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Volumn 34, Issue 5, 2001, Pages 1160-1164

Stereospecific polymerization of propiolic acid with rhodium complexes in the presence of bases and helix induction on the polymer in water

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CARBOXYLIC ACIDS; CAUSTIC SODA; MOLECULAR STRUCTURE; POLYMERIZATION; RHODIUM; SOLUBILITY; WATER;

EID: 0035249811     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma001651i     Document Type: Article
Times cited : (119)

References (37)
  • 21
    • 0020127092 scopus 로고
    • For direct polymerization of propiolic acid with transition-metal catalysts, see: Masuda, T.; Kawai, M.; Higashimura, T. Polymer 1982, 23, 744-747.
    • (1982) Polymer , vol.23 , pp. 744-747
    • Masuda, T.1    Kawai, M.2    Higashimura, T.3
  • 24
    • 0031557569 scopus 로고    scopus 로고
    • note
    • 2O)]) in water did not yield polymeric products and the lack of the Rh-aromatic interaction between the Rh complex and the aliphatic monomers might be responsible for the failure of the polymerization. However, the present results indicate that such a Rh-aromatic interaction may not be necessary for the polymerization of aliphatic acetylenes with the Rh-based complexes, although a Rh-carbonyl interaction could not be ruled out. Tang, B. Z.; Poon, W. H.; Leung, S. M.; Leung, W. H.; Peng, H. Macromolecules 1997, 30, 2209-2212.
  • 25
    • 0343294040 scopus 로고    scopus 로고
    • note
    • 7, indicating that in this eluent, the polymer may aggregate, and the molecular weight of poly-1-Na could not be estimated.
  • 26
    • 6444222991 scopus 로고
    • meter reading + 0.40 reported by Glasoe et al., see: Glasoe, P. K.; Long, F. A. J. Phys. Chem. 1960, 64, 188-190.
    • (1960) J. Phys. Chem. , vol.64 , pp. 188-190
    • Glasoe, P.K.1    Long, F.A.2
  • 29
    • 0342859029 scopus 로고    scopus 로고
    • note
    • The polymers gradually decomposed accompanied by the cis to trans isomerization as detected by the SEC measurements.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.