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Volumn 276, Issue 5317, 1997, Pages 1395-1397

Tin-based amorphous oxide: A high-capacity lithium-ion-storage material

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CARBONIC ACID DERIVATIVE; COBALT; ELECTROLYTE; GLASS; HYDROGEN; LITHIUM ION; NICKEL; OXIDE; POLITEF; TIN;

EID: 0030974077     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.276.5317.1395     Document Type: Article
Times cited : (2600)

References (18)
  • 3
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    • R. Fong, U. Sacken, J. R. Dahn, J. Electrochem. Soc. 137, 2009 (1990); B. Scrosati, ibid. 139, 2776 (1992).
    • (1992) J. Electrochem. Soc. , vol.139 , pp. 2776
    • Scrosati, B.1
  • 4
    • 1842272876 scopus 로고    scopus 로고
    • note
    • All specific capacity and capacity density values are expressed on the basis of unit mass or volume of the starting material (oxidized state) before Li insertion and exclude the mass of any Li in the weights of the anodic materials.
  • 6
  • 7
    • 0027577981 scopus 로고
    • Z. X. Shu, R. S. McMillan, J. J. Murray, J. Electrochem. Soc. 140, 922 (1993). Effort has been made to design Li batteries without the use of Li-graphite anodes at low potentials [W. Li, J. R. Dahn, D. S. Wainwright, Science 264, 1115 (1994)].
    • (1993) J. Electrochem. Soc. , vol.140 , pp. 922
    • Shu, Z.X.1    McMillan, R.S.2    Murray, J.J.3
  • 8
    • 0028439202 scopus 로고
    • Z. X. Shu, R. S. McMillan, J. J. Murray, J. Electrochem. Soc. 140, 922 (1993). Effort has been made to design Li batteries without the use of Li-graphite anodes at low potentials [W. Li, J. R. Dahn, D. S. Wainwright, Science 264, 1115 (1994)].
    • (1994) Science , vol.264 , pp. 1115
    • Li, W.1    Dahn, J.R.2    Wainwright, D.S.3
  • 10
    • 1842359512 scopus 로고    scopus 로고
    • note
    • + (OCV), this loss is reduced to 25%, and further overvoltage recovers charge-discharge efficiency to the level of 85%. This fact indicates that the actual electrochemically irreversible portion in the initial Li-insertion reaction is one-seventh the initial charge capacity.
  • 12
    • 1842304655 scopus 로고    scopus 로고
    • note
    • Some TCOs with low Sn content showed poor glass formability, as a sign that Sn itself serves as a glass-forming component.
  • 13
    • 1842276821 scopus 로고    scopus 로고
    • note
    • We have found other glass-forming elements in metals and semi-metals such as Si, Ge, and V. Examples of other elements capable of constituting Sn-based oxide anodes, the optimization of which led to the invention of TCOs, are given in our patent applications: Y. Idota et al., European Patent 651,450A1 (1995); ibid., Canadian Patent 2,113,053 (1995); Y. Idota, U.S. Patent 5,478,671 (1995).
  • 14
    • 1842305630 scopus 로고    scopus 로고
    • note
    • 2O sample, as a broad complex band (half width in chemical shift of 200 ppm centered near 0 ppm).
  • 15
    • 1842303730 scopus 로고    scopus 로고
    • note
    • The effect of these dopants was discovered by random screening of glass-forming elements, and the exact chemical mechanism has not yet been determined. For detailed information, see K. Goda et al., International Patent Application (PCT) WO96/33519.
  • 17
    • 1842283605 scopus 로고    scopus 로고
    • note
    • Unit C represents the rate of charging (discharging) in which current is equivalent to the quantity of the nominal capacity of a battery, indicating the rate in which charging can be completed in essentially 1 hour if the rate efficiency is unchanged.
  • 18
    • 1842314177 scopus 로고    scopus 로고
    • note
    • 7U-NMR analysis.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.