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14 See also ref 13 for discussions of B-N bond rotational barriers in aminoboratabenzene ligands.
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34
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2 in: Herberich, G. E.; Englert, U.; Schmitz, A. Organometallics 1997, 16, 3751.
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For recent reviews on the use of metallocene complexes in the development of organic reactions, see: (a) Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12. (b) Buchwald, S. L.; Broene, R. D. In Comprehensive Organometallic Chemistry II; Hegedus, L. S., Ed.; Pergamon: Oxford, 1995; Vol. 12.
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The SHOP process circumvents this problem by allowing the 1-alkenes to diffuse into a phase in which the concentration of catalyst is much reduced. For aluminum reactions, a high concentration of ethylene discourages insertion of 1-alkenes into Al-H or Al-C bonds. For a detailed description of the SHOP process, see ref 1c and (a) Peuckert, M.; Keim, W. Organometallics 1983, 2, 594. (b) Keim, W.; Schulz, R. P. J. Mol. Catal. 1994, 92, 21.
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The SHOP process circumvents this problem by allowing the 1-alkenes to diffuse into a phase in which the concentration of catalyst is much reduced. For aluminum reactions, a high concentration of ethylene discourages insertion of 1-alkenes into Al-H or Al-C bonds. For a detailed description of the SHOP process, see ref 1c and (a) Peuckert, M.; Keim, W. Organometallics 1983, 2, 594. (b) Keim, W.; Schulz, R. P. J. Mol. Catal. 1994, 92, 21.
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0344518123
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There is no change in the catalytic properties of 10/500 MAO when two equivalents of ethanol are added
-
There is no change in the catalytic properties of 10/500 MAO when two equivalents of ethanol are added.
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0344518109
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note
-
It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, because systematic error is not included. More reasonable errors might be estimated at 10x the listed value. It should be noted that the SAINT program could not improve the original cell produced by SMART for 11, and hence the final unit cell is based upon only 168 reflections.
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