Dissolution of Fe(III)(hydr) oxides by metal-EDTA complexes

Geochimica et Cosmochimica Acta

Volumn 61, Issue 5, 1997, Pages 951-963

  Nowack, Bernd ^a,b   Sigg, Laura ^a  

^a SWISS FEDERAL INSTITUTE OF AQUATIC SCIENCE AND TECHNOLOGY   (Switzerland)

^b The Johns Hopkins University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DISSOLUTION; EDTA; GOETHITE; HYDROUS FERRIC OXIDE; REACTION KINETICS;

EID: 0030861373     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0016-7037(96)00391-2     Document Type: Article

References (36)

1. Bergers P. J. M. and deGroot A. C. (1994) The analysis of EDTA in water by HPLC. Wat. Res. 28, 639-642.
2. Biber M. V., Dos Santos Afonso M., and Stumm W. (1994) The coordination chemistry of weathering: IV. Inhibition of the dissolution of oxide minerals. Geochim. Cosmochim. Acta 58, 1999-2010.
3. Blesa M. A., Borghi E. B., Maroto A. J. G., and Regazzoni A. E. (1984) Adsorption of EDTA and iron-EDTA complexes on magnetite and the mechanism of dissolution of magnetite by EDTA. J. Colloid Interface Sci. 98, 295-305.
4. Bondietti G., Sinniger J., and Stumm W. (1993) The reactivity of Fe(III)(hydr) oxides: effects of ligands in inhibiting the dissolution. Colloids and Surfaces 79, 157-167.
5. Borggaard O. K. (1991) Effects of phosphate on iron oxide dissolution in EDTA and oxalate. Clays Clay Min. 39, 324-328.
6. Borghi E. B., Regazzoni A. E., Maroto A. J. G., and Blesa M. A. (1989) Reductive Dissolution of magnetite by solutions containing EDTA and Fe(II). J. Colloid Interface Sci. 130, 299-310.
7. Bowers A. R. and Huang C. P. (1986) Adsorption characteristics of metal-EDTA complexes onto hydrous oxides. J. Colloid Interface Sci. 110, 575-590.
8. Chang H-C. and Matijevic E. (1982) Interactions of metal hydrous oxides with chelating agents. Part V. Magnetite-EDTA. Finn. Chem-Lett. 1982, 90-95.
9. Chang H-C. and Matijevic E. (1983) Interactions of metal hydrous oxides with chelating agents. IV: Dissolution of hematite. J. Colloid Interface Sci. 92, 479-488.
10. Coston J. A., Davis J. A., Kent D. B., Hess K., Brienen P., Joye J., and Bussey K. (1994) Multi-species reactive solute transport experiment at the USGS research site, Cape Cod, Massachusetts: 2. reactive transport of metal-EDTA complexes. EOS 75, 249.
11. Davis J. A., Kent D. B., Rea B. A., Maest A. S., and Garabedian S. P. (1993) Influence of redox environment and aqueous speciation on metal transport in groundwater: preliminary results of tracer injection studies. In Metals in Groundwater (ed. M. E. Allen et al.), pp. 223-273. Lewis.
12. Davis J. A., Kent D. B., Coston J. A., Friedly J. C., Fuller C. C., Anderson L. D., and Hess K. M. (1994) Metal transport in groundwater: From microscopic processes to macroscopic observations. Proc. American Chemical Society 34, 323-326.
13. Deng Y. and Stumm W. (1994) Reactivity of aquatic iron(III)oxyhydroxydes - implications for redox cycling of iron in natural waters. Appl. Geochem. 9, 23-36.
14. Dzombak D. A. and Morel F. M. M. (1990) Surface complexation modeling: Hydrous ferric oxide. Wiley.
15. 3 and BeO. Geochim. Cosmochim. Acta 50, 1847-1860.
16. Hering J. (1995) Implications of complexation, sorption and dissolution kinetics for metal transport in soils. In Metal Speciation and Contamination of Soils (ed. H. E. Allen et al.). Lewis.
17. Hering J. G. and Morel F. M. M. (1989) Slow coordination reactions in seawater. Geochim. Cosmochim. Acta 53, 611-618.
18. Jardine P. M., Jacobs G. K., and O'Dell J. D. (1993) Unsaturated transport processes in undisturbed heterogeneous porous media: II. Co-contaminants. Soil Sci. Soc. Amer. J. 57, 954-962.
19. Kari F. G., and Giger W. (1995) Modeling the photochemical degradation of EDTA in the River Glatt. Environ. Sci. Technol. 29, 2814-2827.
20. Kari F. G. and Giger W. (1996) Speciation and fate of ethylenediam-ninetatraacetate (EDTA) in municipal wastewater treatment. Wat. Res. 30, 122-134.
21. Lin C.-F. and Benjamin M. M. (1990) Dissolution kinetics of minerals in the presence of sorbing and complexing ligands. Environ. Sci. Technol. 24, 126-134.
22. Ludwig Ch., Casey W. H., and Rock P. A. (1995) Prediction of ligand-promoted dissolution rates from the reactivities of aqueous complexes. Nature 375, 44-47.
23. Margerum D. W., Cayley G. R., Weatherburn D. C., and Pagenkopf G. K. (1978) Kinetics and mechanisms of complex formation and ligand exchange. In Coordination Chemistry (ed. A. E. Martell); ACS Monograph 174, pp. 1-220.
24. Margerum D. W., Cayley G. R., Weatherburn D. C., and Pagenkopf G. K. (1978) Kinetics and mechanisms of complex formation and ligand exchange. In Coordination Chemistry (ed. A. E. Martell); ACS Monograph 174, pp. 1-220.
25. Martell A. and Smith R. (1974) Critical stability constants. Plenum.
26. Müller B. (1993) MacμQL, V 1.2: A Program to Calculate Chemical Speciation and Adsorption. EAWAG Kastanienbaum.
27. Nowack B. and Sigg L. (1996) Adsorption of EDTA and metalEDTA complexes onto goethite. J. Colloid Interface Sci. 177, 106-121.
28. Nowack B., Lützenkirchen J., Behra P., and Sigg L. (1996) Modeling the adsorption of metal-EDTA complexes onto oxides. Environ. Sci. Technol. 30, 2397-2405.
29. Reichert P. (1994) Aquasim - a tool for simulation and data analysis of aquatic systems. Water. Sci. Technol. 30, 21-30.
30. Rubio J. and Matijevic E. (1979) Interactions of metal hydrous oxides with chelating agents. 1. β-FeOOH-EDTA. J. Colloid Interface Sci. 68, 408-42.
31. Schwertmann U. and Cornell R. M. (1991) Iron Oxides in the Laboratory: VCH.
32. Szecsody J. E., Zachara J. M., and Bruckhart P. L. (1994) Adsorption-dissolution reactions affecting the distribution and stability of Co(II)EDTA in iron oxide-coated sand. Environ. Sci. Technol. 28, 1706-1716.
33. Toste A. P., Osborn B. C., Polach K. J., and Lechner-Fish T. J. (1995) Organic analyses of an actual and simulated mixed waste: Hanford's organic complexant site revisited. J. Radioanal. Nucl. Chem. 194, 25-34.
34. Ulrich M. (1991) Modeling of chemicals in lakes - development and application of user-friendly simulation software (MASAS & CHEMSEE). Diss. ETH, Zurich.
35. Westall J. C. (1982) FITEQL: A program for the determination of chemical equilibrium constants from experimental data. Tech. Rept., Oregon State Univ., Corvallis.
36. Xue H. B., Sigg L., and Kari F. G. (1995) Speciation of EDTA in natural waters: Exchange kinetics of FeEDTA in river water. Environ. Sci. Technol. 29, 59-68.