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Volumn 65, Issue 21, 2001, Pages 3931-3953

Estimation of standard-state entropies of association for aqueous metal-organic complexes and chelates at 25°C and 1 bar

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SOLUTION; CHELATE; ENTROPY; GEOCHEMISTRY; ORGANOMETALLIC COMPOUND;

EID: 0035200960     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(01)00701-3     Document Type: Article
Times cited : (11)

References (165)
  • 1
    • 0000000639 scopus 로고
    • Thermodynamics of metal complex formation in aqueous solution, III, a calorimetric study of hydrogen sulphate and uranium (VI) sulphate, acetate, and thiocyanate complexes
    • (1971) Acta Chem. Scand , vol.25 , pp. 3677-3691
    • Ahrland, S.1    Kullberg, L.2
  • 2
    • 0000511240 scopus 로고
    • Komplexone XXXIII. Reaktionsenthalpie undentropie bei der bildung der metallkomplexe von äthylendiamin- und diaminocyclohexan-tetraessigsäure
    • (1963) Helv. Chim. Acta , vol.46 , pp. 1833-1842
    • Anderegg, G.1
  • 3
    • 84984083445 scopus 로고
    • Komplexone XXXVI. Reaktionsenthalpie und -entropie bei der bildung der metallkomplexe der höheren EDTA-homologen
    • (1964) Helv. Chim. Acta , vol.47 , pp. 1801-1814
    • Anderegg, G.1
  • 4
    • 0006840813 scopus 로고
    • Komplexone XXXIV. Reaktionsenthalpie undentropie bei der bildung der 1:1- und 1:2-metallkomplexe von nitrilotriessigsäure
    • (1964) Experientia Supplementum , vol.9 , pp. 75-83
    • Anderegg, G.1
  • 5
    • 0006800960 scopus 로고
    • Komplexone XXXIX. Die bildungs-enthalpie undentropie der metallkomplexe des diäthylentriaminpentaacetat-ions
    • (1965) Helv. Chim. Acta , vol.48 , pp. 1722-1725
    • Anderegg, G.1
  • 6
    • 0006866979 scopus 로고
    • Komplexone, XLVII Die thermodynamik der komplexbildung von einigen ein-und zweiwertigen metallionen mit aethylendiamintetraacetat-und uramildiacetat-ion
    • (1976) Z. Naturforsch , vol.31 b , pp. 783-789
    • Anderegg, G.1
  • 13
    • 0006801294 scopus 로고
    • Calorimetric studies of the ethereal oxygen and thioethereal sulphur coordinating properties in aqueous solution-II Thermodynamics of association of oxydiacetate and thiodiacetate ions with bivalent metals
    • (1978) J. Inorg. Nucl. Chem , vol.40 , pp. 1077-1080
    • Aruga, R.1
  • 14
    • 0000262292 scopus 로고
    • Coordinating properties of pyridinecarboxylate anions with metals in aqueous solution
    • (1979) J. Inorg. Nucl. Chem , vol.41 , pp. 845-848
    • Aruga, R.1
  • 15
    • 0006841366 scopus 로고
    • Steric factors and stability of the complexes of pyridinecarboxylate ions with group IIA cations, A thermodynamic study
    • (1983) Bull. Soc. Chim. France , pp. 179-182
    • Aruga, R.1
  • 23
    • 0002098450 scopus 로고
    • The heat and entropy of association of the complex ions formed by EDTA with the lanthanide elements in aqueous solution
    • (1959) Can. J. Chem , vol.37 , pp. 91-100
    • Betts, R.H.1    Dahlinger, O.F.2
  • 25
  • 35
    • 0006766361 scopus 로고
    • Thermodynamics of metal chelate formation, I, The third and fourth dissociation constants of ethylenediaminetetraacetic acid
    • (1953) J. Am. Chem. Soc , vol.75 , pp. 4810-4813
    • Carini, F.F.1    Martell, A.E.2
  • 40
    • 33947448472 scopus 로고
    • Heats and entropies of reaction of metal ions with ethylenediaminetetra acetate
    • (1954) J. Am. Chem. Soc , vol.76 , pp. 5854-5858
    • Charles, R.G.1
  • 47
    • 0006833975 scopus 로고
    • Empirical considerations of entropy, I, The entropies of the oxy-anions and related species
    • (1953) J. Chem. Phys , vol.21 , pp. 1443-1446
    • Cobble, J.W.1
  • 48
    • 0006765435 scopus 로고
    • Empirical considerations of entropy, II, The entropies of inorganic complex ions
    • (1953) J. Chem. Phys , vol.21 , pp. 1446-1450
    • Cobble, J.W.1
  • 50
    • 37049093692 scopus 로고
    • Thermodynamic considerations in co-ordination, Part XXIV, Gibbs free-energy changes. enthalpies, and entropies of formation of complexes of glycinate, glycylglycinate, glycylglycylglycinate, cysteinate, and gluthathionate with hydrogen and lead(II) ions and suggested aqueous structures
    • (1976) J. Chem. Soc. Dalton , pp. 1068-1072
    • Corrie, A.M.1    Williams, D.R.2
  • 53
    • 33845378349 scopus 로고
    • Ionic strength dependence of formation constants, Alkali metal complexes of ethylenediaminetetraacetate, nitrilotriacetate, diphosphate, and tripolyphosphate in aqueous solution
    • (1985) Anal. Chem , vol.57 , pp. 2956-2960
    • Daniele, P.G.1    Rigano, C.2    Sammartano, S.3
  • 64
    • 0006800661 scopus 로고
    • Thermometric studies on the Fe(III)-EDTA chelate
    • (1978) Talanta , vol.25 , pp. 97-101
    • Doi, K.1
  • 67
    • 0006841368 scopus 로고
    • Studies on uranyl complexes-V Heats and entropies of formation of uranyl chelates of polyaminocarboxylic acids
    • (1969) Rev. Port. Quim , vol.11 , pp. 54-60
  • 68
  • 71
    • 0000244688 scopus 로고
    • Thermochemical studies on metal complexes V. Free energy, enthalpy, and entropy changes for stepwise formation of some metal (II) acetate complexes in aqueous solution
    • (1967) Acta Chem. Scand , vol.21 , pp. 2015-2027
    • Gerding, P.1
  • 72
    • 0006833976 scopus 로고
    • Thermochemical studies on metal complexes VIII, Free energy, enthalpy, and entropy changes for stepwise formation of cadmium (II) thiocyanate and acetate complexes at different ionic strengths
    • (1968) Acta Chem. Scand , vol.22 , pp. 2255-2262
    • Gerding, P.1    Johansson, B.2
  • 75
    • 0001658680 scopus 로고
    • Thermodynamic properties of rare earth complexes II, Free energy, enthalpy and entropy changes for the formation of rare earth diglycolate and dipicolinate complexes at 25.00°C
    • (1963) Acta Chem. Scand , vol.17 , pp. 2487-2498
    • Grenthe, I.1
  • 76
    • 0001605579 scopus 로고
    • Thermodynamic properties of rare earth complexes III, Free energy, enthalpy, and entropy changes for the formation of rare earth acetate, glycolate and thioglycolate complexes at 25.00°C
    • (1964) Acta Chem. Scand , vol.18 , pp. 283-292
    • Grenthe, I.1
  • 77
    • 0001618287 scopus 로고
    • Thermodynamic properties of rare earth complexes VII, Free energy, enthalpy, and entropy changes for the formation of scandium (III) diglycolate, dipicolinate, and malonate complexes at 25.00°C
    • (1969) Acta Chem. Scand , vol.23 , pp. 611-627
    • Grenthe, I.1    Hansson, E.2
  • 79
    • 0016916923 scopus 로고
    • Theoretical prediction of the thermodynamic properties of aqueous electrolytes at high pressures and temperatures, III, Equation of state for aqueous species at infinite dilution
    • (1976) Am. J. Sci , vol.276 , pp. 97-240
    • Helgeson, H.C.1    Kirkham, D.H.2
  • 81
    • 84987336710 scopus 로고
    • The stabilities and thermodynamic properties of thorium (IV) and zirconium (IV) chelates of ethylenebis (oxyethylenenitrilo) tetraacetic acid
    • (1981) J. Chinese Chem. Soc , vol.28 , pp. 119-124
    • Hseu, T.-M.1    Jyi, K.-M.2
  • 94
    • 0006807459 scopus 로고
    • The entropies of ions in aqueous solution I, Dependence on charge and radius
    • (1956) Can. J. Chem , vol.34 , pp. 1107-1113
    • Laidler, K.J.1
  • 113
    • 0006807460 scopus 로고
    • Thermodynamische untersuchungen an lösungsgleichgewichten zwischen lonen der 3 d-elemente und anthranilsäure-N.N-diessigsäure bzw. ß-aminopropionsäure-N.N-diessingsäure
    • (1970) Z. Anorg. Allg. Chem , vol.375 , pp. 166-170
    • Martin, V.A.1    Uhlig, E.2
  • 119
    • 49949133935 scopus 로고
    • The stabilities and thermodynamic functions for the formation of aluminium and mercury (II) chelates of certain polyaminepolyacetic acids
    • (1966) J. Inorg. Nuel. Chem , vol.28 , pp. 153-159
    • Moeller, T.1    Chu, S.-K.2
  • 120
    • 0000952960 scopus 로고
    • Observations on the rare earths-LXXIII The heat and entropy of formation of the 1:1 chelates of N-hydroxyethylethylenediaminetriacetic acid with the tripositive cations
    • (1961) J. Inorg. Nucl. Chem , vol.20 , pp. 261-273
    • Moeller, T.1    Ferrús, R.2
  • 121
    • 0001445301 scopus 로고
    • Observations on the rare earths-LXXVI the stabilities of the trans-1,2-diaminocyclohexanc-N,N'-tetraacetic acid chelates of the tri-positive ions
    • (1962) J. Inorg. Nucl. Chem , vol.24 , pp. 1635-1643
    • Moeller, T.1    Hseu, T.M.2
  • 124
  • 133
  • 138
    • 0028976031 scopus 로고
    • Organic acids in hydrothermal solutions: Standard molal thermodynamic properties of carboxylic acids and estimates of dissociation constants at high temperatures and pressures
    • (1995) Am. J. Sc , vol.295 , pp. 496-580
    • Shock, E.L.1
  • 139
    • 0024190666 scopus 로고
    • Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C
    • (1988) Geochim. Cosmochim. Acta , vol.52 , pp. 2009-2036
    • Shock, E.L.1    Helgeson, H.C.2
  • 140
    • 0027795506 scopus 로고
    • Metal-organic complexes in geochemical processes: Calculation of standard partial molal thermodynamic properties of aqueous acetate complex at high pressures and temperatures
    • (1993) Geochim. Cosmochim. Acta , vol.57 , pp. 4899-4922
    • Shock, E.L.1    Koretsky, C.M.2
  • 141
    • 0028870761 scopus 로고
    • Metal-organic complexes in geochemical processes: Estimation of standard partial molal thermodynamic properties of aqueous complexes between metal cations and monovalent organic acid ligands at high pressures and temperatures
    • (1995) Geochim. Cosmochim. Acta , vol.59 , pp. 1497-1532
    • Shock, E.L.1    Koretsky, C.M.2
  • 148
    • 33947322698 scopus 로고
    • Lanthanide and actinide complexes of glycine, Determination of stability constants and thermodynamic parameters by a solvent extraction method
    • (1968) Inorg. Chem , pp. 2046-2048
    • Tanner, S.P.1    Choppin, G.R.2
  • 150
    • 0006842854 scopus 로고
    • Thermodynamische untersuchungen an erdalkalichelaten der anthranilsäure-N,N-diessigsäure und der ß-aminopropionsäure-N,N-diessigsäure
    • (1969) J. Inorg. Nucl. Chem , vol.31 , pp. 2781-2786
    • Uhlig, E.1    Martin, A.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.