N-methylsulfonimidoyl-substituted (2-alkenyl)titanium complexes: Application to the synthesis of β- And δ-sulfonimidoyl-substituted chiral homoallylic alcohols, X-ray crystal structure analysis, and fluxional behavior

European Journal of Organic Chemistry

Volumn , Issue 24, 2000, Pages 3973-4009

  Gais, Hans Joachim ^a   Hainz, Rüdiger ^a   Müller, Harald ^a   Bruns, Peter Richard ^a   Giesen, Nicole ^a   Raabe, Gerhard ^a   Runsink, Jan ^a   Nienstedt, Sabine ^a   Decker, Jürgen ^a   Schleusner, Marcel ^a   Hachtel, Jochen ^a   Loo, Ralf ^a   Woo, Chang Wan ^a   Das, Parthasarathi ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Alcohols; Asymmetric synthesis; Chirality; Fluxionality; Sulfur; Titanium

Indexed keywords

ALCOHOL DERIVATIVE; SULFOXIMINE DERIVATIVE; SULFUR DERIVATIVE; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; CRYSTAL STRUCTURE; ISOMERISM; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 0034527402     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0690(200012)2000:24<3973::AID-EJOC3973>3.0.CO;2-B     Document Type: Article

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138. 3.
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149. E. Keller, SCHAKAL 92, Universität Freiburg, Germany, 1992. Note Added in Proof (October 10, 2000): X-ray crystal structure analyses of 18c and 18d not only confirmed the configurations shown in Scheme 12 but revealed also hydrogen bond stabilized conformations of type (B) depicted in Figure 7.