Interaction of sulfur with well-defined metal and oxide surfaces: Unraveling the mysteries behind catalyst poisoning and desulfurization

Accounts of Chemical Research

Volumn 32, Issue 9, 1999, Pages 719-728

  Rodriguez, José A ^a   Hrbek, Jan ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; SULFUR DERIVATIVE; SULFUR OXIDE;

AIR POLLUTANT; AIR POLLUTION; ARTICLE; CATALYST; DESULFURIZATION; INTOXICATION; OIL INDUSTRY; PETROCHEMICAL INDUSTRY;

EID: 0032866538     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar9801191     Document Type: Article

References (56)

1. Speight, J. G. The Chemistry and Technology of Petroleum, 2nd ed; Dekker: New York, 1991.
2. Stern, A. C.; Boubel, R. W.; Turner, D. B.; Fox, D. L. Fundamentals of Air Pollution, 2nd ed; Academic Press: Orlando, 1984.
3. Taylor, K. C. NO Catalysts in Automotive Exhaust Systems. Catal. Rev. Sci. Eng. 1993, 35, 457.
4. Deactivation and Poisoning of Catalysts; Oudar, J., Wise, H., Eds; Dekker: New York, 1991.
5. (a) Handbook of Heterogeneous Catalysis; Ertl, G., Knözinger, H., Weitkamp, J., Eds.; Wiley-VCH: New York, 1997.
6. (b) Somorjai, G. A. Introduction to Surface Chemistry and Catalysis; Wiley: New York, 1994.
7. Rodriguez, J. A.; Goodman, D. W. High-Pressure Catalytic Reactions over Single- Crystal Metal Surfaces. Surf. Sci. Rep. 1991, 14, 1.
8. Chisholm, M. H., Ed. Symposium on Modeling of the Chemistry of Hydrotreating Processes. Polyhedron 1997, 16, 3071-3246.
9. (a) Rodriguez, J. A.; Kuhn, M.; Hrbek, J. The Bonding of Sulfur to a Pt(111) Surface. Chem. Phys. Lett. 1996, 251, 13.
10. (b) Rodriguez, J. A.; Chaturvedi, S.; Jirsak, T. Interaction of Sulfur with Pd Surfaces: Photoemission and Molecular-Orbital Studies. Chem. Phys. Lett. 1998, 296, 421.
11. (a) Feibelman, P. J.; Hamann, D. R. Modification of Transition Metal Electronic Structure by S Adatoms. Surf. Sci. 1985, 149, 48.
12. (b) Wilke, S.; Scheffler, M. Poisoning of Catalytic Activity of Pd(100) by Sulfur. Phys. Rev. Lett. 1996, 76, 3380.
13. (a) Mullins, D. R.; Lyman, P. F.; Overbury, S. H. Interaction of S with W(100). Surf. Sci. 1992, 277, 64.
14. (b) Rodriguez, J. A.; Kuhn, M.; Hrbek, J. Repulsive Interactions between Au and S on Mo(110) and Rh(111). J. Phys. Chem. 1996, 100, 3799.
15. 3. Appl. Surf. Sci. 1995, 89, 63.
16. Lang, N. D.; Holloway, S.; Nørskov, J. K. Electrostatic Adsorbate-Adsorbate Interactions. Surf. Sci. 1985, 150, 24.
17. Goodman, D. W. Chemical Modifications of Chemisorptive and Catalytic Properties of Nickel. Appl. Surf. Sci. 1984, 19, 1.
18. Kiskinova, M. P. Electronegative Additives and Poisoning in Catalysis. Surf. Sci. Rep. 1988, 8, 359.
19. Kiskinova, M.; Szabó, A.; Yates, J. T. CO Adsorption on Pt(111) modified with Sulfur. J. Chem. Phys. 1988, 89, 7599.
20. Campbell, C. T.; Koel, B. E. Sulfur Poisoning of Water-Gas Shift Catalysts. Surf. Sci. 1987, 183, 100.
21. Batteas, J. D.; Dunphy, J. C.; Somorjai, G. A.; Salmeron, M. Reconstruction of a Stepped Pt(111) Surface by Sulfur and CO. Phys. Rev. Lett. 1996, 77, 534.
22. Friend, C. M.; Chen, D. A. Fundamental Studies of Hydrodesulfurization by Metal Surfaces. Polyhedron 1997, 16, 3165.
23. 2 Adsorption on Metal Surfaces. J. Phys.: Condens. Matter 1997, 9, 3647.
24. Sellers, H.; Shustorovich, E. Chemistry of Sulfur Oxides on Transition Metal Surfaces. J. Mol. Catal. A: Chemical 1997, 119, 367.
25. 2 on Cu(100) and Cu(111). Phys. Rev. B 1996, 53, 13720.
26. 2 on Ag(100) J. Chem. Phys. 1991, 95, 6057.
27. 2 on Sn/Pt(111) Alloys: Effects of Meta-Metal Bonding in Reactivity toward Sulfur. J. Am. Chem. Soc. 1998, 120, 11149.
28. 2S with Sn/Pt(111) Surface Alloys. J. Chem. Phys. 1998, 109, 4052.
29. 2. J. Phys. Chem. B 1999, 103, 1966.
30. 2 with Pd/Rh(111) Surfaces. J. Chem. Phys. 1999, 110, 3138.
31. Mullins, D. R. Enhancement of Methane Formation from Methanethiol on Ni/W(001). J. Phys. Chem. B 1997, 101, 1014.
32. (a) Hrbek, J.; Schmid, A. K.; Bartelt, M. C.; Hwang, R. Q STM Study of Au Growth on S-modified Ru(0001). Surf. Sci. 1997, 385, L1002.
33. (b) Kuhn, M.; Rodriguez, J. A. Repulsive Interactions between S and Au on Ru(0001). Chem. Phys. Lett. 1994, 231, 199.
34. Dunphy, J. C.; Chapelier, C.; Ogletree, D. F.; Salmeron, M. B. Deposition of Au on Sulfur Covered Mo(100). J. Vac. Sci. Technol. B 1994, 12, 1742.
35. (a) Kuhn, M.; Rodriguez, J. A.; Hrbek, J. Admetal Promoted Sulfidation of Mo(110). Surf. Sci. 1996, 365, 53.
36. (b) Rodriguez, J. A. Metal-Metal Interactions and the Behavior of HDS Catalysts. Polyhedron 1997, 16, 3177.
37. Pohl, K.; Bartelt, M. C.; de la Figuera, J.; Bartelt, N. C.; Hrbek, J.; Hwang, R. Q. Self-organization of Nanostructures at Crystal Surfaces. Nature 1999, 397, 238.
38. Rodriguez, J. A. Physical and Chemical Properties of Bimetallic Surfaces. Surf. Sci. Rep. 1996, 24, 223.
39. (a) Rodriguez, J. A.; Goodman, D. W. The Nature of the Metal-Metal Bond in Bimetallic Surfaces. Science 1992, 257, 897.
40. (b) Wu, R.; Freeman, A. J. Bonding Mechanism at Bimetallic Interfaces. Phys. Rev. B 1995, 52, 12419.
41. (c) Hammer, B.; Morikawa, Y.; Nørskov, J. K. CO Chemisorption on Metal Surfaces and Overlayers. Phys. Rev. Lett. 1996, 76, 2141.
42. Overbury, S. H.; Mullins, D. R.; Paffett, M. T.; Koel, B. E. Surface Structure Determination of Sn on Pt(111). Surf. Sci. 1991, 254, 45.
43. Harris, S.; Chianelli, R. R. Catalysis by Transition Metal Sulfides. J. Catal. 1986, 98, 17.
44. 2 Surfaces. J. Phys. Chem. B 1997, 101, 7524.
45. (b) Rodriguez, J. A.; Dvorak, J.; Capitano, A. T.; Gabelnick, A. M.; Gland, J. L. Adsorption of Thiophene on Surfaces of Clean and Ni-promoted Molybdenum Sulfide. Surf. Sci. 1999, 429, 462.
46. 2 with Metal/Oxide Surfaces: Band-Gap Size and Chemical Reactivity. J. Phys. Chem. B 1998, 102, 5511.
47. 2O and ZnO Single-Crystal Surfaces. J. Am. Chem. Soc. 1992, 114, 4718.
48. 2S. Chem. Commun. 1996, 1431.
49. Shustorovich, E.; Baetzold, R. C. Toward a Coherent Theory of Chemisorption. Science 1985, 227, 876.
50. 2O and Cu/ZnO. Surf. Sci. 1998, 415, L1065.
51. Campbell, C. T. Ultrathin Metal Films and Particles on Oxide Surfaces. Surf. Sci. Rep. 1997, 27, 1.
52. Valden, M.: Lai, X.; Goodman, D. W. Onset of Catalytic Activity of Gold Clusters on Titania with Appearance of Nonmetallic Properties. Science 1998, 281, 1647.
53. 2S with MgO(100) and Cu/MgO(100) Surfaces: Band-Gap Size and Chemical Reactivity. J. Chem. Phys., submitted.
54. McCarty, J. G.; Wise, H. Thermodynamics of Sulfur Chemisorption on Metals. J. Chem. Phys. 1981, 74, 5877.
55. 4. J. Phys. Chem. B 1998, 103, 770.
56. Norby, P.; Hanson, J. C. In-situ Time-resolved Synchrotron X-ray Powder Diffraction Studies. Catal. Today 1998, 39, 301.