Outer-sphere adsorption of Pb(II)EDTA on goethite

Geochimica et Cosmochimica Acta

Volumn 63, Issue 19-20, 1999, Pages 2957-2969

  Bargar, John R ^a   Persson, Per ^b   Brown Jr , Gordon E ^a,c  

^a SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^b UMEÅ UNIVERSITY   (Sweden)

^c STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; GOETHITE; LEAD;

EID: 0033379761     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(99)00264-1     Document Type: Article

References (56)

1. Bargar J.R., Brown G.E. Jr, Parks G.A. Surface complexation of Pb(II) at oxide-water interfaces I. XAFS and bond-valence determination of mono- and polynuclear Pb(II) sorption products on Al-oxides . Geochim. Cosmochim. Acta. 61:1997;2617-2638.
2. Bargar J.R., Brown G.E. Jr, Parks G.A. Surface complexation of Pb(II) at oxide-water interfaces II. XAFS and bond-valence determination of mononuclear Pb(II) sorption products and surface functional groups on Fe-oxides . Geochim. Cosmochim. Acta. 61:1997;2639-2652.
3. Bargar J.R., Brown G.E. Jr, Parks G.A. Surface complexation of Pb(II) at oxide-water interfaces III. XAFS determination of Pb(II) and Pb(II)-chloro adsorption complexes on goethite and alumina . Geochim. Cosmochim. Acta. 62:1998;193-207.
4. Bargar J. R., Reitmeyer R. L., and Davis J. A. (1999) Spectroscopic characterization of U(VI)-carbonato surface complexes on hematite and ferrihydrite. In Surface Complexation Modeling of U(VI) Adsorption on Natural Mineral Assemblages. NUREG Report. U.S. Nuclear Regulatory Commission.
5. Bargar J.R., Towle S.N., Brown G.E. Jr, Parks G.A. Outer-sphere lead(II) adsorbed at specific surface sites on single crystal α-alumina. Geochim. Cosmochim. Acta. 60:1996;3541-3548.
6. 3. J. Coll. Interf. Sci. 185:1997;473-492.
7. Blaylock M.J., Salt D.E., Dushenkov S., Sakharova O., Gussman C., Kapulnik Y., Ensley B.D., Raskin I. Enhanced accumulation of Pb in Indian mustard by soil-applied chelating agents. Environ. Sci. Technol. 31:1997;860-865.
8. Bowers A.R., Huang C.P. Adsorption characteristics of metal-EDTA complexes onto hydrous oxides. J. Coll. Interf. Sci. 110:1986;575-590.
9. Bryce A.L., Kornicker W.A., Clark S.B. Nickel adsorption to hydrous ferric oxide in the presence of EDTA Effects of component addition sequence . Environ. Sci. Technol. 28:1994;2353-2359.
10. Busch D.H., Bailar J.C. The stereochemistry of complex inorganic compounds XVII. The stereochemistry of hexadentate ethylenediaminetetraacetic acid complexes. J. Am. Chem. Soc. 75:1953;4574-4575.
11. 3/water interface. Geochim. Cosmochim. Acta. 54:1990;1897-1909.
12. Erel Y., Morgan J.J. The relationships between rock-derived lead and iron in natural waters. Geochim. Cosmochim. Acta. 56:1992;4157-4167.
13. Fujita J., Martell A.E., Nakamoto K. Infrared spectra of metal chelate compounds. VI. A normal coordinate treatment of oxalato metal complexes. J. Chem. Phys. 36:1962;324-338.
14. George G.N. EXAFSPAK. 1993;Stanford Synchrotron Radiation Laboratory.
15. 3. Soil Sci. Soc. Am. J. 57:1993;45-57.
16. Greenwood N.N., Earnshaw A. Chemistry of the Elements. 1985;Pergamon Press.
17. Gunneriusson L., Lovgren L., Sjöberg S. Complexation of Pb(II) at the goethite (α-FeOOH)/water interface The influence of chloride . Geochim. Cosmochim. Acta. 58:1994;4973-4983.
18. Harrison P.G., Healy M.A., Steel A.T. EDTA-chelation therapy of lead poisoning Lead-207 nuclear magnetic resonance and X-ray diffraction studies . Inorg. Chim. Acta. 67:1982;L15-L16.
19. Harrison P.G., Steel A.T. Lead(II) carboxylate structures. J. Organometallic Chem. 239:1982;105-113.
20. Hem J.D. Geochemical controls on lead concentrations in stream water and sediments. Geochim. Cosmochim. Acta. 40:1976;599-609.
21. Huang J.W., Chen J., Berti W.B., Cunningham S.D. Phytoremediation of lead-contaminated soils Role of synthetic chelates in lead phytoextraction . Environ. Sci. Technol. 31:1997;800-805.
22. Huang J.W., Cunningham S.D. Lead phytoextraction Species variation in lead uptake and translocation . N. Phytol. 134:1996;75-84.
23. Jardine P.M., Jacobs G.K., O'Dell J.D. Unsaturated transport processes in undisturbed heterogeneous porous media II. Co-contaminants . Soil Sci. Soc. Am. J. 57:1993;954-962.
24. Jenne E.A. Controls on Mn, Fe, Co, Ni, Cu and Zn concentrations in soils and water The signficant role of hydrous Mn and Fe oxides . Trace Inorganics in Water. Vol. 73:1967;337-387 American Chemical Society.
25. Jørgensen S.E. Removal of heavy metals from compost and soil by echotechnological methods. Ecol. Eng. 2:1993;89-100.
26. Kari F.G., Giger W. Modeling the photochemical degredation of EDTA in the river Glatt. Environ. Sci. Technol. 29:1995;2814-2827.
27. Krishnan K., Plane R.A. Raman spectra of ethylenediaminetetraacetic acid and its metal complexes. J. Am. Chem. Soc. 90:1968;3195-3199.
28. Manceau A., Charlet L., Boisset M.C., Didier B., Spadini L. Sorption and speciation of heavy metals on hydrous Fe and Mn oxides. From microscopic to macroscopic. Appl. Clay Sci. 7:1992;201-230.
29. McConell A.A., Nuttall R.H. The vibrational spectra of EDTA complexes of divalent tin and lead. Spectrochim. Acta. 33A:1977;459-462.
30. Means J.L., Kucak T., Crerar D.A. Relative degradation rates of NTA, EDTA, and DTPA and environmental implications. Environ. Poll. 1:1980;45-60.
31. Morris M.L., Busch D.H. The properties and infrared absorption spectra of complexes of cobalt(III) with pentadentate ethylenediaminetetraacetic acid and hydroxyethylenediaminetriacetic acid. J. Am. Chem Soc. 78:1956;5178-5181.
32. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 1986;J. Wiley & Sons.
33. Nakamoto K., Morimoto Y., Martell A.E. Infrared spectra of aqueous solutions. III. Ethylenediaminetetraacetic acid, N-hydroxyethylenediaminetriacetic acid, and diethylenetriaminepentaacetic acid. J. Am. Chem. Soc. 85:1963;309-316.
34. Nordin J., Persson P., Laiti E., and Sjoberg S. (1997) Adsorption of o-phthalate at the water-boehmite (γ-AlOOH) interface: Evidence for two coordination modes. Langmuir 13, 4085-4083.
35. Nordin J., Persson P., Nordin A., Sjoberg S. Inner- and outer-sphere complexation of a polycarboxylic acid at the water-boehmite (γ-AlOOH) interface A combined potentiometric and IR spectroscopic study . Langmuir. 14:1998;3655-3662.
36. Nowack B., Sigg L. Adsorption of EDTA and metal-EDTA complexes onto goethite. J. Colloid Interf. Sci. 177:1996;106-121.
37. Nowack B., Sigg L. Dissolution of Fe(III)(hydr)oxides by metal-EDTA complexes. Geochim. Cosmochim. Acta. 61:1997;951-963.
38. Persson P., Karlsson M., Ohman L.-O. Coordination of acetate to Al(III) in aqueous solution and at the water-aluminum hydroxide interface A potentiometric and attenuated total reflectance FTIR study . Geochim. Cosmochim. Acta. 62:1998;3657-3668.
39. 3, and goethite. J. Coll. Interf. Sci. 206:1998;252-256.
40. Reed G.H., Kula R.J. Nuclear magnetic resonance and infrared spectral studies of structural and kinetic properties of amino polycarboxylate chelates of divalent lead, zinc, cadmium, and mercury in acidic aqueous solution. Inorg. Chem. 10:1971;2050-2057.
41. Rehr J.J., Albers R.C. Scattering-matrix formulation of curved-wave multiple-scattering calculations of X-ray absorption fine structure. Phys. Rev. B. 41:1990;8139-8149.
42. Rehr J.J., Mustre de Leon J., Zabinsky S.I., Albers R.C. Theoretical X-ray absorption fine structure standards. J. Am. Chem. Soc. 113:1991;5135-5140.
43. Rehr J.J., Zabinsky S.I., Albers R.C. High-order multiple-scattering calculations of X-ray absorption fine structure. Phys. Rev. Lett. 69:1992;3397.
44. Roe A.L., Hayes K.F., Chisholm-Brause C.J., Brown G.E.J., Parks G.A., Hodgson K.O., Leckie J.O. In-situ X-ray absorption study of lead ion surface complexes at the goethite-water interface. Langmuir. 7:1991;367-373.
45. Rojo T., Insausti M., Arriortua M.I., Hernandez E., Zubillaga J. Thermal decomposition study of some complexes, precursors of mixed oxides, with formula MM′(L)·nH2O. Thermochim. Acta. 195:1992;94-104.
46. Sawer D.T., Tackett J.E. Properties and infrared spectra of ethylenediaminetetraacetic acid complexes V. Bonding and structure of several metal chelate complexes . J. Am. Chem. Soc. 85:1963;2390-2394.
47. Scott K.L., Wieghardt K., Sykes A.G. μ-Oxalato-cobalt(III) complexes. Inorg. Chem. 12:1973;655-663.
48. Shields K.G., Seccombe R.C., Kennard C.H.L. Stereochemistry of flexible-chelate-metal complexes. Part III. Crystal structure of dihydrogen ethylenediaminetetra-acetatostannate(II). J. Chem. Soc. Dalton Trans. 1973;741-743.
49. Sievers R.E., Bailar J.J.C. Some metal chelates of ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and triethylenetetraaminehexaaacetic acid. Inorg. Chem. 1:1962;174-182.
50. Sposito G. The Surface Chemistry of Soils. 1984;Oxford University Press.
51. Stumm W. Chemistry of the Solid-Water Interface. 1992;J. Wiley & Sons.
52. Szecsody J.E., Achara J.M., Bruckhart P.L. Adsorption-dissolution reactions affecting the distribution and stability of Co(II)EDTA in iron oxide-coated sand. Environ. Sci. Technol. 28:1994;1706-1716.
53. Van Geen A., Robertson A.P., Leckie J.O. Complexation of carbonate species at the goethite surface Implications for adsorption of metal ions in natural waters . Geochim. Cosmochim. Acta. 58:1994;2073-2086.
54. van Remoortere F.P., Flynn J.J., Boer F.P., North P.P. The crystal structure of distannous ethylenediaminetetraacetate dihydrate. Inorg. Chem. 10:1971;1511-1518.
55. 2O crystal. Cryst. Res. Technol. 28:1993;K49-K53.
56. Zachara J.M., Smith S.C., Kuzel L.S. Adsorption and dissociation of Co-EDTA complexes in iron oxide-containing subsurface sands. Geochim. Cosmochim. Acta. 59:1995;4825-4844.