Reaction of S2 and H2S with Sn/Pt(111) surface alloys: Effects of metal-metal bonding on reactivity towards sulfur

Journal of Chemical Physics

Volumn 109, Issue 10, 1998, Pages 4052-4062

  Rodriguez, José A ^a   Chaturvedi, Sanjay ^a   Jirsak, Tomas ^a   Hrbek, Jan ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000958418     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.477005     Document Type: Article

References (91)

1. G. A. Somorjai, Introduction to Surface Chemistry and Catalysis (Wiley, New York, 1994).
2. J. M. Thomas and W. J. Thomas, Principles and Practice of Heterogeneous Catalysis (VHC, New York, 1997).
3. (a) O. A. Barias, A. Holmen, and E. A. Blekkan, J. Catal. 158, 1 (1996);
4. (b) E. Merlen, P. Beccat, J. C. Bertolini, P. Delichere, N. Zanier, and B. Didillon, 159, 178 (1996);
5. (c) J. Llorca, N. Homs, J. L. Fierro, J. Sales, and P. Ramirez, 166, 44 (1997);
6. (d) S. M. Stagg, C. A. Querini, W. E. Alvarez, and D. E. Resasco, 168, 75 (1997).
7. C. Xu, J. W. Peck, and B. E. Koel, J. Am. Chem. Soc. 115, 751 (1993).
8. (a) J. Szanyi and M. T. Paffett, J. Am. Chem. Soc. 117, 1034 (1995);
9. (b) J. Szanyi, S. Anderson, and M. T. Paffett, J. Catal. 149, 438 (1994).
10. H. Verbeek and W. M. H. Sachtler, J. Catal. 42, 257 (1976).
11. G. Meitzner, G. H. Via, F. W. Lytle, S. C. Fung, and J. H. Sinfelt, J. Phys. Chem. 92, 2925 (1988).
12. P. Ross, J. Vac. Sci. Technol. A 10, 2546 (1992).
13. C. H. Bartholomew, P. K. Agrawal, and J. R. Katzer, Adv. Catal. 31, 135 (1982).
14. P. G. Menon, Chem. Rev. 94, 1021 (1994).
15. M. T. Paffett and R. G. Windham, Surf. Sci. 208, 34 (1989).
16. S. H. Overbury, D. R. Mullins, M. T. Paffett, and B. E. Koel, Surf. Sci. 254, 45 (1991).
17. C. T. Campbell, Annu. Rev. Phys. Chem. 41, 775 (1990).
18. J. A. Rodriguez, Surf. Sci. Rep. 24, 223 (1996).
19. C. Xu and B. E. Koel, Surf. Sci. 327, 38 (1995).
20. C. Xu and B. E. Koel, Surf. Sci. 310, 198 (1994);
21. J. Chem. Phys. 100, 664 (1994).
22. (a) M. T. Paffett, S. C. Gebhard, R. G. Windham, and B. E. Koel, J. Phys. Chem. 94, 6831 (1990);
23. Surf. Sci. 223, 449 (1989);
24. (b) J. M. Heitzinger, S. C. Gebhard, and B. E. Koel, J. Phys. Chem. 97, 5327 (1993);
25. (c) C. Xu, B. E. Koel, and M. T. Paffett, Langmuir 10, 166 (1994).
26. M. Kuhn and J. A. Rodriguez, J. Catal. 154, 355 (1995).
27. J. A. Rodriguez, M. Kuhn, and J. Hrbek, J. Phys. Chem. 100, 15494 (1996).
28. M. Kuhn and J. A. Rodriguez, J. Vac. Sci. Technol. A 13, 1569 (1995).
29. M. Kuhn and J. A. Rodriguez, Catal. Lett. 32, 345 (1995).
30. J. A. Rodriguez and M. Kuhn, J. Vac. Sci. Technol. A 15, 1608 (1997).
31. G. P. Williams, Electron Binding Energies of the Elements, Version II (National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York, 1992).
32. J. A. Rodriguez, M. Kuhn, and J. Hrbek, Chem. Phys. Lett. 251, 13 (1996).
33. M. Dupuis, S. Chin, and A. Marquez, in Relativistic and Electron Correlation Effects in Molecules and Clusters, NATO ASI Series, edited by G. L. Malli (Plenum, New York, 1992).
34. (a) W. R. Wadt and P. J. Hay, J. Chem. Phys. 82, 284 (1985);
35. (b) P. J. Hay and W. R. Wadt, 82, 270 (1985).
36. J. A. Rodriguez and M. Kuhn, J. Phys. Chem. B 101, 3187 (1997).
37. J. A. Rodriguez, S. Chaturvedi, M. Kuhn, J. van Ek, U. Diebold, P. S. Robbert, H. Geisler, and C. Ventrice, J. Chem. Phys. 107, 9146 (1997).
38. (a) S. Chaturvedi, J. A. Rodriguez, and J. Hrbek, J. Phys. Chem. B 101, 10860 (1997);
39. (b) J. A. Rodriguez, T. Jirsak, S. Chaturvedi, and J. Hrbek, Surf. Sci. 407, 171 (1998);
40. (c) J. A. Rodriguez, S. Chaturvedi, M. Kuhn, and J. Hrbek, J. Phys. Chem. B 102, 5511 (1998).
41. (a) J. A. Rodriguez and M. Kuhn, J. Phys. Chem. 98, 11251 (1994);
42. (b) J. Chem. Phys. 102, 4279 (1995);
43. (c) J. A. Rodriguez, Surf. Sci. 345, 347 (1996);
44. (d) J. A. Rodriguez and M. Kuhn, Chem. Phys. Lett. 240, 435 (1995);
45. (e) L. Zhang, M. Kuhn, U. Diebold, and J. A. Rodriguez, J. Phys. Chem. B 101, 4588 (1997).
46. (a) J. L. Whitten and H. Yang, Surf. Sci. Rep. 24, 55 (1996);
47. (b) R. A. van Santen and M. Neurock, Catal. Rev. Sci. Eng. 37, 557 (1995).
48. Quantum Chemistry Approaches to Chemisorption and Heterogeneous Catalysis, edited by F. Ruette (Kluwer, Dordrecht, 1992).
49. (a) J. Hrbek, S. Y. Li, J. A. Rodriguez, D. G. van Campen, H. H. Huang, and G.-Q. Xu, Chem. Phys. Lett. 267, 65 (1997);
50. (b) S. Y. Li, J. A. Rodriguez, J. Hrbek, H. H. Huang, and G.-Q. Xu, Surf. Sci. 366, 29 (1996).
51. 5/2 binding energies are 1.5-2 eV larger than for metallic Sn;
52. (b) C. Wagner, W. M. Riggs, L. E. Davis, J. F. Moulder, and G. E. Muilenberg, Handbook of X-Ray Photoelectron Spectroscopy (Perkin-Elmer, Eden Praire, Minnesota, 1978), p. 118.
53. 2 and SnS [see Ref. 34 (b)].
54. J. A. Rodriguez, S. Chaturvedi, and M. Kuhn, J. Chem. Phys. 108, 3064 (1998).
55. B. Meyer, Chem. Rev. 76, 367 (1976).
56. W. F. Egelhoff, Surf. Sci. Rep. 6, 253 (1987).
57. W. Jaegermann and D. Schmeisser, Surf. Sci. 165, 143 (1986).
58. J. A. Rodriguez, Surf. Sci. 278, 326 (1992).
59. R. F. Hout, W. J. Pietro, and W. J. Hehre, A Pictorial Approach to Molecular Structure and Reactivity (Wiley, New York, 1984).
60. J. G. Speight, The Chemistry and Technology of Petroleum, 2nd ed. (Dekker, New York, 1991).
61. The complex line shape of the spectrum indicates that we have at least two sulfur species. If one takes into consideration the energy separation reported for adsorbed S and SH (Refs. 44 45), one can expect a spectrum similar to that seen here.
62. D. R. Huntley, Surf. Sci. 240, 13 (1990), and references therein.
63. C. T. Campbell and B. E. Koel, Surf. Sci. 183, 100 (1987).
64. R. J. Koestner, M. Salmeron, E. B. Kollin, and J. L. Gland, Surf. Sci. 172, 668 (1986).
65. Lange's Handbook of Chemistry, 13th ed. (McGraw-Hill, New York, 1985), Table 9-1.
66. K. Hayek, H. Glassl, A. Gutmann, H. Leonhard, M. Prutton, S. P. Tear, and M. R. Welton-Cook, Surf. Sci. 151/153, 419 (1985).
67. C. Kittel, Introduction to Solid State Physics, 6th ed. (Wiley, New York, 1986), pp. 23 and 24.
68. 3Sn alloy (2.83 Å);
69. (b) S. H. Overbury and Y.-S. Ku, Phys. Rev. B 46, 7868 (1992).
70. (a) N. J. Castellani and P. Legare, J. Phys. Chem. 98, 9606 (1994).
71. (b) A. Rochefort and R. Fournier, 100, 13506 (1996).
72. (c) R. M. Ferullo and N. Castellani, Langmuir 12, 70 (1996).
73. (a) The charges and orbital populations were calculated by a Mulliken population analysis [see (b)]. Due to the limits of this analysis [see (c)], the reported values must be considered only in qualitative terms;
74. (b) R. S. Mulliken, J. Chem. Phys. 23, 1841 (1955);
75. (c) A. Szabo and N. S. Ostlund, Modern Quantum Chemistry (McGraw-Hill, New York, 1989).
76. A. L. Allred, J. Inorg. Nucl. Chem. 17, 215 (1961).
77. Y. Jeon, J. Chen, and M. Croft, Phys. Rev. B 50, 6555 (1994).
78. (a) G. Apai, R. C. Baetzold, P. J. Jupiter, A. J. Viescas, and I. Lindau, Surf. Sci. 134, 122 (1983);
79. (b) J. A. Horsley, J. Chem. Phys. 76, 1451 (1982);
80. (c) P. J. Hay, J. Am. Chem. Soc. 103, 1390 (1981).
81. (a) R. Wu, Chem. Phys. Lett. 238, 99 (1995);
82. (b) R. Wu and A. J. Freeman, Phys. Rev. B 52, 12419 (1995).
83. H. Sellers, Surf. Sci. 249, 99 (1993).
84. A. G. Baca, M. A. Shultz, and D. A. Shirley, J. Chem. Phys. 81, 6304 (1984).
85. (a) B. K. Janousek and J. I. Brauman, in Gas Phase Ion Chemistry edited by M. T. Bowers (Academic, New York, 1979), Vol. 2, Chap. 10;
86. (b) T. Moeller, Inorganic Chemistry (Wiley, New York, 1982), p. 81.
87. (a) J. K. A. Clarke, Chem. Rev. 75, 291 (1975);
88. (b) V. Ponec, Adv. Catal. 32, 149 (1983).
89. 2 at 298.15 K.
90. L. Z. Mezey and J. Giber, Jpn. J. Appl. Phys., Part 1 21, 1569 (1982).
91. J. A. Rodriguez, T. Jirsak, S. Chaturvedi, and J. Hrbek, J. Am. Chem. Soc. (submitted).