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Landolt-Boernstein: Numerical Data and Functional Relationships in Science and Technology, New Series ed.; Madelung, O., Ed.; Springer-Verlag: Berlin, Heidelberg, New York, 1991; Vol. Group IV, Vol. 6.
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(1991)
Landolt-Boernstein: Numerical Data and Functional Relationships in Science and Technology
, vol.6
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Madelung, O.1
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95
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1842309194
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note
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As one of the reviewers suggested, we can also consider the shifts along the y axis. The overall CPD changes for zero dipole moment are 380 mV for Au and 170 mV for CISe, using the linear curve fits shown in Figure 6. Neglecting variabilities and uncertainties in the selection of the reference samples, the shift for Au is attributed to the molecules' residual dipole moments exclusive of the benzoyl and palmitoyl substituents and the shift on CISe to both the molecules' residual dipole moments exclusive of the benzoyl and palmitoyl substituents and the dipole moment of the In-S bond. The latter contribution will be scaled according to the tilt of the bond relative to the surface normal; see eq 5. The numerically larger effect on Au relative to CISe can be attributed to the twice as large coverage on Au relative to CISe and to the difference in structure and morphology (including roughness) between the surfaces.
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97
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0000311936
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Bastide, S.; Butruille, R.; Cahen, D.; Dutta, A.; Libman, J.; Shanzer, A.; Sun, L.; Vilem, A. J. Phys. Chem. B 1997, 101, 2678-2684.
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(1997)
J. Phys. Chem. B
, vol.101
, pp. 2678-2684
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Bastide, S.1
Butruille, R.2
Cahen, D.3
Dutta, A.4
Libman, J.5
Shanzer, A.6
Sun, L.7
Vilem, A.8
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