The absolute configuration and asymmetric total synthesis of the CP molecules (CP-263,114 and CP-225,917, phomoidrides B and A)

Angewandte Chemie - International Edition

Volumn 39, Issue 10, 2000, Pages 1829-1832

  Nicolaou, K C ^a,b   Jung, Jae Kyu ^a   Yoon, Won Hyung ^a   He, Yun ^a   Zhong, Yong Li ^a   Baran, Phil S ^a  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Asymmetric synthesis; Configuration determination; Natural products; Polycycles; Total synthesis

Indexed keywords

ALDEHYDE; ORGANIC COMPOUND; PHOMOIDRIDE A; PHOMOIDRIDE B; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CIRCULAR DICHROISM; DIASTEREOISOMER; ENANTIOMER; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0034658143     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000515)39:10<1829::AID-ANIE1829>3.0.CO;2-6     Document Type: Article

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46. 2, in aqueous methanol (71 %).
47. 2, 25 C.
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49. A similar effect was observed for (-)-16 and (+)-16.