Self-assembly at the air-water interface. In-situ preparation of thin films of metal ion grid architectures

Journal of the American Chemical Society

Volumn 120, Issue 19, 1998, Pages 4850-4860

  Weissbuch, Isabelle ^a   Baxter, Paul N W ^d   Cohen, Sidney ^a   Cohen, Hagai ^a   Kjaer, Kristian ^b   Howes, Paul B ^b   Als Nielsen, Jens ^c   Hanan, Gary S ^d   Schubert, Ulrich S ^d   Lehn, Jean Marie ^d   Leiserowitz, Leslie ^a   Lahav, Meir ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

^d UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL ORIENTATION; INTERFACES (MATERIALS); IONS; MOLECULAR DYNAMICS; THIN FILMS; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

AIR WATER INTERFACE; GRAZING INCIDENCE SYNCHROTRON X RAY DIFFRACTION; SCANNING FORCE MICROSCOPY; SPECULAR X RAY REFLECTIVITY MEASUREMENT;

FILM PREPARATION;

METAL ION; WATER;

AIR; AQUEOUS SOLUTION; ARTICLE; MOLECULAR INTERACTION; PHASE TRANSITION; SCANNING FORCE MICROSCOPY; SYNCHROTRON; X RAY DIFFRACTION;

EID: 0032550684     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja980205w     Document Type: Article

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20. 3 solution do not show any increase in surface pressure.
21. We were not able to make quantitative measurement of the absorption coefficients. Nevertheless, the SFM images show a homogeneous distribution of the crystallites on the solid support.
22. Frames of 5 mm size covered only with ∼5 Å domains were also observed.
23. 3Ag clearly show the residual free ligand; unpublished results.
24. z is the distance between the intensity modulations.
25. 2, Molecular Modeling Software for materials research from BIOSYM/Molecular Simulations Inc., San Diego, CA and Cambridge, UK.
26. 4 on the water surface whose long molecular axis is vertical or slightly tilted from the normal to the water surface.
27. Note that Scheme 2 depicts packing arrangements showing two layers given by empty and patterned molecules: (a) the 3-D crystal structure, where molecules 1 and 2 are related by center of inversion, 1 and 3 by 2-fold screw symmetry about an axis perpendicular to the ab plane, and 1 and 4 by an n-glide parallel to the ab plane;
28. (b) the proposed bilayer structure at the air - solution interface, where molecules of type 1 and of type 3 are each related by translation, and molecules 1 and 3 by 2-fold screw symmetry.
29. - ions in the compounds which were spread.