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12944311489
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note
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To achieve near-quantitative initiator immobilization, we used a concentrated 2-bromopropionyl bromide solution (0.1 M). Since a thiol SAM could be unstable in the acid bromide, substrate-1 was dipped in acid bromide solution for only 2 min. This reaction was done in a drybox because the acid bromides are moisture sensitive, especially in the presence of an organic base.
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31
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12944290265
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note
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2, all the polymerizations were carried out in a drybox filled with helium.
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12944255049
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note
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2 treatment conditions.
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33
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0032481675
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Templeton, A. C.; Hosteller, M. J.; Kraft, C. T.; Murray, R. W. J. Am. Chem. Soc. 1998, 120, 1906-1911.
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Templeton, A.C.1
Hosteller, M.J.2
Kraft, C.T.3
Murray, R.W.4
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12944255048
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note
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A is Avogadro's number.
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36
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12944277652
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note
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Substrate-4 was prepared by the immersion of substrate-1 in a solution of 0.1 M propionyl chloride and pyridine for 2 min.
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