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The stereoselectivity of the aminophosphine borane acidolysis depends on the substrate and on the HCl concentration: Moulin, D. PhD thesis University of Cergy-Pontoise, 1999.
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57
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0007233113
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The pentacoordinate isomers are denoted by their apical substituents. When the upper substituent is facing the lower, the notation of the stereoisomer is surmounted by a bar, if the equatorial substituents are in counter-clockwise position: Muetterties, E. L. J. Am. Chem. Soc. 1969, 91, 1636-1643.
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For the concept of relative stereoapicophilicity, see: Uziel, J.; Stephan, M., El Bachir Kaloun, Genet, J. P.; Juge, S. Bull. Soc. Chim. Fr. 1997, 134, 379-389.
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For decomplexation of phosphinite boranes with dabco, see Ref. 13 and references cited therein.
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