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Volumn 121, Issue 6, 1999, Pages 1288-1298

Alkoxy- and aryloxyboratabenzene complexes of zirconium

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALKADIENE; ALKENE; BENZENE DERIVATIVE; ETHYLENE; LITHIUM DERIVATIVE; MONOMER; POLYETHYLENE; ZIRCONIUM;

EID: 0033576993     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja983270e     Document Type: Article
Times cited : (50)

References (56)
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    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford
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    • Herberich, G.E.1
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    • note
    • 14 See also ref 13 for discussions of B-N bond rotational barriers in aminoboratabenzene ligands.
  • 24
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    • Useful discussion can be found in: Collins, S. Organometallics 1991, 10, 2349.
    • (1991) Organometallics , vol.10 , pp. 2349
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    • Abel, E. W., Stone, F. G. A., Wilkinson, G. W., Eds.; Pergamon: New York
    • Ryan, E. J. in Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G. W., Eds.; Pergamon: New York, 1995.
    • (1995) Comprehensive Organometallic Chemistry
    • Ryan, E.J.1
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    • note
    • 2 and EtOH.
  • 35
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    • Hegedus, L. S., Ed.; Pergamon: Oxford
    • For recent reviews on the use of metallocene complexes in the development of organic reactions, see: (a) Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12. (b) Buchwald, S. L.; Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12
    • Broene, R.D.1
  • 36
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    • For recent reviews on the use of metallocene complexes in the development of organic reactions, see: (a) Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12. (b) Buchwald, S. L.; Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12
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    • 0001046188 scopus 로고
    • The SHOP process circumvents this problem by allowing the 1-alkenes to diffuse into a phase in which the concentration of catalyst is much reduced. For aluminum reactions, a high concentration of ethylene discourages insertion of 1-alkenes into Al-H or Al-C bonds. For a detailed description of the SHOP process, see ref 1c and (a) Peuckert, M.; Keim, W. Organometallics 1983, 2, 594. (b) Keim, W.; Schulz, R. P. J. Mol. Catal. 1994, 92, 21.
    • (1983) Organometallics , vol.2 , pp. 594
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    • The SHOP process circumvents this problem by allowing the 1-alkenes to diffuse into a phase in which the concentration of catalyst is much reduced. For aluminum reactions, a high concentration of ethylene discourages insertion of 1-alkenes into Al-H or Al-C bonds. For a detailed description of the SHOP process, see ref 1c and (a) Peuckert, M.; Keim, W. Organometallics 1983, 2, 594. (b) Keim, W.; Schulz, R. P. J. Mol. Catal. 1994, 92, 21.
    • (1994) J. Mol. Catal. , vol.92 , pp. 21
    • Keim, W.1    Schulz, R.P.2
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    • There is no change in the catalytic properties of 10/500 MAO when two equivalents of ethanol are added
    • There is no change in the catalytic properties of 10/500 MAO when two equivalents of ethanol are added.
  • 51
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    • Experimental Organometallic Chemistry; Wayda, A. L., Darensbourg, M. Y. Eds.; American Chemical Society: Washington DC
    • Burger, B. J.; Bercaw, J. E. In Experimental Organometallic Chemistry; Wayda, A. L., Darensbourg, M. Y. Eds.; ACS Symposium Series 357; American Chemical Society: Washington DC, 1987.
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    • Burger, B.J.1    Bercaw, J.E.2
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    • note
    • It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, because systematic error is not included. More reasonable errors might be estimated at 10x the listed value. It should be noted that the SAINT program could not improve the original cell produced by SMART for 11, and hence the final unit cell is based upon only 168 reflections.


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