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2O)]) in water did not yield polymeric products and the lack of the Rh-aromatic interaction between the Rh complex and the aliphatic monomers might be responsible for the failure of the polymerization. However, the present results indicate that such a Rh-aromatic interaction may not be necessary for the polymerization of aliphatic acetylenes with the Rh-based complexes, although a Rh-carbonyl interaction could not be ruled out. Tang, B. Z.; Poon, W. H.; Leung, S. M.; Leung, W. H.; Peng, H. Macromolecules 1997, 30, 2209-2212.
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The polymers gradually decomposed accompanied by the cis to trans isomerization as detected by the SEC measurements.
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