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0342278073
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note
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4OH was added to deprotect the thiol endgroup. TEM grids were prepared by first diluting the solution of linked gold or silver particles by 20-fold. One drop of the solution was then placed on a Formvar-coated Cu grid in contact with filter paper. The solvent was quickly wicked away by the filter paper, preventing particle agglomeration.
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0343583247
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note
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In discrete dipole calculations, each particle is divided into a large number of dipoles. An average particle polarization is then calculated which includes electric field contributions from the incident light and dipoles on the neighboring particle. Importantly, these calculations assume that the incident electric field is polarized along the long axis of the particle pair structure. Thus, only longitudinal plasmon modes are apparent in calculated extinction spectra.
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21
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0342278068
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note
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d structures.
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22
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0343583246
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note
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3h symmetry. (Vance, F. W.; Novak, J. P.; Johnson, R. C.; Hupp, J. T.; Feldheim, D. L., unpublished results).
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23
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0342278061
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note
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(aq) revealed a gradual disappearance in absorbance at 420 nm with a concommitent increase at 800 nm characteristic of extended particle aggregates.
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24
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33748590820
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