27. A. Fries, Dissertation, Universität Würzburg, 1993.
28. H. G. Schuster-Woldan, F. Basolo, J. Am. Chem. Soc. 1966, 88, 1657-1663.
29. J. Wolf, L. Brandt, A. Fries, H. Werner, Angew. Chem. 1990, 102, 584-586; Angew. Chem. Int. Ed. Engl. 1990, 29, 510-512.
30. J. Wolf, L. Brandt, A. Fries, H. Werner, Angew. Chem. 1990, 102, 584-586; Angew. Chem. Int. Ed. Engl. 1990, 29, 510-512.
31. S. Otsuka, A. Nakamura, Inorg. Chem. 1968, 7, 2542-2544.
32. a) M. E. Gross, W. C. Trogler, J. Organomet. Chem. 1981, 209, 407-414;
33. b) M. E. Gross, W. C. Trogler, J. A. Ibers, Organometallics 1982, 1, 732-739.
34. G. Hörlin, Dissertation, Universität Würzburg, 1993.
35. a) F. W. B. Einstein, D. Sutton, Inorg. Chem. 1972, 11, 2827-2831;
36. b) P. Overbosch, G. van Koten, D. M. Grove, A. L. Spek, A. J. M. Duisenberg, Inorg. Chem. 1982, 21, 3253-3260;
37. c) P. Overbosch, G. van Koten, A. L. Spek, G. Roclofsen, A. J. M. Duisenberg, Inorg. Chem. 1982, 21, 3908-3913;
38. d) J. Geisenberger, U. Nagel, A. Sebald, W. Beck, Chem. Ber. 1983, 16, 911-916;
39. e) D. S. Moore, S.D. Robinson, Adv. Inorg. Chem. Radiochem. 1986, 30, 1-68.
40. a) J. Wolf, R. Zolk, U. Schubert, H. Werner, J. Organomet. Chem. 1988, 340, 161-178;
41. b) H. Werner, J. Wolf, G. Müller, C. Krüger, J. Organomet. Chem. 1988, 342, 381 398;
42. c) A. Holm, H. Werner, Chem. Ber. 1988, 121, 881-886;
43. d) H. Werner, F. J. Garcia Alonso, H. Otto, K. Peters, H. G. von Schnering, Chem. Ber. 1988, 121, 1565-1573.
44. G. A. Olah, T. Nakajima, D. K. Surya Prakash. Angew. Chem. 1980, 92, 837-838; Angew. Chem. Int. Ed. Engl. 1980, 19, 811-812.
45. G. A. Olah, T. Nakajima, D. K. Surya Prakash. Angew. Chem. 1980, 92, 837-838; Angew. Chem. Int. Ed. Engl. 1980, 19, 811-812.
46. H. Fischer, S. Zcuner, Z. Naturforsch. B 1983, 38, 1365.
47. H. Werner, W. Paul, W. Knaup, J. Wolf, G. Müller, J. Riede, J. Organomet. Chem. 1988, 358, 95-121.
48. H. Fischer, S. Zeuner, U. Gerbing, J, Riede, C. G. Kreiter, J. Organomet. Chem. 1989, 377, 105-122.
49. E. Goldish, K. Hedberg, R. E. Marsh, V. Schomaker, J. Am. Chem. Soc. 1955, 77, 2948-2949.
50. a) M. Hutchinson, H. W. Kroto, J. Mol. Spectrosc. 1978, 70, 347-356;
51. b) R. D. Brown, P. D. Godfrey, D. McNaughton, Chem. Phys. Lett. 1985, 118, 29-30.
52. U. Herber, E. Bleuel, O. Gevert, M. Laubender, H. Werner, Organometallics 1998, 17, 10-12.
53. H. Werner, P. Schwab, N. Mahr, J. Wolf, Chem. Ber. 1992, 725, 2641-2650.
54. a) J. Firl, W. Runge, Z. Naturforsch. B 1974, 29, 393-398;
55. b) C. Ainsworth, F. Chen, Y.-N. Kuo, J. Organomet. Chem. 1972, 46, 59-71.
56. J. A. Green, L. A. Singer, Tetrahedron Lett. 1969, 5093-5095.
57. a) D. Hernandez, G. L. Larson, J. Org. Chem. 1984, 49, 4285-4287;
58. b) S. S. Hixson, L. A. Franke, J. Org. Chem. 1988, 53, 2706-2711.
59. H. Werner, R. Feser, J. Organomet. Chem. 1982, 252, 351-370.
60. G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467-473.
61. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, 1997.
62. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-146602 and CCDC-146603. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).