Clean oxidation of thiolates to sulfinates in a four-coordinate CoIII complex with a mixed carboxamido N-thiolato S donor set: Relevance to nitrile hydratase

Journal of Inorganic Biochemistry

Volumn 84, Issue 3-4, 2001, Pages 207-213

  Rat, M ^a   Alves De Sousa, R ^a   Vaissermann, J ^b   Leduc, P ^a   Mansuy, D ^a   Artaud, I ^a  

^a UNIVERSITÉ PARIS DESCARTES   (France)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

Amide; Cobalt; Nitrile hydratase; Oxidation; Sulfinic

Indexed keywords

COBALT; HYDROLYASE; NITRILE HYDRATASE; ORGANOMETALLIC COMPOUND; SULFINIC ACID DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ENZYME ACTIVE SITE; INFRARED SPECTROPHOTOMETRY; OXIDATION REDUCTION REACTION; SYNTHESIS;

CATALYTIC DOMAIN; COBALT; HYDRO-LYASES; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; SPECTROPHOTOMETRY, INFRARED; SULFINIC ACIDS;

EID: 0035320791     PISSN: 01620134     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0162-0134(01)00181-7     Document Type: Article

References (23)

1. A. Claiborne, J.I. Yeh, T.C. Mallett, E.J. Crane, V. Charrier, D. Parsonage, Biochemistry 38 (1999) 15407-15416.
2. H.P. Fierobe, E. Mirgorodskaya, K.A. McGuire, P. Roepstorff, B. Svensson, A.J. Clarke, Biochemistry 37 (1998) 3743-3752.
3. J. Voss, J. Sun, P. Venkatesan, H.R. Kaback, Biochemistry 37 (1998) 8191-8196.
4. M. Kobayashi, S. Shimizu, Nature Biotech. 16 (1998) 733-736.
5. S. Nagashima, M. Nakasako, N. Dhomae, M. Tsujimura, K. Takio, M. Odaka, M. Yohda, N. Kamiya, I. Endo, Nature Struct. Biol. 5 (1998) 347-351.
6. B.A. Brennan, G. Alms, M.J. Nelson, L.T. Durney, R.C. Scarrow, J. Am. Chem. Soc. 118 (1996) 9194-9195.
7. M. Nojiri, H. Nakayama, M. Odaka, M. Yohda, K. Takio, I. Endo, FEBS Lett. 465 (2000) 173-177.
8. I. Kung, D. Schweitzer, J. Shearer, W.D. Taylor, H.L. Jackson, S. Lovell, J.A. Kovacs, J. Am. Chem. Soc. 1222 (2000) 8299-9300.
9. J.C. Noveron, M.M. Olmstead, P.K. Mascharak, J. Am. Chem. Soc. 121 (1999) 3553-3554.
10. L.A. Tyler, J.C. Noveron, M.M. Olmstead, P.K. Mascharak, Inorg. Chem. 39 (2000) 357-362.
11. S. Chatel, M. Rat, S. Dijols, P. Leduc, J.P. Tuchagues, D. Mansuy, I. Artaud, J. Inorg. Biochem. 80 (2000) 239-246.
12. S. Ito, A. Ota, H. Suhara, K. Tabashi, Y. Kawashima, Chem. Pharm. Bull. 41 (1993) 1066-1073.
13. W. Adam, J. Bialas, L. Hadjiarapoglou, Chem. Ber. 124 (1991) 2377.
14. G.M. Sheldrick, SHELXS86 Programme for the Solution of Crystal Structures, University of Göttingen, Göttingen, 1986.
15. D.J. Watkin, C.K. Prout, J.R. Carruthers, P.W. Bettendge, in: Crystals, Vol. 10, Chemical Crystallography Laboratory, University of Oxford, 1996.
16. P.J. Van der Put, A.A. Schilperood, Inorg. Chem. 13 (1974) 2476-2481, and references therein.
17. C.P. Sloan, J.H. Krueger, Inorg. Chem. 14 (1975) 1481-1485.
18. I.K. Adzamli, K. Libson, J.D. Lydon, R.C. Elder, E. Deutsch, Inorg. Chem. 18 (1979) 303-311.
19. K. Yamanari, T. Kawamoto, Y. Kushi, T. Komorita, A. Fuyuhiro, Chem. Lett. (1997) 559-560.
20. 13C NMR.
21. G. Simonneaux, F. Hindre, M. Le Plouzennec, Inorg. Chem. 28 (1989) 823-825.
22. J.C. Brewer, J.T. Collins, M.R. Smith, B.D. Santasiero, J. Am. Chem. Soc. 110 (1988) 423-428.
23. C.A. Grapperhaus, M.Y. Darensbourg, Acc. Chem. Res. 31 (1998) 451-459.