Energetic iron(VI) chemistry: The super-iron battery

Science

Volumn 285, Issue 5430, 1999, Pages 1039-1042

  Licht, Stuart ^a   Wang, Baohui ^a   Ghosh, Susanta ^a  

^a TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROLYTE; IRON; POTASSIUM HYDROXIDE;

ARTICLE; BATTERY INDUSTRY; ELECTROCHEMICAL ANALYSIS; ELECTROCHEMISTRY; ENGINEERING; PRIORITY JOURNAL;

EID: 0033551886     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.285.5430.1039     Document Type: Article

References (20)

1. J. R. Dahn, T. Zheng, Y. Liu, J. S. Xue, Science 270, 590 (1995).
2. Y. Idota, T. Kubota, A. Matsufuji, Y. Maekawa, T. Miyasaka, ibid. 276, 1395 (1997).
3. E. Reddington et al., ibid. 280, 1735 (1998).
4. B. T. Holland, C. F. Blanford, A. Stein, ibid. 281, 538 (1998).
5. S. R. Ovshinsky, M. A. Fetcenko, J. Ross, ibid. 260, 176 (1993); S. K. Dhar et al., J. Power Sources 65, 1 (1997).
6. S. R. Ovshinsky, M. A. Fetcenko, J. Ross, ibid. 260, 176 (1993); S. K. Dhar et al., J. Power Sources 65, 1 (1997).
7. Z. Rong et al., Science 276, 926 (1997).
8. D. Peramunage and S. Licht, ibid. 261, 1029 (1993).
9. S. Licht, D. Peramunage, N. Myung, J. Phys. Chem. B. 102, 6780 (1998).
10. M. D. Johnson and J. F. Read, Inorg. Chem. 35, 6795 (1996).
11. J. D. Carr et al., Proceedings of the 5th Conference, Water Chlorination, Williamsburg, VA, 3 to 8 June 1984, R. L. Jolley, Ed., (Lewis, Chelsea, MI, 1985), pp. 1285-1298; V. K. Sharma, J. O. Smith, F. J. Millero, Environ. Sci. Technol. 31, 2486 (1997).
12. J. D. Carr et al., Proceedings of the 5th Conference, Water Chlorination, Williamsburg, VA, 3 to 8 June 1984, R. L. Jolley, Ed., (Lewis, Chelsea, MI, 1985), pp. 1285-1298; V. K. Sharma, J. O. Smith, F. J. Millero, Environ. Sci. Technol. 31, 2486 (1997).
13. M. D. Johnson and B. Hornstein, Chem. Commun. 1996, 965 (1996).
14. L. Delaude and P. A Laszlo, J. Org. Chem. 61, 6360 (1996).
15. 4 solution) but yielded lower purity.
16. J. Chen and H. Y. Che, J. Electrochem. Soc. 140, 1205 (1993).
17. J. Veprek-Siska and V. Ettel, Chem. Ind. 1967, 548 (1967).
18. S. Licht, B. Wang, S. Ghosh, data not shown.
19. Duracell Web site, file MX2400.pdf (ULTRA vs. Standard AAA) downloaded 24 June 1999. (www.duracell. com/OEM/Primary/Alkaline/alkaline_manganese_ data.html.)
20. We thank V. Naschitz, J. Li, S. Shesternin, and V. Nair, who participated in synthesis of the Fe(VI) compounds, and G. Xu, V. Goldstein, O. Khaselev, and E. Kvashnina who participated in cell discharges.