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Volumn 17, Issue 5, 2001, Pages 1731-1736

Surface-initiated thermal radical polymerization on gold

Author keywords

[No Author keywords available]

Indexed keywords

THERMAL RADICAL POLYMERIZATIONS;

EID: 0035815042     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la001325w     Document Type: Article
Times cited : (79)

References (40)
  • 26
    • 0021788046 scopus 로고
    • We note that absorbances in reflectance FTIR spectra depend on the orientation of the transition dipole with respect to the surface normal (see: Allara, D.L.; Nuzzo, R.G. Langmuir 1985, 1, 52.). Because partial desorption of the SAM may result in orientation changes of the remaining carbonyl groups attached to the surface, estimates of surface coverage from IR spectra are only approximate.
    • (1985) Langmuir , vol.1 , pp. 52
    • Allara, D.L.1    Nuzzo, R.G.2
  • 27
    • 0011272482 scopus 로고    scopus 로고
    • note
    • Thickness data for initiator layers suggest that coverage by initiator A on Au may be less than that of initiator C on aluminum, whereas initiator B on Au has a similar coverage to that of initiator C on aluminum. All of the initiator layers on gold should still be dense enough to initiate polymerization.
  • 29
    • 0011318532 scopus 로고    scopus 로고
    • note
    • It must be pointed out that the amount of AIBN in solution is 104 times larger than the amount of azo-initiator in the monolayer. Therefore, the effect of radicals from initiator monolayers could be less than the effect of radicals from AIBN. However, radicals formed from immobilized initiators will be concentrated at the surface.
  • 30
    • 0011331208 scopus 로고    scopus 로고
    • note
    • Direct detection of the formation of cyclic or linear sulfides would not be possible because of the very small number of molecules in a SAM.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.