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HRS arises from an instantaneous anisotropy that breaks the centrosymmetry present in an otherwise homogeneous solution.
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18
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11744288353
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note
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The orientation information present in SHG is also lost in an HRS experiment, where orientational averaging allows only for the reporting of the average symmetry of individual (noninteracting) chromophores.
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11744284546
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Polarization experiments (Figure 1 inset) also revel a dramatic difference between gold and silica colloids, where the ratio of vertically to horizontally scattered light for gold was found to be 2.2 ± 0.2 vs 22 ± 3 for silica (ref 19).
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27
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11744351965
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note
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The enhancement mechanism could be similar to that previously observed for hyper-Raman scattering experiments (refs 28 and 29), but differences in experimental conditions and parameters make a direct comparison difficult.
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28
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22844442386
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11744280662
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note
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12 is the change in dipole moment between ground and excited states.
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32
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0001393783
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11744273337
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note
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-30 esu.
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