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Volumn 6, Issue 4, 2000, Pages 725-734

Oriented crystalline monolayers and bilayers of 2 x 2 silver(I) grid architectures at the air-solution interface: Their assembly and crystal structure elucidation

Author keywords

N ligands; Self assembly; Silver; Structure elucidation; Supramolecular chemistry thin films

Indexed keywords

PYRIDAZINE DERIVATIVE; SILVER;

EID: 0034681538     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(20000218)6:4<725::AID-CHEM725>3.0.CO;2-E     Document Type: Article
Times cited : (54)

References (30)
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    • note
    • The C(1s) line measured for the grid bulk was fitted with the same four components to which a fifth component was added in order to consider the contribution of the tape used to glue the powder on the holder (not shown).
  • 20
    • 12944252634 scopus 로고    scopus 로고
    • note
    • Note that the observed reflectivity curve did not change after compression of the film which induced a transition to the crystalline bilayer, as determined from the GIXD measurements on the same sample, and repeated several times.
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    • note
    • In terms of the molecular dimensions of 1, the unit cell may contain two molecules oriented with the molecular plane parallel to the airwater interface (see ref. [14]). The d spacing of 5.5 Å may correspond to the stacking of the molecules.
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    • note
    • 1/2 = constant; this denotes random orientation with respect to the surface. We assign these peaks as belonging to microcrystals of AgCl, since, in accordance to the Inorganic Powder Diffraction File, they correspond to the (111), (200), and (220) reflections of AgCl with d spacings of 3.20 Å, 2.77 Å, and 1.96 Å, respectively. We account for the presence of these three peaks in various systems by formation of AgCl due to the presence of traces of Cl ions in the ligand compound.
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    • The atomic coordinates of the crystal structure reported by M.-T. Youinou, N. Rahmouni, J. Fischer, J. A. Osborn, Angew. Chem. 1992, 104, 771; Angew. Chem. Int. Ed. Engl. 1992, 31, 733, were used as a basis for the model.
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    • Youinou, M.-T.1    Rahmouni, N.2    Fischer, J.3    Osborn, J.A.4
  • 24
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    • The atomic coordinates of the crystal structure reported by M.-T. Youinou, N. Rahmouni, J. Fischer, J. A. Osborn, Angew. Chem. 1992, 104, 771; Angew. Chem. Int. Ed. Engl. 1992, 31, 733, were used as a basis for the model.
    • (1992) Angew. Chem. Int. Ed. Engl. , vol.31 , pp. 733
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    • note
    • 2.
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    • 2, molecular modeling software for materials research from BIOSYM/Molecular Simulations, San Diego CA (USA) and Cambridge (UK).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.