Oriented crystalline thin films of tetracosanedioic acid and its metal salts at the air-aqueous solution interface

Advanced Materials

Volumn 10, Issue 2, 1998, Pages 117-121

  Weissbuch, Isabelle ^a   Guo, Shouwa ^a   Edgar, Ron ^a   Cohen, Sidney ^a   Howes, Paul ^b   Kjaer, Kristian ^b   Als Nielsen, Jens ^c   Lahav, Meir ^a   Leiserowitz, Leslie ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; CADMIUM; COMPOSITION EFFECTS; CRYSTAL ORIENTATION; LEAD; MICA; MOLECULAR ORIENTATION; MULTILAYERS; PHASE INTERFACES; SALTS; THIN FILMS;

TETRACOSANEDIOIC ACID;

CRYSTALLINE MATERIALS;

EID: 0031647154     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-4095(199801)10:2<117::AID-ADMA117>3.0.CO;2-M     Document Type: Article

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23. -1.
24. 2+ salt a = 6.73 Å, b = 33.36 Å, c = 5.92 Å, α = γ = 90°, and β= 98.3°.
25. Placing the two independent molecules at coordinates (0.0) and (0.5,0.5) or (0,0) and (0.0.5) would yield zero intensity for the (100) or (100) reflections, respectively. The interchain distances between the nearest neighbors for the three possible positions of the second molecule (i.e., 0.5,0.5; 0.0.5; and 0.25,0.5) are in the same range.
26. 2 aqueous solution.
27. 2) divided by 0.334 - the electron density of water. With a film thickness of 56 Å, the known number of spread molecules corresponds to a coverage of about 33 %.