Co(III) complexes with carboxamido N and thiolato S donor centers: Models for the active site of co-containing nitrile hydratases [13]

Journal of the American Chemical Society

Volumn 121, Issue 14, 1999, Pages 3553-3554

  Noveron, Juan C ^a   Olmstead, Marilyn M ^a   Mascharak, Pradip K ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; NITRILE HYDRATASE;

CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; LETTER; STRUCTURE ANALYSIS;

EID: 0033553135     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9833523     Document Type: Letter

References (22)

1. (a) Yamada, H.; Kobayashi, M. Biosci. Biotechnol. Biochem. 1996, 60, 1391.
2. (b) Kobayashi, M.; Nagasawa, T.; Yamada, H. TIBTECH 1992, 10, 402.
3. (c) Nagasawa, T.; Yamada, H. Trends Biotechnol. 1989, 7, 153.
4. Huang, W.; Jia, J.; Cummings, J.; Nelson, M.; Schneider, G.; Lindqvist, Y. Structure 1997, 5, 691.
5. Nagashima, S.; Nakasako, M.; Dohmae, N.; Tsujimura, M.; Takio, K.; Odaka, M.; Yohda, M.; Kamiya, N.; Endo, I. Nat. Struct. Biol. 1998, 5, 347.
6. Nagasawa, T.; Takeuchi, K.; Yamada, H. Eur. J. Biochem. 1991, 196, 581.
7. Brennan, B. A.; Alms, G.; Nelson, M. J.; Durney, L. T.; Scarrow, R. C. J. Am. Chem. Soc. 1996, 118, 9194.
8. 3, 298 K, ppm from TMS) δ 3.39 (s, 2H, SH groups), 7.12 (t, 2H), 7.36 (t, 2H), 7.55 (d, 2H), 8.18 (t, 1H), 8.37 (d, 2H), 8.53 (d, 2H), 10.49 (s, 2H, carboxamide groups).
9. 3, R1 = 5.89%, wR2 = 11.05%. The structure was solved by direct methods (SHELXS-97).
10. (a) Ray, M.; Ghosh, D.; Shirin, Z.; Mukherjee, R. Inorg. Chem. 1997, 36, 3568 and references therein.
11. (b) Freeman, H. C.; Moore, C. J.; Jackson, W. G.; Sargeson, A. M. Inorg. Chem. 1978, 17, 3513.
12. (c) Helis, H. M.; de Meester, P.; Hodgson, D. J. J. Am. Chem. Soc. 1977, 99, 3309.
13. 3, R1 = 6.77%, wR2 = 13.57%. The structure was solved by direct methods (SHELXS-97).
14. (a) Romero, R. G.; Morales, A. D.; Rodriguez, J. D.; Bertran, J. F. Transition Met. Chem. 1992, 17, 573.
15. (b) Fronczek, F. R.; Marsh, R. E.; Schaefer, W. P. J. Am. Chem. Soc. 1982, 104, 3382.
16. -1): 600 sh, 470 (4100), 413 (4700).
17. 2-.
18. - (Supporting Information).
19. (a) Chavez, F. A.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chem. 1997, 36, 6323.
20. (b) Chavez, F. A.; Nguyen, C. V.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chem. 1996, 35, 6282.
21. (a) Kim, J. H.; Britten, J.; Chin, J. J. Am. Chem. Soc. 1993, 115, 3618.
22. (b) Chin, J.; Kim, J. H. Angew. Chem., Int. Ed. Engl. 1990, 29, 523.