Resorcarene-based nanoarchitectures: Metal- directed assembly of a molecular loop and tetrahedron

Angewandte Chemie - International Edition

Volumn 39, Issue 1, 2000, Pages 136-140

  O Danny, Fox ^a   Drew, Michael G B ^b   Paul, D Beer ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b UNIVERSITY OF READING   (United Kingdom)

Author keywords

Copper; Nanostructures; Resorcarenes; Self assembly; Zinc

Indexed keywords

AMINE; CARBAMIC ACID; COPPER; COPPER COMPLEX; ZINC;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0034598521     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (43)

1. a) T. Douglas, M. Young, Nature 1998, 393, 152-155;
2. b) D. J. Cram, M. E. Tanner, R. Thomas, Angew. Chem. 1991, 103, 1048-1051; Angew. Chem. Int. Ed. Engl. 1991, 30, 1024-1027.
3. b) D. J. Cram, M. E. Tanner, R. Thomas, Angew. Chem. 1991, 103, 1048-1051; Angew. Chem. Int. Ed. Engl. 1991, 30, 1024-1027.
4. Recent reviews: a) R. W. Saalfrank, B. Demleitner in Transition Metals in Supramolecular; Perspectives in Supramolecular Chemistry (Ed.: J. P. Sauvage). Wiley-VCH, Weinheim, 1999, 5, 1-51;
5. b) R. W. Saalfrank, I. Bernt, Curr. Opin. Solid State Mater. Sci. 1998, 3, 407-413;
6. c) M. Fujita, Chem. Soc. Rev. 1998, 27, 417-425;
7. d) C. J. Jones, Chem. Soc. Rev. 1998, 27, 289-299;
8. e) B. Linton, A. D. Hamilton, Chem. Rev. 1997, 97, 1669-1680;
9. f) P. N. W. Baxter in Comprehensive Supramolecular Chemistry, Vol. 9 (Eds.: J. P. Sauvage, M. W. Hosseini), Pergamon, Oxford, 1996, 165-211.
10. M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura, Nature 1995, 378, 469-471.
11. D. J. Cram, M. J. Cram in Container Molecules and Their Guests, Monographs in Supramolecular Chemistry (Ed.: J. F. Stoddart), The Royal Society of Chemistry, Cambridge, 1994, and references therein.
12. D. M. Roundhill, Prog. Inorg. Chem. 1995, 43, 533-592.
13. M. M. Conn, J. Rebek, Jr., Chem. Rev. 1997, 97, 1647-1668, and references therein.
14. E. R. MacGillivray, J. L. Atwood, Nature 1997, 389, 469-472.
15. a) E. Dalcanale, P. Jacopozzi, Angew. Chem. 1997, 109, 665-667; Angew. Chem. Int. Ed. Engl. 1997, 36, 613-615;
16. a) E. Dalcanale, P. Jacopozzi, Angew. Chem. 1997, 109, 665-667; Angew. Chem. Int. Ed. Engl. 1997, 36, 613-615;
17. b) K. Fujimoto, S. Shinkai, Tetrahedron Lett. 1994, 35, 2915-2918.
18. O. D. Fox, N. K. Dalley, R. G. Harrison, J. Am. Chem. Soc. 1998, 120, 7111-7112.
19. D. Coucouvanis, Prog. Inorg. Chem. 1979, 26, 301-469.
20. Recent examples of triangular based complexes: a) J. R. Hall, S. J. Loeb, G. K. H. Shimizu, G. P. A. Yap, Angew. Chem. 1998, 110, 130-133; Angew. Chem. Int. Ed. 1998, 37, 121-123;
21. Recent examples of triangular based complexes: a) J. R. Hall, S. J. Loeb, G. K. H. Shimizu, G. P. A. Yap, Angew. Chem. 1998, 110, 130-133; Angew. Chem. Int. Ed. 1998, 37, 121-123;
22. b) R. D. Schenbeck, L. Randacio, E. Zangrando, B. Lippert, Angew. Chem. 1998, 110, 128-130; Angew. Chem. Int. Ed. 1998, 37, 119-121;
23. b) R. D. Schenbeck, L. Randacio, E. Zangrando, B. Lippert, Angew. Chem. 1998, 110, 128-130; Angew. Chem. Int. Ed. 1998, 37, 119-121;
24. c) D. Whang, K. M. Park, J. Heo, P. Ashton, K. Kim, J. Am. Chem. Soc. 1998, 120, 4899-4900.
25. The triangle is defined by three carbon atoms situated at the base of the resorc|4|arene ligand (C28a, C28b, and C28e).
26. Q. J. McCubbin, F. J. Stoddart, T. Welton, A. J. P. White, D. J. Williams, Inorg. Chem. 1998, 37, 3753-3758.
27. To date, we have been unsuccessful in our attempts to obtain crystals of 3 suitable for an X-ray structure determination.
28. a) D. L. Caulder, K. N. Raymond, J. Chem. Soc. Dalton Trans. 1999, 1185-1200, and references therein;
29. b) C. Bruckner, R. E. Powers, K. N. Raymond, Angew. Chem. 1998, 110, 1937-1940; Angew. Chem. Int. Ed. 1998, 37, 1837-1839;
30. b) C. Bruckner, R. E. Powers, K. N. Raymond, Angew. Chem. 1998, 110, 1937-1940; Angew. Chem. Int. Ed. 1998, 37, 1837-1839;
31. c) J. S. Fleming, K. L. V. Mann, C. A. Carraz, E. Psillakis, J. C. Jeffery, J. A. McCleverty, M. D. Ward, Angew. Chem. 1998, 110, 1315-1318; Angew. Chem. Int. Ed. 1998, 37, 1279-1281;
32. c) J. S. Fleming, K. L. V. Mann, C. A. Carraz, E. Psillakis, J. C. Jeffery, J. A. McCleverty, M. D. Ward, Angew. Chem. 1998, 110, 1315-1318; Angew. Chem. Int. Ed. 1998, 37, 1279-1281;
33. d) R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Muther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
34. d) R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Muther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
35. a) J. G. Wijnhoven, T. E. M. van den Hark, P. T. Beurskens, J. Cryst. Mol. Struct. 1972, 2, 189-196;
36. b) G. M. Larin, G. A. Zvereva, P. A. Kozmin, T. B. Larina, M. D. Svrazhskaya, Izv. Akad. Nauk SSSR Neorg. Mater. 1984, 20, 530-533; Inorganic Materials (Engl. Transl.) 1984, 20, 451.
37. b) G. M. Larin, G. A. Zvereva, P. A. Kozmin, T. B. Larina, M. D. Svrazhskaya, Izv. Akad. Nauk SSSR Neorg. Mater. 1984, 20, 530-533; Inorganic Materials (Engl. Transl.) 1984, 20, 451.
38. R. M. Golding, C. M. Harris, K. J. Jessop, W. C. Tennant, Aust. J. Chem. 1972, 25, 2567-2576.
39. H. Boerrigter, W. Verboom, D. N. Reinhoudt, J. Org Chem. 1997, 62, 7148-7155.
40. W. Kabsch, J. Appl. Crystallogr. 1988, 21 916.
41. SHELXL, Program for Crystal Structure Refinement, G. M. Sheldrick, Universität Göttingen, 1997.
42. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-133532 (2) and CCDC-133533 (4). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ ccdc.cam.ac.uk).
43. +: 1595.23; found: 1595.51.