Effect of reaction conditions and alkyl chain lengths on the properties of hydroxyalkyl starch ethers

Starch/Staerke

Volumn 53, Issue 11, 2001, Pages 547-554

  Funke, Ulrike ^a   Lindhauer, Meinolf G ^a  

^a Inst Cereal Potato Starch Technol   (Germany)

Author keywords

Hydrophobic properties; Starch ethers; Thermoplastic properties

Indexed keywords

EID: 0035505226     PISSN: 00389056     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-379X(200111)53:11<547::AID-STAR547>3.0.CO;2-C     Document Type: Article

References (30)

1. R. F. T. Stepto, I. Tomka: Injection Moulding of Natural Hydrophilic Polymers in the Presence of Water. Chimia 1987, 3, 76-81.
2. H. Röper, H. Koch: The Role of Starch in Biodegradable Thermoplastic Materials. Starch/Stärke 1990, 42, 123-130.
3. W. Wiedmann, E. Strobel: Compounding of Thermoplastic Starch with Twin-Screw Extruders. Starch/Stärke 1991, 43, 138-145.
4. R. L. Shogren, G. F. Fanta, W. M. Doane: Development of Starch Based Plastics - A Reexamination of Selected Polymers Systems in Historical Perspective. Starch/Stärke 1993, 45, 276-280.
5. R. L. Shogren, B. K. Jasberg: Aging Properties of Extruded High-Amylose Starch. J. Environ. Polym. Degr. 1994, 2, 99-109.
6. R. L. Shogren, C. L. Swanson, A. R. Thompson: Extrudates of Corn Starch with Urea and Glycols: Structure/Mechanical Property Relations. Starch/Stärke 1992, 9, 335-338.
7. J. Schroeter, H.-J. Endres: Eigenschaften thermoplastisch verarbeiteter reiner Kartoffelstärke. Kunststoffe 1992, 82, 1086-1089.
8. U. Funke, M. G. Lindhauer: Eigenschaften von Gießfilmen aus nativen und chemisch modifizierten Stärken. Starch/ Stärke 1994, 46, 384-388.
9. A. T. Gros, R. O. Fenge: Properties of the Fatty Acid Esters of Amylose. J. Am. Oil. Chem. Soc. 1962, 39, 19-24.
10. M. L. Rooney: Interesterification of Starch with Methyl Palmitate. Polymer 1976, 17, 555-558.
11. C. Fringant, M. Rinaudo, M. F. Foray, M. Bardet: Preparation of Mixed Esters of Starch or Use of an External Plasticizer: Two Different Ways to Change the Properties of Acetate Films. Carbohydr. Polym. 1998, 35, 97-106.
12. C. Fringant, J. Desbieres, M. Rinaudo: Physical Properties of Acetylated Starch Based Materials: Relation with Molecular Characteristics. Polymer 1996, 37, 2663-2673.
13. A. D. Sagar, E. W. Merrill: Properties of Fatty-Acid Esters of Starch. J. Appl. Polym. Sci. 1995, 58, 1647-1656.
14. S. Thiebaud, J. Aburto, I. Alric, E. Borredon, D. Bikiaris, J. Pinos, C. Panayioton: Properties of Fatty-Acid Esters of Starch and Their Blends with LDPE. J. Appl. Polym. Sci. 1997, 65, 705-721.
15. J. W. Mullen II, E. Pascu: Preparation and Properies of Starch Triesters. Ind. Eng. Chem. 1942, 34, 1209-1217.
16. I. A. Wolff, D. W. Olds, G. E. Hilbert: Triesters of Corn Starch, Amylose, and Amylopectin. Ind. Eng. Chem. 1951, 43, 911-914.
17. I. A. Wolff, D. W. Olds, G. E. Hilbert: Mixed Esters of Amylose. Ind. Eng. Chem. 1957, 49, 1247-1248.
18. A. M. Mark, C. L. Mehltretter: Acetylation of High-Amylose Corn Starch. Stärke 1970, 22, 108-110.
19. A. M. Mark, C. L. Mehltretter: Facile Preparation of Starch Triacetates. Stärke/Starch 1972, 24, 73-100.
20. A. Jeanes, R. W. Jones: Acetylation of Amylaceous Polysaccharides. J. Am. Chem. Soc. 1952, 74, 6116-8.
21. I. A. Wolff, D. W. Olds, G. E. Hilbert: The Acetylation of Corn Starch, Amylose and Amylopectin. J. Am. Chem. Soc. 1951, 73, 346-349.
22. E. Husemann, H. Bartl: Über natürliche und synthetische Amylose. Die Acetylierung der Amylose. Makromolekulare Chemie 19 1956, 342-351.
23. M. Rinaudo, C. Fringant: Structure and Properties of Starch Acetates, in Carbohydrates as Organic Raw Materials IV (Eds. W. Praznik, A. Huster), WUV-Universitäts-Verlag, Wien, 1998.
24. J. Aburto, I. Alric, E. Borredon: Preparation of Long-Chain Esters of Starch Using Fatty Acid Chlorides in the Absence of an Organic Solvent. Starch/Stärke 1999, 51, 132-135.
25. J. Aburto, H. Hamaili, G. Mouysset-Baziard, F. Senocq, I. Alric, E. Borredon: Free-Solvent Synthesis and Properties of Higher Fatty Esters of Starch. Part 2. Starch/Stärke 1999, 51, 302-307.
26. J. Aburto: Study of the Reactivity of Starch with Fatty Acid Derivatives, Production of Thermoplastic and Hydrophobic Materials. Carbohydrates in Europe 1999, 27, 42-43.
27. B. Wesslen: Amphiphilic Graft Copolymers. Preparation and Interfacial Properties. Macromol. Symp. 1998, 130, 403-410.
28. F. Bien, B. Wiege, S. Warwel, Hydrophobic Modification of Starch by Alkali-catalyzed Addition of 1,2-Epoxyalkanes. Starch/Stärke 2001, 53, 555-559.
29. DIN-Taschenbuch 18, Prüfnormen Kunststoffe, mechanische und thermische Eigenschaften, 10. Aufl., Beuth-Verlag, Berlin 1997, pp. 493-500.
30. A. van Warners, Modification of Starch by Reaction with Ethylene Oxide in Liquid-Solid and Gas-Solid Reactors, PhD Thesis, University of Groningen, 1992.