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The electrolyte suppresses the electrostatic repulsion between the particles and leads to coagulation. The adverse effect of electrolyte was shown by adding 0.05 M NaCl to the initial particle suspension, which disrupted the ordering and eventually led to breakdown of the assembled particles. Conversely, the quality of the ordered array improved if a sound/ ultrasound treatment was applied during the assembly process through a piezoelectric transducer attached to the bottom of the Petri dish. The application of a square wave of 11-kHz frequency noticeably improved the ordering of the microspheres both throughout the particle bulk and on the surface. However, this was also accompanied by an overall shape deformation in the area of contact with the Teflon wall.
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Hydrophilic-hydrocarbon surfactants are active at the air-water interface, ones with hydrophilic-fluorocarbon chains are active at the water-fluorinated oil interface, and hydrocarbon-fluorocarbon ones are active exclusively at the air-fluorinated oil interface (18).
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Supplementary material is available at www. sciencemag.org/feature/data/1047430.shl.
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We are grateful to N. L. Abbott and R. F. Lobo for useful discussions
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We are grateful to N. L. Abbott and R. F. Lobo for useful discussions.
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