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Volumn 39, Issue 3, 2000, Pages 495-499

How long have nonlinear effects been known in the field of catalysis?

Author keywords

Asymmetric amplification; Asymmetric catalysis; Chirality; Nonlinear effects

Indexed keywords

AMINOALCOHOL; BENZALDEHYDE; DIETHYLZINC; ESTER DERIVATIVE; OXALIC ACID DERIVATIVE;

EID: 0034603008     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000204)39:3<495::AID-ANIE495>3.0.CO;2-G     Document Type: Review
Times cited : (55)

References (43)
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    • The term "nonlinear effect" is somewhat unfortunate, as other correlations such as the product selectivity as a function of the optical purity of a catalyst are also nonlinear. An example is the dependence of the logarithmic product ratio of selective reactions as a function of the reciprocal temperature (isoinversion principle): a) H. Buschmann, H.-D. Scharf, N. Hoffmann, P. Esser, Angew. Chem. 1991, 103, 480- 515: Angew. Chem. Int. Ed. Engl. 1991, 30, 477-515. b) D. Heller, H. Buschmann, Top. Catal. 1998, 5, 159-176. This nonlinear temperature dependence - the first work was carried out by Pracejus (H. Pracejus. Justus Liebigs Ann. Chem. 1960, 634, 9-22) - should be typical for all reactions displaying nonlinear effects in the "Kaganian" sense. The product enantiomers result from various reaction pathways.
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    • The term "nonlinear effect" is somewhat unfortunate, as other correlations such as the product selectivity as a function of the optical purity of a catalyst are also nonlinear. An example is the dependence of the logarithmic product ratio of selective reactions as a function of the reciprocal temperature (isoinversion principle): a) H. Buschmann, H.-D. Scharf, N. Hoffmann, P. Esser, Angew. Chem. 1991, 103, 480- 515: Angew. Chem. Int. Ed. Engl. 1991, 30, 477-515. b) D. Heller, H. Buschmann, Top. Catal. 1998, 5, 159-176. This nonlinear temperature dependence - the first work was carried out by Pracejus (H. Pracejus. Justus Liebigs Ann. Chem. 1960, 634, 9-22) - should be typical for all reactions displaying nonlinear effects in the "Kaganian" sense. The product enantiomers result from various reaction pathways.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.