Kinetic influences on enantioselectivity for non-diastereopure catalyst mixtures

Angewandte Chemie - International Edition

Volumn 38, Issue 15, 1999, Pages 2196-2199

  Blackmond, Donna G ^a,b   Rosner, Thorsten ^a   Neugebauer, Torsten ^a   Reetz, Manfred T ^a  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^b UNIVERSITY OF HULL   (United Kingdom)

Author keywords

Asymmetric catalysis; Asymmetric synthesis; Hydrogenations; Rhodium

Indexed keywords

RHODIUM;

ARTICLE; CATALYSIS; CATALYST; DIASTEREOISOMER; HYDROGENATION; REACTION ANALYSIS;

EID: 0033516889     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990802)38:15<2196::AID-ANIE2196>3.0.CO;2-9     Document Type: Article

References (19)

1. a) D. Guillaneux, S. H. Zhao, O. Samuel, D. Rainford, H. B. Kagan, J. Am. Chem. Soc. 1994, 116, 9430;
2. b) C. Puchot, O. Samuel, E. Duñach, S. H. Zhao, C. Agami, H. B. Kagan, J. Am. Chem. Soc. 1986, 108, 2353.
3. Recent review: C. Girard, H. B. Kagan, Angew. Chem. 1998, 110, 3088; Angew. Chem. Int. Ed. 1998, 37, 2922.
4. Recent review: C. Girard, H. B. Kagan, Angew. Chem. 1998, 110, 3088; Angew. Chem. Int. Ed. 1998, 37, 2922.
5. M. Zhao, A. O. King, R. D. Larsen, T. R. Verhoeven, P. J. Reider, Tetrahedron Lett. 1997, 38, 2641-2644.
6. S. Y. Zhang, C. Girard, H. B. Kagan, Tetrahedron: Asymmetry 1995, 6, 2637.
7. a) D. G. Blackmond, J. Am. Chem. Soc. 1997, 119, 12934;
8. b) D. G. Blackmond, J. Am. Chem. Soc. 1998, 120, 13349.
9. W. S. Knowles, Acc. Chem. Res. 1983, 16, 106.
10. a) H. B. Kagan in Asymmetric Synthesis, Vol. 5 (Ed: J. D. Morrison), Academic Press, New York, 1985, chap. 1;
11. b) J. Halpern in ref. [7a], chap. 2;
12. R. Noyori, Asymmetric Catalysis in Organic Synthesis, Wiley-Interscience, New York, 1994.
13. a) T. Neugebauer, Dissertation, Ruhr-Universität Bochum, 1998 (ISBN 3-89653-451-3);
14. b) M. T. Reetz, T. Neugebauer, Angew. Chem. 1999, 111, 134; Angew. Chem. Int. Ed. 1999, 38, 179.
15. b) M. T. Reetz, T. Neugebauer, Angew. Chem. 1999, 111, 134; Angew. Chem. Int. Ed. 1999, 38, 179.
16. D. Heller, J. Holz, S. Borns, A. Spannenberg, R. Kempe, U. Schmidt, A. Börner, Tetrahedron: Asymmetry 1997, 8, 213.
17. Examples of homogeneous and heterogeneous catalytic reactions where a conversion-dependent enantioselectivity has been used to derive mechanistic insight are found in; a) D. P. Heller, D. R. Goldberg, W. D. Wulff, J. Am. Chem. Soc. 1997, 119, 10551;
18. b) S. E. Denmark, S. P. O'Connor, J. Org. Chem. 1997, 62, 3390;
19. c) J. Wang, Y. Sun, C. LeBlond, R. N. Landau, D. G. Blackmond, J. Catal. 1996, 161, 752.