Synthesis, characterization, and reactivity of chromium boratabenzene complexes

Organometallics

Volumn 19, Issue 19, 2000, Pages 3948-3956

  Rogers, Jonathan S ^a   Bu, Xianhui ^a   Bazan, Guillermo C ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CHROMIUM COMPOUNDS; COMPLEXATION; COMPOSITION EFFECTS; NITROGEN COMPOUNDS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

CHROMIUM BORATABENZENE; PYRIDINE;

ORGANOMETALLICS;

EID: 0034683310     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0003685     Document Type: Article

References (46)

1. Parshall, G. W.; Ittel, S. D., Homogeneous Catalysis, 2nd ed.; Wiley: New York, 1992.
2. Clark, A.; Hogan, J. P., Banks, R. L.; Lanning, W. C. Ind. Eng. Chem. 1956, 48, 1152.
3. Karol, F. J.; Karapinka, G. L.; Wu, C.; Dow, A. W.; Johnson, R. N.; Carrick, W. L. J. Polym. Sci. A 1972, 10, 2621.
4. (a) Theopold, K. H. CHEMTECH 1997, 26, and references therein.
5. (b) Thomas, B. J.; Noh, S. N.; Schulte, G. K.; Sendlinger, S. C.; Theopold, K. H. J. Am. Chem. Soc. 1991, 113, 893.
6. (a) Kim, W.; Fevola, M. J.; Liable-Sands, L. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1998, 17, 4541.
7. (b) Dohring, A.; Gohre, J.; Jolly, P. W.; Kryger, B.; Rust, J.; Verhovnik, G. P. J. Organometallics 2000, 19, 388.
8. Rogers, J. S.; Bu, X.; Bazan, G. C. J. Am. Chem. Soc. 2000, 122, 730.
9. (a) Bazan, G. C.; Rodriguez, G.; Ashe, A. J., III.; Al-Ahmad, S.; Müller, C. J. Am. Chem. Soc. 1996, 118, 2291.
10. (b) Bazan, G. C.; Rodriguez, G.; Ashe, A. J., III.; Al-Ahmad, S.; Kampf, J. W. Organometallics 1997, 16, 2492.
11. (c) Rogers, J. S.; Bazan, G. C.; Sperry, C. K. J. Am. Chem. Soc. 1997, 119, 9305.
12. (d) Barnhart, R. W.; Bazan, G. C.; Mourey, T. J. Am. Chem. Soc. 1998, 120, 1082.
13. (e) Rogers, J. S.; Lachicotte, R. J.; Bazan, G. C. J. Am. Chem. Soc. 1999, 121, 1288.
14. (a) Boese, R.; Finke, N.; Henkelmann, J.; Maier, G.; Paetzold, P.; Reisenauer, H. P.; Schmid, G. Chem. Ber. 1985, 118, 1644.
15. (b) Hoic, D. A.; Wolf, J. R.; Davis, W. M.; Fu, G. C. Organometallics 1996, 15, 1315.
16. Herwig, W.; Zeiss, H. H. J. Am. Chem. Soc. 1957, 79, 6561.
17. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
18. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
19. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
20. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
21. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
22. For reviews of group 4 polymerization catalysts, see: (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. (b) Transition Metals and Organometallics as Catalysts for Olefin Polymerization; Kaminsky, W., Sinn, H., Eds.; Springer-Verlag: Berlin, 1988. (c) Ziegler Catalysts; Fink, G., Mülhaupt, R., Brintzinger, H. H., Eds.; Springer-Verlag: Berlin, 1995. (d) Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: New York, 1998. (e) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 429. (f) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 3, 255.
23. Ashe, A. J., III.; Al-Ahmad, S.; Fang, X. G. J. Organomet. Chem. 1999, 581, 92 and references therein.
24. Richeson, D. S.; Mitchell, J. F.; Theopold, K. H. Organometallics 1989, 8, 2570.
25. Herberich, G. E.; Koch, W. Chem. Ber. 1977, 110, 816.
26. (a) Flower, K. R.; Hitchcock, P. B. J. Organomet. Chem. 1996, 507, 275.
27. (b) Blumel, J.; Herker, M.; Hiller, W.; Kohler, F. H. Organometallics 1996, 15, 3474.
28. Ashe, A. J., III; Al-Ahmad, S.; Kampf, J. W.; Young, V. G. Angew. Chem., Int. Ed. Engl. 1997, 36, 2014.
29. Herberich, G. H.; Ohst, H. Adv. Organomet. Chem. 1986, 25, 199
30. Sperry, C. K.; Bazan, G. C.; Cotter, W. D. J. Am. Chem. Soc. 1999, 121, 1513.
31. Bazan, G. C.; Cotter, W. D.; Komon, Z. J. A.; Lee, R. A.; Lachicotte, R. J. J. Am. Chem. Soc. 2000, 122, 1371.
32. Bazan, G. C.; Rodriguez, G.; Ashe, A. J., III; Al-Ahmad, S.; Müller, C. J. Am. Chem. Soc. 1996, 118, 2291.
33. (a) Ashe, A. J., III; Kampf, J. W.; Müller, C.; Schneider, M. Organometallics 1996, 15, 387.
34. (b) Ashe, A. J., III; Kampf, J. W.; Wass, J. R. Organometallics 1997, 16, 163.
35. (c) See also ref 12.
36. Nishimura, K.; Kuribayashi, H.; Yamamoto, A.; Ikeda, S. J. Organomet. Chem. 1972, 37, 317.
37. Putzer, M. A.; Rogers, J. S.; Bazan, G. C. J. Am. Chem. Soc. 1999, 121, 8112.
38. Richeson, D. S.; Hsu, S.; Fredd, N. H.; Van Duyne, G.;Theopold, K. H. J. Am. Chem. Soc. 1986, 108, 8273.
39. Chien, J. C.; Tsai, W.; Rausch, M. D. J. Am. Chem. Soc. 1991, 113, 8570.
40. Rogers, J. S.; Bazan, G. C. Chem. Commun. 2000, 1209.
41. Noh, S. K.; Sendlinger, S. C.; Janiak, C.; Theopold, K. H. J. Am. Chem. Soc. 1989, 111, 9127.
42. Chain transfer to aluminum also occurs with iron-based catalysts; see: Britovsek, G. J. P.; Bruce, M.; Gibson, V. C.; Kimberley, B. S.; Maddox, P. J.; Mastroianni, S.; McTavish, S. J.; Redshaw, C.; Solan, G. A.; Strömberg, S.; White, A. J. P.; Williams, D. J. J. Am. Chem. Soc. 1999, 121, 8728.
43. Burger, B. J.; Bercaw, J. E. In Experimental Organometallic Chemistry; Wayda, A. L., Darensbourg, M. Y., Eds.; ACS Symposium Series 357; American Chemical Society: Washington, DC, 1987.
44. Herwig, W.; Zeiss, H. H. J. Org. Chem. 1968, 23, 1404.
45. Qiao, S.; Hoic, D. A.; Fu, G. C. J. Am. Chem. Soc. 1998, 118, 2291.
46. Massey, A. G.; Park, A. J. J. Organomet. Chem. 1964, 2, 245.