Large free volume in maximally interpenetrating networks: The role of secondary building units exemplified by TB2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]

Journal of the American Chemical Society

Volumn 122, Issue 19, 2000, Pages 4843-4844

  Reineke, Theresa M ^a   Eddaoudi, Mohamed ^a   Moler, David ^a   O'Keeffe, M ^b   Yaghi, O M ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

^b ARIZONA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIMETHYL SULFOXIDE; ORGANOMETALLIC COMPOUND;

ARTICLE; CRYSTAL STRUCTURE; POLYMERIZATION; POROSITY; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0034679054     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000363z     Document Type: Article

References (43)

1. (a) Free volume refers to space unoccupied by the metal-organic frameworks.
2. 2.
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31. 3 respectively, which is due to disorder in the S and C atoms of DMSO.
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36. Van der Waals radii of C (1.7 Å), O (1.4 Å), and H (1.1 Å) were used in the calculation of (a) pore dimensions, (b) percent volume occupied by the frameworks (CERIUS program was used, where crevices of less than 1 Å diameter were not included as free volume), and (c) SBU axial and equatorial lengths.
37. 3: C, 35.95; H, 2.40; N, 5.13; S, 3.92. Found: C, 35.00; H, 2.55; N, 5.10; S, 4.03.
38. 20: C, 46.92; H, 6.44; N, 13.68; S, 1.20. Found: C, 46.93; H, 6.17; N, 13.37; S, 1.14.
39. 2/g. These observations coupled to the clean weight loss obtained in the TG experiment point to a flexible evacuated framework, perhaps due to the flexible nature of ADB.
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43. Assuming that the octahedron approximates a sphere with d being the longest C⋯C distance (9.65 Å) in the SBU and l is the distance between the carboxylate C atoms (11.88 Å) within an ADB linker.