Symmetry-driven rational design of a tetrahedral supramolecular Ti4L4 cluster

Angewandte Chemie - International Edition

Volumn 37, Issue 13-14, 1998, Pages 1837-1839

  Brückner, Christian ^a   Powers, Ryan E ^a   Raymond, Kenneth N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cage compounds; Clusters; O ligands; Self organization; Titanium

Indexed keywords

EID: 0042340042     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980803)37:13/14<1837::AID-ANIE1837>3.0.CO;2-A     Document Type: Article

References (37)

1. J.-M. Lehn, Supramolecular Chemistry: Concepts and Perspectives, VCH, Weinheim, 1995.
2. a) T. Beissel, R. E. Powers, K. N. Raymond Angew. Chem. 1996, 108, 1166; Angew. Chem. Int. Ed. Engl. 1996, 35, 1084. Other tetrahedra have been reported whose formation can be rationalized with this approach:
3. a) T. Beissel, R. E. Powers, K. N. Raymond Angew. Chem. 1996, 108, 1166; Angew. Chem. Int. Ed. Engl. 1996, 35, 1084. Other tetrahedra have been reported whose formation can be rationalized with this approach:
4. b) R. W. Saalfrank, A. Stark, M. Bremer, H. Hummel, ibid. 1990, 102, 292 and 1990, 29, 311;
5. b) R. W. Saalfrank, A. Stark, M. Bremer, H. Hummel, ibid. 1990, 102, 292 and 1990, 29, 311;
6. c) R. W. Saalfrank, B. Hörner, D. Stalke, J. Salbeck, ibid. 1993, 105, 1223 and 1993, 32, 1179;
7. c) R. W. Saalfrank, B. Hörner, D. Stalke, J. Salbeck, ibid. 1993, 105, 1223 and 1993, 32, 1179;
8. d) R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Forsch, E. Bill, M. Müther, A. X. Trautwein, ibid. 1994, 106, 1697 and 1994, 33, 1621;
9. d) R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Forsch, E. Bill, M. Müther, A. X. Trautwein, ibid. 1994, 106, 1697 and 1994, 33, 1621;
10. e) E. J. Enemark, T. D. P. Stack, ibid. 1998, 110, 977 and 1998, 37, 932;
11. e) E. J. Enemark, T. D. P. Stack, ibid. 1998, 110, 977 and 1998, 37, 932;
12. f) D. L. Caulder, R. E. Powers, T. N. Parac, K. N. Raymond, ibid. 1998, 110, 1940 and 1998, 37, 1840 (following paper).
13. f) D. L. Caulder, R. E. Powers, T. N. Parac, K. N. Raymond, ibid. 1998, 110, 1940 and 1998, 37, 1840 (following paper).
14. A. von Zelewsky, Stereochemistry of Coordination Compounds, Wiley, New York 1996.
15. K. N. Raymond, D. L. Caulder, R. E. Powers, T. Beissel, M. Meyer, B. Kersting, Proc. 40th Robert A. Welch Found. Chem. Res. 1996, 40, 115.
16. Corresponding to twist angles of about 40°; a) B. A. Borgias, S. R. Cooper, Y. B. Koh, K. N. Raymond, Inorg. Chem. 1984, 23, 1009; b) M. Albrecht, S. Kotila, Angew. Chem. 1995, 107, 2285; Angew. Chem. Int. Ed. Engl. 1995, 34, 2134; c) M. Albrecht, H. Röttele, P. Burger, Chem. Ear. J. 1996, 2, 1264.
17. Corresponding to twist angles of about 40°; a) B. A. Borgias, S. R. Cooper, Y. B. Koh, K. N. Raymond, Inorg. Chem. 1984, 23, 1009; b) M. Albrecht, S. Kotila, Angew. Chem. 1995, 107, 2285; Angew. Chem. Int. Ed. Engl. 1995, 34, 2134; c) M. Albrecht, H. Röttele, P. Burger, Chem. Ear. J. 1996, 2, 1264.
18. Corresponding to twist angles of about 40°; a) B. A. Borgias, S. R. Cooper, Y. B. Koh, K. N. Raymond, Inorg. Chem. 1984, 23, 1009; b) M. Albrecht, S. Kotila, Angew. Chem. 1995, 107, 2285; Angew. Chem. Int. Ed. Engl. 1995, 34, 2134; c) M. Albrecht, H. Röttele, P. Burger, Chem. Ear. J. 1996, 2, 1264.
19. Corresponding to twist angles of about 40°; a) B. A. Borgias, S. R. Cooper, Y. B. Koh, K. N. Raymond, Inorg. Chem. 1984, 23, 1009; b) M. Albrecht, S. Kotila, Angew. Chem. 1995, 107, 2285; Angew. Chem. Int. Ed. Engl. 1995, 34, 2134; c) M. Albrecht, H. Röttele, P. Burger, Chem. Ear. J. 1996, 2, 1264.
20. a) T. J. McMurry, M. W. Hosseini, T. M. Garret, F. E. Hahn, Z. E. Reyes, K. N. Raymond, J. Am. Chem. Soc. 1987, 109, 7196;
21. b) T. M. Garrett, P. W. Miller, K. N. Raymond, Inorg. Chem 1989, 28, 128.
22. T. Yamaoka, H. Hosoya, S. Nagakura, Tetrahedron 1968, 24, 6203.
23. F. L. Weitl, K. N. Raymond, J. Am. Chem. Soc. 1980, 102, 2289.
24. R. E. Powers, Ph. D. thesis, University of California, Berkeley, CA (USA), 1997.
25. a) R. R. Holmes, S. Shafieezad, V. Chandrasekhar, A. C Sau, J. M. Holmes, R. O. Day, J. Am. Chem. Soc. 1988, 110, 1168;
26. b) C. Lambert, J. C. Machell, D. M. P. Mingos, T. L. Stolberg, J. Mater. Chem. 1991, 1, 775.
27. a) A. Marquis-Rigault, A. Dupont-Gervais, A. Van Dorsselaer, J.-M. Lehn, Chem. Eur. J. 1996, 2, 1395 and references therein;
28. b) A. Marquis-Rigault, A. Dupont-Gervais, P. N. W. Baxter, A. Van Dorsselaer, J.-M. Lehn, Inorg. Chem. 1996, 35, 2307 and references therein.
29. + cations per asymmetric unit were distributed unequally over all four possible catecholate and all four possible carbonyl oxygen positions. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-101007. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax:(+44)1223-336-033, e-mail: deposit@ccdc.cam.ac.uk).
30. S. Mann, G. Huttner, L. Zsolnai, K. Heinze, Angew. Chem. 1996, 108, 2983; Angew. Chem. Int. Ed. 1996, 35, 2808.
31. S. Mann, G. Huttner, L. Zsolnai, K. Heinze, Angew. Chem. 1996, 108, 2983; Angew. Chem. Int. Ed. 1996, 35, 2808.
32. A. J. Amoroso, J. C. Jeffery, P. L. Jones, J. A. McCleverty, P. Thorton, M. D. Ward, Angew. Chem. 1995, 107, 1577; Angew. Chem. Int. Ed. Engl. 1995, 34, 1443.
33. A. J. Amoroso, J. C. Jeffery, P. L. Jones, J. A. McCleverty, P. Thorton, M. D. Ward, Angew. Chem. 1995, 107, 1577; Angew. Chem. Int. Ed. Engl. 1995, 34, 1443.
34. SMART Area Detector Software Package, V4.050, Siemens Industrial; Automation, Inc., Madison, WI (USA), 1995.
35. SAINT, Siemens Area Detector Integration Program, V4.024, Siemens Industrial; Automation, Inc., Madison, WI (USA), 1995.
36. SADABS, Siemens Area Detector Absorption Correction Program, George Sheldrick, advance copy.
37. teXsan, Crystal Structure Analysis Package, Molecular Structure Corporation, 1992.