Molecular phosphonate cages: Model compounds and starting materials for phosphate materials

Accounts of Chemical Research

Volumn 32, Issue 2, 1999, Pages 117-126

  Walawalkar, Mrinalini G ^a   Roesky, Herbert W ^a   Murugavel, Ramaswamy ^b  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALI METAL; PHOSPHATE; PHOSPHONIC ACID DERIVATIVE; TITANIUM; TITANOPHOSPHONIC ACID; UNCLASSIFIED DRUG;

CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR MODEL; REVIEW; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0032901758     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar980040w     Document Type: Review

References (62)

1. Corbridge, D. E. C. Phosphorus: An Outline of its Chemistry, Biochemistry and Technology, 5th ed.; Elsevier: Amsterdam, 1995.
2. Milton, R. M. Commercial Development of Molecular Sieve Technology. In Molecular Sieves, Pap. Conf. Soc. Chem. Ind., London, 1968; pp 199-203.
3. Wilson, S. T.; Lok, B. M.; Messina, C. A.; Cannan, T. R.; Flanigen, E. M. Aluminophosphate Molecular Sieves: A New Class of Microporous Crystalline Inorganic Solids. J. Am. Chem. Soc. 1982, 104, 1146-1147.
4. Yin, X.; Nazar, L. F. The Synthesis and Crystal Structure of a Novel Oxyfluorinated Gallium Phosphate Using Diaminobutane as a Template. J. Chem. Soc., Chem. Commun. 1994, 2349-2350.
5. Oliver, S.; Kuperman, A.; Ozin, G. A. A New Model for Aluminophosphate Formation: Transformation of a Linear Chain Aluminophosphate to Chain, Layer, and Framework Structures. Angew. Chem. 1998, 110, 48-64; Angew. Chem., Int. Ed. Engl. 1998, 37, 46-62.
6. Oliver, S.; Kuperman, A.; Ozin, G. A. A New Model for Aluminophosphate Formation: Transformation of a Linear Chain Aluminophosphate to Chain, Layer, and Framework Structures. Angew. Chem. 1998, 110, 48-64; Angew. Chem., Int. Ed. Engl. 1998, 37, 46-62.
7. Gier, T. E.; Stucky, G. D. Low-Temperature Synthesis of Hydrated Zinco(beryllo)phosphate and Arsenate Molecular Sieves. Nature 1991, 349, 508-510.
8. Hevesey, G.; Kimura, K. The Solubilities of the Phosphates of Zirconium and Hafnium. J. Am. Chem. Soc. 1925, 47, 2540-2544.
9. For an extensive list of recent references on framework phosphates and phosphonates, see: Walawalkar, M. G. Synthesis and Structural Studies of Model Compounds for Zeolites and Phosphate Molecular Sieves; Cuvillier: Göttingen, 1997.
10. For some recent work, see: (a) Byrd, H.; Clearfield, A.; Poojary, D.; Reis, K. P.; Thompson, M. E. Crystal Structure of a Porous Zirconium Phosphate/Phosphonate Compound and Photocatalytic Hydrogen Production from Related Materials. Chem. Mater. 1996, 8, 2239-2246.
11. 3. J. Chem. Soc., Chem. Commun. 1994, 1171-1172.
12. 3. Chem. Mater. 1996, 8, 2259-2264.
13. Zubieta, J. Clusters and Solid Phases of the Oxovanadium Phosphate and Organophosphonate Systems. Comments Jnorg. Chem. 1994, 16, 153-183.
14. Cao, G.; Hong, H.-G.; Mallouk, T. E. Layered Metal Phosphates and Phosphonates: From Crystals to Monolayers. Acc. Chem. Res. 1992, 25, 420-427.
15. Clearfield, A. Layered Phosphates, Phosphites and Phosphonates of Groups 4 and 14 Metals. Comments Inorg. Chem. 1990, 10, 89-128.
16. Alberti, G.; Constantino, U. In Inclusion Compounds 5; Atwood, J. L., Davis, J. E. D., MacNicol, D. D., Eds.; Oxford University Press: Oxford, 1991.
17. Haushalter, R. C.; Mundi, L. A. Reduced Molybdenum Phosphates: Octahedral-Tetrahedral Framework Solids with Tunnels, Cages, and Micropores. Chem. Mater. 1992, 4, 31-48.
18. Behrens, P.; Stucky, G. D. Ordered Molecular Arrays as Templates: A New Approach to the Synthesis of Mesoporous Materials. Angew. Chem. 1993, 105, 729-732; Angew. Chem., Int. Ed. Engl. 1993, 32, 696-699.
19. Behrens, P.; Stucky, G. D. Ordered Molecular Arrays as Templates: A New Approach to the Synthesis of Mesoporous Materials. Angew. Chem. 1993, 105, 729-732; Angew. Chem., Int. Ed. Engl. 1993, 32, 696-699.
20. Hu, Y.; Navrotsky, A.; Chen, C.-Y.; Davis, M. E. Thermochemical Study of the Relative Stability of Dense and Microporous Aluminophosphate Frameworks. Chem. Mater. 1995, 7, 1816-1823.
21. Lewis, D. W.; Willock, D. J.; Catlow, C. R. A.; Thomas, J. M.; Hutchings, G. J. De Novo Design of Structure-Directing Agents for the Synthesis of Microporous Solids. Nature 1996, 382, 604-606.
22. Szostak, R. Molecular Sieves: Principles of Synthesis and Identification; Van Nostrand Reinhold: New York, 1989.
23. Meier, W. M. Zeolite Structures. In Molecular Sieves, Pap. Conf. Soc. Chem. Ind., London, 1968; pp 10-27.
24. Witt, M.; Roesky, H. W. Transition and Main Group Metals in Cyclic Phosphazanes and Phosphazenes. Chem. Rev. 1994, 94, 1163-1181.
25. Murugavel, R.; Chandrasekhar, V.; Roesky, H. W. Discrete Silanetriols: Building Blocks for Three-Dimensional Metallasiloxanes. Acc. Chem. Res. 1996, 29, 183-189.
26. Murugavel, R.; Voigt, A.; Walawalkar, M. G.; Roesky, H. W. Hetero- and Metallasiloxanes Derived from Silanediols, Disilanols, Silanetriols and Trisilanols. Chem. Rev. 1996, 96, 2205-2236.
27. For a recent minireview, see: Mason, M. R. Molecular Phosphates, Phosphonates, Phosphinates, and Arsonates of the Group 13 Elements. J. Cluster Sci. 1998, 9, 1-23.
28. Estermann, M.; McCusker, L B.; Baerlocher, C.; Merrouche, A.; Kessler, H. A Synthetic Gallophosphate Molecular Sieve with a 20-Tetrahedral-Atom Pore Opening. Nature 1991, 352, 320-323.
29. Yang, Y.; Schmidt, H.-G.; Noltemeyer, M.; Pinkas, J.; Roesky, H. W. Synthesis and Structure of an Organic-soluble Cage Aluminophosphonate. J. Chem. Soc., Dalton Trans. 1996, 3609-3610.
30. Walawalkar, M. G.; Murugavel, R.; Roesky, H. W.; Schmidt, H.-G. The First Molecular Borophosphonate Cage: Synthesis, Spectroscopy, and Single-Crystal X-ray Structure. Organometallics 1997, 16, 516-518.
31. Walawalkar, M. G.; Murugavel, R.; Roesky, H. W.; Schmidt, H.-G. Molecular Group 13 Phosphonates: A Synthetic, Spectroscopic, Structural and Reactivity Study. Inorg. Chem. 1997, 36, 4202-4207.
32. 12. Angew. Chem. 1997, 109, 251-253; Angew. Chem., Int. Ed. Engl. 1997, 56, 241-243.
33. 12. Angew. Chem. 1997, 109, 251-253; Angew. Chem., Int. Ed. Engl. 1997, 56, 241-243.
34. Mason, M. R.; Mashuta, M. S.; Richardson, J. F. Cyclic and Cubic Organophosphonates of Gallium and Their Relationship to Structural Motifs in Gallophosphate Molecular Sieves. Angew. Chem. 1997, 709, 249-251; Angew. Chem., Int. Ed. Engl. 1997, 36, 239-241.
35. Mason, M. R.; Mashuta, M. S.; Richardson, J. F. Cyclic and Cubic Organophosphonates of Gallium and Their Relationship to Structural Motifs in Gallophosphate Molecular Sieves. Angew. Chem. 1997, 709, 249-251; Angew. Chem., Int. Ed. Engl. 1997, 36, 239-241.
36. -. J. Solid State Chem. 1994, 111, 403-415.
37. Merrouche, A.; Patarin, J.; Soulard, M.; Kessler, H.; Angelrot, D. Orienting Effect of Fluoride Anions in the Synthesis of a Novel Gallophosphate of the LTA Type. Synth. Microporous Mater. 1992, 1, 384-389.
38. 4]. J. Chem. Soc., Dalton Trans. 1975, 1497-1499.
39. Yang, Y.; Walawalkar, M. G.; Pinkas, J.; Roesky, H. W.; Schmidt, H.-G. Molecular Aluminophosphonate: Model Compound for the Isoelectronic Double-Six-Ring (D6R) Secondary Building Unit of Zeolites. Angew. Chem. 1998, 110, 101-103; Angew. Chem., Int. Ed. Engl. 1998, 37, 96-98.
40. Yang, Y.; Walawalkar, M. G.; Pinkas, J.; Roesky, H. W.; Schmidt, H.-G. Molecular Aluminophosphonate: Model Compound for the Isoelectronic Double-Six-Ring (D6R) Secondary Building Unit of Zeolites. Angew. Chem. 1998, 110, 101-103; Angew. Chem., Int. Ed. Engl. 1998, 37, 96-98.
41. 4-18. Zeolites 1991, 11, 654-661.
42. 4-5: An Aluminophosphate with a Large Cage. Zeolites 1995, 15, 460-469.
43. Lok, B. M.; Messina, C. A.; Patton, R. L.; Gajek, R. T.; Cannan, T. R.; Flanigen, E. M. Silicoaluminophosphate Molecular Sieves: Another New Class of Microporous Crystalline Inorganic Solids. J. Am. Chem. Soc. 1984, 106, 6092-6093.
44. Yang, Y.; Pinkas, J.; Roesky, H. W. Unpublished results.
45. 2: A Novel Three-Coordinate Gallium Compound. J. Chem. Soc., Chem. Commun. 1996, 2339-2340.
46. Edwards, P. P.; Anderson, P. A.; Thomas, J. M. Dissolved Alkali Metals in Zeolites. Acc. Chem. Res. 1996, 29, 23-29.
47. Barrer, R. M.; Whiteman, J. L. Mercury Uptake in Various Forms of Several Zeolites. J. Chem. Soc. A 1967, 19-25.
48. Walawalkar, M. G.; Murugavel, R.; Voigt, A.; Roesky, H. W.; Schmidt, H.-G. A Novel Layered Molecular Lithium Galliumphosphonate Cage: Synthesis and Structure. J. Am. Chem. Soc. 1997, 119, 4656-4661.
49. + Ions Incorporated Gallophosphonates. Inorg. Chem. 1998, 37, 473-478.
50. Yang, Y.; Pinkas, J.; Schäfer, M.; Roesky, H. W. Unpublished results.
51. Yang, Y.; Pinkas, J.; Schäfer, M.; Roesky, H. W. Molecular Model for Aluminophosphates Containing Fluoride as a Structure-Directing and Mineralizing Agent. Angew. Chem. 1998, 110, 2795-2798; Angew. Chem., Int. Ed. Engl. 1998, 37, 2650-2653.
52. Yang, Y.; Pinkas, J.; Schäfer, M.; Roesky, H. W. Molecular Model for Aluminophosphates Containing Fluoride as a Structure-Directing and Mineralizing Agent. Angew. Chem. 1998, 110, 2795-2798; Angew. Chem., Int. Ed. Engl. 1998, 37, 2650-2653.
53. Murugavel, R.; Roesky, H. W. Titanosilicates: Recent Developments in Synthesis and Use as Oxidation Catalysts. Angew. Chem. 1997, 109, 491-494; Angew. Chem., Int. Ed. Engl. 1997, 36, 477-479.
54. Murugavel, R.; Roesky, H. W. Titanosilicates: Recent Developments in Synthesis and Use as Oxidation Catalysts. Angew. Chem. 1997, 109, 491-494; Angew. Chem., Int. Ed. Engl. 1997, 36, 477-479.
55. Voigt, A.; Murugavel, R.; Montero, M. L.; Wessel, H.; Liu, F.-Q.; Roesky, H. W.; Usón, I.;Albers, T.; Parisini, E. Soluble Molecular Titanosilicates. Angew. Chem. 1997, 109, 1020-1022; Angew. Chem., Int. Ed. Engl. 1997, 36, 1001-1003.
56. Voigt, A.; Murugavel, R.; Montero, M. L.; Wessel, H.; Liu, F.-Q.; Roesky, H. W.; Usón, I.;Albers, T.; Parisini, E. Soluble Molecular Titanosilicates. Angew. Chem. 1997, 109, 1020-1022; Angew. Chem., Int. Ed. Engl. 1997, 36, 1001-1003.
57. Walawalkar, M. G.; Horchler, S.; Dietrich, S.; Chakraborty, D.; Roesky, H. W.; Schäfer, M.; Schmidt, H.-G.; Sheldrick, G. M.; Murugavel, R. Novel Organic-Soluble Molecular Titanophosphonates with Cage Structures Comparable to Titanium-Containing Silicates. Organometallics 1998, 17, 2865-2868.
58. 2] have also been synthesized. However, analytically pure products have not been obtained.
59. Roberts, M. A.; Sankar, G.; Thomas, J. M.; Jones, R. H.; Du, H.; Chen, J.; Pang, W.; Xu, R. Synthesis and Structure of a Layered Titanosilicate Catalyst with Five-Coordiante Titanium. Nature 1996, 381, 401-404.
60. Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Zinc Di(tert-butyl)phosphate Complexes as Precursors to Zinc Phosphates. Manipulation of Zincophosphate Structures. Chem. Mater. 1997, 9, 339-348.
61. Thorn D. L.; Harlow, R. L.; Herron, N. Phosphatovanadium Chemistry: New Compounds Including an Example of "Tenne's Prospect", and Oxidation of Cyclohexadiene. Inorg. Chem. 1995, 34, 2629-2638.
62. Holmes R. R. Organotin Cluster Chemistry. Acc. Chem. Res. 1989, 22, 192-197.