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Volumn 38, Issue 9, 1999, Pages 1257-1261

Functional monolayers with coordinatively embedded metalloporphyrins

Author keywords

Monolayers; N ligands; Porphyrinoids; Self assembly

Indexed keywords

METALLOPORPHYRIN;

EID: 0033519270     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H     Document Type: Article
Times cited : (47)

References (34)
  • 21
    • 33747533097 scopus 로고    scopus 로고
    • note
    • The diastereotopic nature of the separate signals was established by 2D COSY NMR measurements.
  • 23
    • 33747537682 scopus 로고    scopus 로고
    • note
    • 2 protons of the ligand.
  • 27
    • 33747554129 scopus 로고    scopus 로고
    • note
    • III(TPP)]-imidazole complexation can be achieved either intra-molecularly to form 1:1 complexes, or intermolecularly to form a lateral array. In both arrangements the porphyrin ring would be oriented perpendicular to the surface.
  • 28
    • 33747556290 scopus 로고    scopus 로고
    • note
    • Theoretic monolayer thicknesses were calculated from a model where the complexes or free ligands are oriented perpendicularly with respect to the surface.
  • 29
    • 33747581673 scopus 로고    scopus 로고
    • note
    • [4a] (UPD=underpotential metal deposition) as 77-85%. The exposed surface is attributed to the relatively large space between the bound disulfides.
  • 31
    • 33747581015 scopus 로고    scopus 로고
    • note
    • Prolonged rinsing in pure ethanol was ineffective, while the use of pure water caused the gold layer to exfoliate from the silicon surface.
  • 34
    • 33747522659 scopus 로고    scopus 로고
    • note
    • III(TPP)Cl] solution under the same conditions showed no voltammetric peak or a very weak peak > 100 mV negative of that of the complex monolayer, which is attributed to physisorbed porphyrins.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.