Poly((4-dihydroxyborophenyl)acetylene) as a novel probe for chirality and structural assignments of various kinds of molecules including carbohydrates and steroids by circular dichroism

Journal of the American Chemical Society

Volumn 118, Issue 40, 1996, Pages 9800-9801

  Yashima, Eiji ^a   Nimura, Tsuyoshi ^a   Matsushima, Teruyuki ^a   Okamoto, Yoshio ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

STEROID;

ARTICLE; CARBOHYDRATE ANALYSIS; CHIRALITY; CIRCULAR DICHROISM; DRUG STRUCTURE; TECHNIQUE;

EID: 0029972307     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960439k     Document Type: Article

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43. -1) and λ (nm)) of the second Cotton for the complexes were 3.8 (372), 14 (379), and 1.3 (365), respectively.
44. -1) and λ (nm)) of the second Cotton for the complexes with (S)-9, (R)-10, (S)-11, (S)-13, and (5)-14 were -9.4 (370), 5.6 (374), -15 (372), 17 (368), and 18 (371), respectively.
45. The magnitude of the ICDs was significantly influenced by pH. The influence of the pH on the ICD was investigated for the mixtures of poly-1 with (S,S)-4, (R)-7, (S)-12, or (S)-16 (see supporting information).
46. 13C NMR studies of the model complexes with respect to the relation between the split-type of the Cotton effects and configuration of the molecules, see the supporting information.