Ring-opening metathesis polymerization from surfaces

Journal of the American Chemical Society

Volumn 121, Issue 16, 1999, Pages 4088-4089

  Weck, Marcus ^a   Jackiw, Jennifer J ^b   Rossi, Robert R ^a   Weiss, Paul S ^b   Grubbs, Robert H ^a  

^a California Institute of Technology   (United States)

^b PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; MOLECULAR DYNAMICS; POLYMERIZATION; REACTION ANALYSIS; SCANNING ELECTRON MICROSCOPY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0033611952     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja983297y     Document Type: Article

References (25)

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4. For some examples, see: (a) Albagli, D.; Bazan, G. C.; Schrock, R. R.; Wrighton, M. S. J. Am. Chem. Soc. 1993, 115, 7328. (b) Heise, A.; Menzel, H.; Yim, H.; Foster, M. D.; Wieringa, R. H.; Schouten, A. J.; Erb, V.; Stamm, M. Langmuir 1997, 13, 723. (c) Huang, Z.; Wang, P.-C.; MacDiarmid, A. G.; Xia, Y.; Whitesides, G. M. Langmuir 1997, 13, 6480. (d) Lenk, T. J.; Hallmark, V. M.; Rabolt, J. F.; Häussling, L.; Ringsdorf, H. Macromolecules 1993, 26, 1230. (e) Sun, F.; Castner, D. G.; Grainger, D. W. Langmuir 1993, 9, 3200. (f) Stouffer, J. M.; McCathy, T. J. Macromolecules 1988, 21, 1204. (g) Smela, E.; Zuccarello, G.; Kariis, H.; Liedberg, B. Langmuir 1998, 14, 2970.
5. For some examples, see: (a) Albagli, D.; Bazan, G. C.; Schrock, R. R.; Wrighton, M. S. J. Am. Chem. Soc. 1993, 115, 7328. (b) Heise, A.; Menzel, H.; Yim, H.; Foster, M. D.; Wieringa, R. H.; Schouten, A. J.; Erb, V.; Stamm, M. Langmuir 1997, 13, 723. (c) Huang, Z.; Wang, P.-C.; MacDiarmid, A. G.; Xia, Y.; Whitesides, G. M. Langmuir 1997, 13, 6480. (d) Lenk, T. J.; Hallmark, V. M.; Rabolt, J. F.; Häussling, L.; Ringsdorf, H. Macromolecules 1993, 26, 1230. (e) Sun, F.; Castner, D. G.; Grainger, D. W. Langmuir 1993, 9, 3200. (f) Stouffer, J. M.; McCathy, T. J. Macromolecules 1988, 21, 1204. (g) Smela, E.; Zuccarello, G.; Kariis, H.; Liedberg, B. Langmuir 1998, 14, 2970.
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7. For some examples, see: (a) Albagli, D.; Bazan, G. C.; Schrock, R. R.; Wrighton, M. S. J. Am. Chem. Soc. 1993, 115, 7328. (b) Heise, A.; Menzel, H.; Yim, H.; Foster, M. D.; Wieringa, R. H.; Schouten, A. J.; Erb, V.; Stamm, M. Langmuir 1997, 13, 723. (c) Huang, Z.; Wang, P.-C.; MacDiarmid, A. G.; Xia, Y.; Whitesides, G. M. Langmuir 1997, 13, 6480. (d) Lenk, T. J.; Hallmark, V. M.; Rabolt, J. F.; Häussling, L.; Ringsdorf, H. Macromolecules 1993, 26, 1230. (e) Sun, F.; Castner, D. G.; Grainger, D. W. Langmuir 1993, 9, 3200. (f) Stouffer, J. M.; McCathy, T. J. Macromolecules 1988, 21, 1204. (g) Smela, E.; Zuccarello, G.; Kariis, H.; Liedberg, B. Langmuir 1998, 14, 2970.
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24. Immersion of the wafer into the monomer solution for longer periods resulted in continued polymer growth. For the STM characterization the wafers were immersed for only a short period of time (2-20 min) to yield only oligomerization (due to the greatly reduced electron tunneling properties of large polymer brushes), while for the AFM and SEM characterization the wafers were immersed in the monomer solution for longer periods to obtain longer polymer brushes on the surface.
25. Bumm; L. A.; Arnold, J. J.; Charles, L. F.; Dunbar, T. D.; Allara, D. L.; Weiss, P. S. submitted to J. Am. Chem. Soc.