New chemical and electrochemical synthesis of the [Mn4(IV)O6(bpy)6]4+ cluster. Electrochemical interconversion with corresponding Bi- and mononuclear complexes

Journal of the American Chemical Society

Volumn 120, Issue 22, 1998, Pages 5373-5380

  Dunand Sauthier, Marie Noëlle Collomb ^a   Deronzier, Alain ^a   Piron, Alexis ^a   Pradon, Xavier ^a   Ménage, Stéphane ^a  

^a UNIV GRENOBLE ALPES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

MANGANESE DERIVATIVE; METAL COMPLEX;

ARTICLE; COMPLEX FORMATION; ELECTROCHEMISTRY; OXIDATION; REACTION ANALYSIS; SYNTHESIS;

EID: 0032503596     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja974246o     Document Type: Article

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22. pc = 0.03 V).
23. + buffer (pH 4.5) for several hours. However, 4 is slowly converted to 2 after several days despite the large excess of bpy ligand.
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27. 2O
28. + buffer but this complex is stable enough in this medium (several hours) to be electrochemically studied.