Independent Synthesis and Structural Characterization of a Mononuclear Copper-Hydroxide Complex Previously Assigned as a Copper-Superoxide Species

Inorganic Chemistry

Volumn 35, Issue 21, 1996, Pages 6339-6342

  Berreau, Lisa M ^a   Mahapatra, Samiran ^a   Halfen, Jason A ^a   Young Jr , Victor G ^a   Tolman, William B ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000969116     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960340e     Document Type: Article

References (23)

1. Recent reviews: (a) Kitajima, N.; Moro-oka, Y. Chem. Rev. 1994, 94, 737-757. (b) Karlin, K. D.; Tyeklár, Z. Adv. Inorg. Biochem. 1994, 9, 123-172. Fox, S.; Karlin, K. D. In Active Oxygen in Biochemistry; Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic & Professional, Chapman & Hall: Glasgow, Scotland, 1995; pp 188-231.
2. Recent reviews: (a) Kitajima, N.; Moro-oka, Y. Chem. Rev. 1994, 94, 737-757. (b) Karlin, K. D.; Tyeklár, Z. Adv. Inorg. Biochem. 1994, 9, 123-172. Fox, S.; Karlin, K. D. In Active Oxygen in Biochemistry; Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic & Professional, Chapman & Hall: Glasgow, Scotland, 1995; pp 188-231.
3. Recent reviews: (a) Kitajima, N.; Moro-oka, Y. Chem. Rev. 1994, 94, 737-757. (b) Karlin, K. D.; Tyeklár, Z. Adv. Inorg. Biochem. 1994, 9, 123-172. Fox, S.; Karlin, K. D. In Active Oxygen in Biochemistry; Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Blackie Academic & Professional, Chapman & Hall: Glasgow, Scotland, 1995; pp 188-231.
4. Karlin, K. D.; Wei, N.; Jung, B.; Kaderli, S.; Niklaus, P.; Zuberbühler, A. D. J. Am. Chem. Soc. 1993, 115, 9506-9514.
5. Fujisawa, K.; Tanaka, M.; Moro-oka, Y.; Kitajima, N. J. Am. Chem. Soc. 1994, 116, 12079-12080.
6. Harata, M.; Jitsukawa, K.; Masuda, H.; Einaga, H. J. Am. Chem. Soc. 1994, 116, 10817-10818.
7. Halfen, J. A.; Mahapatra, S.; Wilkinson, E. C.; Gengenbach, A. J.; Young, V. G., Jr.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1996, 118, 763-776.
8. Harata, M.; Jitsukawa, K.; Masuda, H.; Einaga, H. Chem. Lett. 1995, 61-62.
9. Ruggiero, C. E.; Carrier, S. M.; Antholine, W. E.; Whittaker, J. W.; Cramer, C. J.; Tolman, W. B. J. Am. Chem. Soc. 1993, 115, 11285-11298.
10. SHELXTL V5.0, Siemens Energy & Automation, Inc., Madison, WI 53719-1173.
11. -3.
12. Lee, S. C.; Holm, R. H. J. Am. Chem. Soc. 1993, 115, 11789-11798 and ref 45 cited therein.
13. For example, see: (a) Duggan, M.; Ray, N.; Hathaway, B.; Tomlinson, G.; Brint, P.; Pelin, K. J. Chem. Soc., Dalton Trans. 1980, 1342-1348. (b) Karlin, K. D.; Hayes, J. C.; Juen, S.; Hutchinson, J. P.; Zubieta, J. Inorg. Chem. 1982, 21, 4106-4108. Chuang, C.; Lim, K.; Chen, Q.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2562-2568.
14. For example, see: (a) Duggan, M.; Ray, N.; Hathaway, B.; Tomlinson, G.; Brint, P.; Pelin, K. J. Chem. Soc., Dalton Trans. 1980, 1342-1348. (b) Karlin, K. D.; Hayes, J. C.; Juen, S.; Hutchinson, J. P.; Zubieta, J. Inorg. Chem. 1982, 21, 4106-4108. Chuang, C.; Lim, K.; Chen, Q.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2562-2568.
15. For example, see: (a) Duggan, M.; Ray, N.; Hathaway, B.; Tomlinson, G.; Brint, P.; Pelin, K. J. Chem. Soc., Dalton Trans. 1980, 1342-1348. (b) Karlin, K. D.; Hayes, J. C.; Juen, S.; Hutchinson, J. P.; Zubieta, J. Inorg. Chem. 1982, 21, 4106-4108. Chuang, C.; Lim, K.; Chen, Q.; Zubieta, J.; Canary, J. W. Inorg. Chem. 1995, 34, 2562-2568.
16. Bertini, I.; Luchinat, C. In Bioinorganic Chemistry; Bertini, I., Gray, H. B., Lippard, S. J., Valentine, J. S., Eds.; University Science Books: Mill Valley, CA, 1994.
17. 2, the X-ray crystal structure of which reveals binding of one pivaloylamide carbonyl to the fifth available Cu(II) coordination position (see Supporting Information).
18. The generation of copper-hydroxide complexes (typically dinuclear) upon decomposition of copper-dioxygen adducts is well-known. For example, see: (a) Mahapatra, S.; Halfen, J. A.; Wilkinson, E. C.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1994, 116, 9785-9786. (b) Mahapatra, S.; Halfen, J. A.; Wilkinson, E. C.; Pan, G.; Cramer, C. J.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1995, 117, 8865-8866.
19. The generation of copper-hydroxide complexes (typically dinuclear) upon decomposition of copper-dioxygen adducts is well-known. For example, see: (a) Mahapatra, S.; Halfen, J. A.; Wilkinson, E. C.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1994, 116, 9785-9786. (b) Mahapatra, S.; Halfen, J. A.; Wilkinson, E. C.; Pan, G.; Cramer, C. J.; Que, L., Jr.; Tolman, W. B. J. Am. Chem. Soc. 1995, 117, 8865-8866.
20. (a) Takahashi, K.; Ogawa, E.; Oishi, N.; Nishida, Y.; Kida, S. Inorg. Chim. Acta 1982, 66, 97-103.
21. (b) Addison, A. W.; Hendriks, H. M. J.; Reedijk, J.; Thompson, L. K. Inorg. Chem. 1981, 20, 103-110.
22. For example, see: (a) Mahapatra, S.: Halfen, J. A.; Tolman, W. B. J. Chem. Soc., Chem. Commun. 1994, 1625-1626. (b) Karlin, K. D.; Gultneh, Y. Prog. Inorg. Chem. 1987, 35, 219-328 (especially pp 273-275).
23. For example, see: (a) Mahapatra, S.: Halfen, J. A.; Tolman, W. B. J. Chem. Soc., Chem. Commun. 1994, 1625-1626. (b) Karlin, K. D.; Gultneh, Y. Prog. Inorg. Chem. 1987, 35, 219-328 (especially pp 273-275).