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Volumn 297, Issue 1-2, 2000, Pages 338-350

Amine conformational change and spin conversion induced by metal-assisted ligand oxidation: From the seven-coordinate iron(II)-TPAA complex to the two oxidized iron(II)-(py)3tren isomers. Characterization, crystal structures, and density functional study

(6) Morgenstern Badarau, Irène a Lambert, François a Philippe Renault, Jean a Cesario, Michèle b Maréchal, Jean Didier c Maseras, Feliu c

a UNIVERSITÉ PARIS SUD (France)

b CNRS (France)

c UNIVERSITAT AUTÒNOMA DE BARCELONA (Spain)

Author keywords

Conformational change; Density functional calculation; Intermediate spin; Iron(II) complexes; Seven coordinate; Spin conversion

Indexed keywords

CRYSTALS; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; ISOMERS; LIGANDS; NITROGEN; OXIDATION; PLANTS (BOTANY); X RAY CRYSTALLOGRAPHY;

CONFORMATIONAL CHANGE; INTERMEDIATE SPINS; IRON COMPLEX; SEVEN-COORDINATE; SPIN CONVERSION;

IRON COMPOUNDS;

AMINE; IRON COMPLEX; LIGAND; METAL;

ARTICLE; CALCULATION; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; ELECTROMAGNETIC FIELD; ELECTRON SPIN RESONANCE; GEOMETRY; ISOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; X RAY CRYSTALLOGRAPHY;

EID: 0033806594 PISSN: 00201693 EISSN: None Source Type: Journal
DOI: 10.1016/S0020-1693(99)00363-1 Document Type: Article

Times cited : (63)

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