Discrete silanetriols: Building blocks for three-dimensional metallasiloxanes

Accounts of Chemical Research

Volumn 29, Issue 4, 1996, Pages 183-189

  Murugavel, Ramaswamy ^a,b,c   Chandrasekhar, Vadapalli ^a,b,c,d,e,f   Roesky, Herbert W ^{a,c,g,h,i,j,k,l,m}  

^a Inst fur Anorganische Chemie   (Germany)

^b INDIAN INSTITUTE OF SCIENCE   (India)

^c UNIVERSITY OF GÖTTINGEN   (Germany)

^d UNIVERSITY OF MASSACHUSETTS   (United States)

^e INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

^f UNIVERSITY OF CALGARY   (Canada)

^g DUPONT COMPANY   (United States)

^h KYOTO UNIVERSITY   (Japan)

ⁱ TEXAS A AND M UNIVERSITY   (United States)

^j UNIVERSITY OF TEXAS AT AUSTIN   (United States)

^k UNIVERSITY OF IOWA   (United States)

^l Saxonian Academy of Sciences   (Germany)

^m Academy of Scientists Leopoldina   (Germany)

more..

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001648361     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar950154x     Document Type: Article

References (74)

1. Borisov, S. N.; Voronkov, M. G.; Lukevits, E. Y. Organosilicon Heteropolymers and Hetero Compounds, Plenum: New York, 1970.
2. (a) Yermakov, Y. I.; Kuznetsov, B. N.; Zakharov, V. A. Catalysis by Supported Complexes; Elsevier: Amsterdam, 1981.
3. (b) Seiyama, T.; Tanabe, K. New Horizons in Catalysis; Elsevier: Amsterdam, 1980.
4. (c) Hartley, F. R. Supported Metal Complexes; Reidel: Boston, 1985.
5. (a) Feher, F. J.; Budzichowski, T. A. Polyhedron 1995, 14, 3239
6. (b) Shakir, M.; Roesky, H. W. Phosphorus, Sulfur Silicon Relat. Eiern. 1994, 93-94, 13.
7. (c) Struchkov, Yu. T.; Lindeman, S. V. J. Organomet. Chem. 1995, 488, 9
8. (d) Voronkov, M. G ; Maletina, E. A.; Roman, V. K. In Heterosiloxanes; Soviet Scientific Review Supplement, Series Chemistry; Vol'pin, M. E., Gingold, K., Eds.; translation; Harwood, Academic: London, 1988; Vol. 1.
9. (e) Burgy, H.; Calzaferri, G.; Herren, D.; Zhdanov, A A. Chimia 1991, 45, 3.
10. (f) Abrahams, I.; Motevalli, M.; Shah, S. A.; Sullivan, A. C. J. Organomet. Chem. 1995, 452, 99.
11. For a comprehensive review on the synthesis and structures of various types of silanols, see: Lickiss, P. D. Adv. Inorg. Chem. 1995, 42, 147.
12. (a) Tyler, L J. J. Am. Chem. Soc. 1955, 77, 770.
13. (b) Andrianov, K. A.; Zhdanov, A A. Zh. Obshch. Khim. 1957, 27, 156.
14. (c) Takiguchi, T. J. Am. Chem. Soc. 1959, 81, 2359.
15. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
16. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
17. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
18. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
19. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
20. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
21. For other examples of silanetriols, see: (a) Michalska, Z.; Lasocki, Z. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1971, 19, 757. (b) Seyferth, D.; Nivert, C. L. J. Am. Chem. Soc. 1977, 99, 5209. (c) Seyferth, D.; Rudie, C. N.; Nestle, M. O. J. Organomet. Chem. 1979, 178, 227. (d) Ishida, H.; Koenig, J. L.; Gardner, K. C. J. Chem. Phys 1982, 77, 5748. (e) Al-Juaid, S. S.; Buttrus, N. H.; Damja, R. I., Derouiche, Y.; Eaborn, C.; Hitchcock, P. B.; Lickiss, P D. J. Organomet Chem. 1989, 371, 287. (f) Rickard, C. E. F.; Roper, W. R ; Salter, D. M.; Wright, L. J. J. Am. Chem. Soc. 1992, 114, 9682. (g) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701.
22. (a) Roesky, H. W. In Rings, Clusters and Polymers of Main Group and Transition Elements, Roesky, H. W., Ed ; Elsevier: Amsterdam, 1989; pp 369-408.
23. (b) Roesky, H. W. In The Chemistry of Inorganic Ring Systems; Studies in Inorganic Chemistry, Steudel, R., Ed.; Elsevier: Amsterdam, 1992; Vol. 14, pp 255-270.
24. Witt, M.; Roesky, H. W. Chem. Rev. 1994, 94, 1163.
25. (a) Gosink, H.-J.; Roesky, H. W.; Schmidt, H.-G ; Noltemeyer, M.; Irmer, E.; Herbst-Irmer, R. Organometallics 1994, 13, 3420.
26. (b) Gosink, H.-J.; Roesky, H. W.; Noltemeyer, M.; Schmidt, H -G.; Freire-Erdbrugger, F.; Sheldrick, G. M. Chem. Ber. 1993, 126, 279.
27. (c) Roesky, H. W.; Mazzah, A.; Hesse, D ; Noltemeyer, M. Chem. Ber. 1991, 124, 519.
28. (d) Haoudi-Mazzah, A.; Mazzah, A.; Schmidt, H.-G.; Noltemeyer, M.; Roesky, H. W. Z. Naturforsch. 1991, 46b, 587.
29. (a) Bhaumik, A.; Kumar, R. J. Chem. Soc , Chem Commun. 1995, 869.
30. (b) Perego, G.; Bellussi, G.; Corno, C.; Taramasso, M.; Buonomo, F.; Esposito, A. In Studies in Surface Science and Catalysis, New Developments in Zeolite Science and Technology; Murakami, Y., Iijima, A., Ward, J. W., Eds.; Elsevier: Amsterdam, 1986.
31. (c) Boccuti, M. R.; Rao, K. M ; Zecehina, A ; Leofanti, G.; Petrini, G. In Structure and Reactivity of Surfaces; Morterra, C., Zecehina, A., Costa, G , Eds.; Elsevier: Amsterdam, 1989; p L33.
32. (d) Joseph, R.; Ravindranathan, T.; Sudalai, A. Tetrahedron Lett. 1995, 36, 1903 and references cited therein.
33. (e) Notari, B. Stud. Surf. Sci. Catal. 1988, 37, 413.
34. Winkhofer, N.; Rocsky, H. W.; Noltemeyer, M.; Robinson, W. T. Angew. Chem. 1992, 104, 670; Angew. Chem., Int. Ed Engl. 1992, 31, 599.
35. Winkhofer, N.; Rocsky, H. W.; Noltemeyer, M.; Robinson, W. T. Angew. Chem. 1992, 104, 670; Angew. Chem., Int. Ed Engl. 1992, 31, 599.
36. 3 under different experimental conditions leads to other types of silanols/siloxanes; see: Lickiss, P. D.; Litster, S. A.; Redhouse, A. D.; Wisener, C. A. J. Chem. Soc., Chem. Commun. 1991, 173.
37. Ritter, U.; Winkhofer, N.; Stalke, D.; Roesky, H. W. J. Am. Chem. Soc., in press.
38. Murugavel, R.; Chandrasekhar, V.; Voigt, A.; Roesky, H. W; Schmidt, H.-G.; Noltemeyer, M. Organometallits 1995, 14, 5298
39. Winkhofer, N.; Voigt, A.; Dorn, H.; Roesky, H. W.; Steiner, A.; Stalke, D.; Relier, A. Angew. Chem. 1994, 106, 1414; Angew. Chem., Int. Ed. Engl 1994, 33, 1352.
40. Winkhofer, N.; Voigt, A.; Dorn, H.; Roesky, H. W.; Steiner, A.; Stalke, D.; Relier, A. Angew. Chem. 1994, 106, 1414; Angew. Chem., Int. Ed. Engl 1994, 33, 1352.
41. Al-Juaid, S. S.; Eaburn, C.; Hitchcock, P. B.; Lickiss, P. D. J. Organomet. Chem. 1992, 423, 5.
42. Voigt, A.; Murugavel, R.; Chandrasekhar, V.; Winkhofer, N.; Roesky, H. W.; Schmidt, H.-G.; Usón, I Organometallics, in press.
43. (a) Huybreehts, D. R. C.; Bruycker, D. L.; Jacobs, P. A. Nature 1990, 345, 240.
44. (b) Camblor, M. A.; Corma, A., Pérez-Pariente, J. J. Chem. Soc., Chem. Commun. 1992, 589.
45. (c) Boccuti, M. R.; Rao, K. M. Stud. Surf. Sci. Catal. 1989, 48, 133.
46. Liebau, F. Structural Chemistry of Silicates; Springer: Berlin, 1985; pp 244-260.
47. Montero, M.; Voigt, A.; Teichert, M.; Usón, I., Roesky, H W. Angew. Chem. 1995, 107, 2761; Angew. Chem , Int. Ed. Engl. 1995, 34, 2504.
48. Montero, M.; Voigt, A.; Teichert, M.; Usón, I., Roesky, H W. Angew. Chem. 1995, 107, 2761; Angew. Chem , Int. Ed. Engl. 1995, 34, 2504.
49. Chandrasekhar, V.; Murugavel, R.; Voigt, A.; Roesky, H W.; Schmidt, H.-G ; Noltemeyer, M. Organometallics 1996, 15, 918.
50. Smith, J. V. Chem. Rev. 1988, 88, 149.
51. Montero, M.; Usón, I.; Roesky, H. W. Angew. Chem. 1994, 106, 2198; Angew. Chem., Int Ed. Engl. 1994, 33, 2103.
52. Montero, M.; Usón, I.; Roesky, H. W. Angew. Chem. 1994, 106, 2198; Angew. Chem., Int Ed. Engl. 1994, 33, 2103.
53. Voigt, A.; Murugavel, R.; Parisini, E., Roesky, H. W. Angew. Chem., in press.
54. Voigt, A.; Murugavel. R.; Chandrasekhar, V.; Roesky, H. W. In preparation.
55. (a) Feher, F. J. J. Am. Chem. Soc. 1986, 108, 3850.
56. (b) Feher, F J.; Newman, D. A.; Walzer, J. F J. Am. Chem. Soc. 1989, 111, 1741.
57. (c) Feher, F. J.; Budzichowski, T. A.; Weller, K. J. J. Am. Chem. Soc 1989, 111, 7288.
58. (d) Feher, F. J.; Blanski, R. L. J. Chem Soc., Chem. Commun. 1990, 1614.
59. (e) Feher, F. J.; Budzichowski. T. A. Organometallics 1991, 10, 812.
60. (f) Feher, F J.; Walzer, J. F. Inorg. Chem. 1991, 30, 1689.
61. (g) Feher. F. J.; Walzer, J. F.; Blanski, R. L. J. Am. Chem. Soc. 1991, 113, 3618.
62. (h) Budzichowski, T. A.; Chacon, S. T.; Chisholm, M. H.; Feher, F. J.; Streib, W. J. Am. Chem. Soc, 1991, 113, 689.
63. (i) Feher, F. J.; Blanski, R. L. J. Am. Chem. Soc. 1992, 114, 5886.
64. (j) Feher, F. J.; Budzichowski. T. A.; Rahimian, K.; Ziller, J. W J. Am. Chem. Soc. 1902, 114, 3859.
65. (k) Feher, F. J.; Budzichowski, T. A.; Ziller, J. W. Inorg. Chem. 1992, 31, 5100.
66. (l) Feher, F. J.; Weller, K. J.; Ziller, J. W. J. Am Chem. Soc. 1992, 114, 9686.
67. (m) Feher, F. J.; Tajima, T. L. J. Am. Chem. Soc. 1994, 116, 2145.
68. Herrmann, W. A.; Anwander, R.; Dufaud, V.; Scherer, W. Angew. Chem. 1994, 106, 1338; Angew. Chem., Int. Ed. Engl. 1994, 33, 1285.
69. Herrmann, W. A.; Anwander, R.; Dufaud, V.; Scherer, W. Angew. Chem. 1994, 106, 1338; Angew. Chem., Int. Ed. Engl. 1994, 33, 1285.
70. (a) Igonin, V. A., Shchegolikhina, O. I.; Lindeman, S. V.; Levitsky, M. M.; Struchkov, Yu. T.; Zhdanov, A. A. J. Organomet. Chem. 1992, 423, 351.
71. (b) Levitsky, M. M.; Shchegolikhina, O. I.; Zhdanov, A. A.; Igonin, V. A.; Ovchinnikov, Yu. E.; Shklover, V. E.; Struchkov, Yu. T. J. Organomet. Chem. 1991, 401, 199.
72. (c) Kuznetsov, V. L.; Elizarova, G. L.; Matvienko, L. G.; Lantyukhova, I. G.; Kolomiichuk, V. N.; Zhdanov, A. A.; Shchegolikhina, O. I. J. Organomet. Chem. 1994, 475, 65.
73. Wraage, K.; Kunzel, A.; Schmidt, H.-G.; Noltemeyer, M.; Roesky, H. W. Angew. Chem. 1995, 107, 2954; Angew. Chem., Int. Ed. Engl. 1995, 34, 2645.
74. Wraage, K.; Kunzel, A.; Schmidt, H.-G.; Noltemeyer, M.; Roesky, H. W. Angew. Chem. 1995, 107, 2954; Angew. Chem., Int. Ed. Engl. 1995, 34, 2645.