Separation of an enantiomorph and its racemate by distillation: strong chiral recognizing ability of trifluorolactates

Chemistry Letters

Volumn , Issue 2, 1996, Pages 115-116

  Katagiri, Toshimasa ^a,c   Yoda, Chika ^a   Furuhashi, Keizo ^a   Ueki, Katsuyuki ^b   Kubota, Toshio ^b  

^a JAPAN ENERGY CORPORATION   (Japan)

^b IBARAKI UNIVERSITY   (Japan)

^c OKAYAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030558966     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.115     Document Type: Article

References (5)

1. J. Jacques, A. Collet, and S. H. Wilen, in "Enantiomers, Racemates, and Resolutions" John Wiley & Sons, New York (1981), p165-166.
2. T. Katagiri, F. Obara, S. Toda, and K. Furuhashi, SYNLETT, 1994, 507.
3. The trifluoropropeneoxideis commercially available from Japan Energy; K. Furuhashi, in "Chirality in Industry," ed by A. N. Collins, G. N. Sheldreke, and J. Crosby, John Wiley & Sons, New York (1992), p 167.
4. T. Kubola, K. Ueki, T. Katagiri, and K. Furuhashi, (Japan Energy Corp.), Japan Kokai, JP 6-256227 (1994).
5. The enantiomeric excess of these compounds was determined by gas chromatography using a CP-Cyclodex β 236M column (GL Science). V. Shurig and HP. Nowotny, Angew. Chem., Int. Ed. Engl., 29, 939 (1990).