Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes

Inorganic Chemistry

Volumn 36, Issue 20, 1997, Pages 4539-4547

  Hikichi, Shiro ^a   Ogihara, Tamako ^a   Fujisawa, Kiyoshi ^a   Kitajima, Nobumasa ^a   Akita, Munetaka ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000820511     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960903m     Document Type: Article

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78. 17 give the corresponding 6-coordinate MeCN adducts, and the dioxygen adducts are suggested to have 6-coordinate Fe(III) centers. Therefore, we speculate that the steric demand becomes a dominant factor for reactivity toward dioxygen. However, we have not performed yet a theoretical study about the possibility of formation of a 5-coordinate Fe(III)-superoxo species.