Reaction of S2 with X/Mo(110) (X = Fe, Pt or Al) surfaces: Admetal-promoted sulfidation of Mo and the behavior of hydrodesulfurization catalysts

Surface Science

Volumn 365, Issue 1, 1996, Pages 53-68

  Kuhn, Markus ^a   Rodriguez, José A ^a   Hrbek, Jan ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

Aluminum; Catalysis; Iron; Molybdenum; Platinum; Sulfides; Surface chemical reaction; Thermal desorption spectroscopy; X ray photoelectron spectroscopy

Indexed keywords

ALUMINUM; ANNEALING; AUGER ELECTRON SPECTROSCOPY; CATALYSIS; CHEMICAL REACTIONS; HIGH TEMPERATURE EFFECTS; MOLYBDENUM; MULTILAYERS; PLATINUM; SULFUR; SURFACE PHENOMENA; X RAY PHOTOELECTRON SPECTROSCOPY;

ADMETAL PROMOTED SULFIDATION; BIMETALLIC BONDING; COHESIVE ENERGIES; ELECTRONIC INTERACTIONS; HYDRODESULFURIZATION CATALYSTS; MOLYBDENUM SULFIDES; THERMAL DESORPTION SPECTROSCOPY; X RAY EXCITED AUGER ELECTRON SPECTROSCOPY;

SURFACE TREATMENT;

EID: 0030244003     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/0039-6028(96)00693-0     Document Type: Article

References (59)

1. R. Prins, V.H.J. de Beer and G.A. Somorjai, Catal. Rev. Sci. Eng. 31 (1989) 1.
2. R.R. Chianelli, M. Daage and N.J. Ledoux, Adv. Catal. 40 (1994) 177.
3. C.C. Knight and G.A. Somorjai, Surf. Sci. 240 (1990) 101.
4. J.C. Dunphy, C. Chapelier, D.F. Ogletree and M.B. Salmeron, J. Vac. Sci. Technol. B 12, (1994) 1742; J.A. Rodriguez, M. Kuhn and J. Hrbek, J. Phys. Chem. 100 (1996) 3799.
5. J.C. Dunphy, C. Chapelier, D.F. Ogletree and M.B. Salmeron, J. Vac. Sci. Technol. B 12, (1994) 1742; J.A. Rodriguez, M. Kuhn and J. Hrbek, J. Phys. Chem. 100 (1996) 3799.
6. J.A. Rodriguez and M. Kuhn, J. Phys. Chem. 99 (1995) 9567.
7. M. Kuhn and J.A. Rodriguez, Surf. Sci. 355 (1996) 85.
8. M. Kuhn and J.A. Rodriguez, Surf. Sci. 336 (1995) 1.
9. CRC Handbook of Chemistry and Physics, 67th ed. (CRC Press, Boca Raton, 1986) Section D.
10. L. Peralta, Y. Berthier and J. Oudar, Surf. Sci. 55 (1976) 199.
11. A. Sanchez, J.J. De Miguel, E. Martinez and R. Miranda, Surf. Sci. 171 (1986) 157.
12. J. Toofan, G.R. Tinseth and P.R. Watson, J. Vac. Sci. Technol. A 12 (1994) 2246.
13. J.T. Roberts and C.M. Friend, J. Chem. Phys. 88 (1988) 7172.
14. M. Tikhov and E. Bauer, Surf. Sci. 232 (1990) 73.
15. J.-W. He, W.L. Shea, X. Jiang and D.W. Goodman, J. Vac. Sci. Technol. A 8 (1990) 2435.
16. A. Linsebigler, G. Lu and J.T. Yates, Surf. Sci. 294 (1993) 284.
17. J. Kolaczkiewicz, M. Hochół and S. Zuber, Surf. Sci. 247 (1990) 284.
18. 1/2 positions are given in Ref. [18] as 72.5 and 72.9 eV, respectively. Since we are unable to resolve the doublet in our spectra, we have opted for a weighted average, based on the theoretical 3/2 to 1/2 intensity ratio of 2:1, for the binding energy position.
19. G.P. Williams, Electron Binding Energies of the Elements, Version II, (National Synchrotron Light Source, Brookhaven National Laboratory, 1992).
20. J.A. Rodriguez, R.A. Campbell and D.W. Goodman, J. Phys. Chem. 95 (1991) 5716; R.A. Campbell, J.A. Rodriguez and D.W. Goodman, Surf. Sci. 256 (1991) 272.
21. J.A. Rodriguez, R.A. Campbell and D.W. Goodman, J. Phys. Chem. 95 (1991) 5716; R.A. Campbell, J.A. Rodriguez and D.W. Goodman, Surf. Sci. 256 (1991) 272.
22. W. Heegemann, K.H. Meister, E. Betchtold and K. Hayek, Surf. Sci. 256 (1975) 161; G.Q. Xu and J. Hrbek, Catal. Lett. 2 (1989) 35.
23. W. Heegemann, K.H. Meister, E. Betchtold and K. Hayek, Surf. Sci. 256 (1975) 161; G.Q. Xu and J. Hrbek, Catal. Lett. 2 (1989) 35.
24. A. Ohsawa, H. Yamamoto and H. Watanabe, J. Phys. Soc. Jpn. 37 (1974) 568.
25. M. Bronold, Y. Tomm and W. Jaegermann, Surf. Sci. 314 (1994) L931.
26. H. Binder, Z. Natürforsch. B 28 (5) (1973) 256.
27. J.C. Carver, G.K. Schweitzer and T.A. Carlson, J. Chem. Phys. 57 (1972) 980.
28. C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder, and G.E. Muilenberg, Handbook of X-ray Photoelectron Spectroscopy, (PerkinElmer, Eden Prairie, 1978) p. 104.
29. W. Jaegermann and D. Schmeisser, Surf. Sci. 165 (1986) 143.
30. G. Apai, R.C Baetzold, P.J. Jupiter, A.J. Jupiter, A.J. Viescas and I. Lindau, Surf. Sci. 134 (1983) 122.
31. W.F. Egelhoff, Surf. Sci. Rep. 6 (1987) 253.
32. M. Kuhn and J.A. Rodriguez, J. Catal. 154 (1995) 355. J.A. Rodriguez, M. Kuhn and J. Hrbek, Chem. Phys. Lett. 251 (1996) 13.
33. M. Kuhn and J.A. Rodriguez, J. Catal. 154 (1995) 355. J.A. Rodriguez, M. Kuhn and J. Hrbek, Chem. Phys. Lett. 251 (1996) 13.
34. R.P. Elliot, Constitution of Binary Alloys, First Supplement, (McGrawHill, New York, 1965) p 45.
35. F.A. Shunk, Constitution of Binary Alloys, Second Supplement, (McGraw-Hill, New York, 1969) p. 29.
36. J.A. Rodriguez and M. Kuhn, Chem. Phys. Lett. 240 (1995) 435.
37. Y. Wu, HS. Tao, E. Garfunkel, T.E. Madey and N. Shinn, Surf. Sci. 336 (1995) 123.
38. C.T. Campbell and D.W. Goodman, J. Phys. Chem. 92 (1988) 2569.
39. L.Q. Jiang, M.W. Ruckman and M. Strongin, Phys. Rev. B 39 (1989) 1564.
40. W.J. Wytenburg, R.M. Ormerod and R.M. Lambert, Surf. Sci. 282 (1993) 205.
41. S. Doniach and M. Šunjić, J. Phys. C 3 (1970) 285.
42. N.R. Gleason and D.R. Strongin, Surf. Sci. 295 (1993) 306.
43. G.E. McGuire, G.K. Schweitzer and T.A. Carlson, Inorg. Chem. 12 (1973) 2450.
44. Lange's Handbook of Chemistry, 13th Ed. (McGraw-Hill, New York, 1985) Table 9-1.
45. L.Z. Mezey and J. Giber, Jpn. J. Appl. Phys. 21 (1982) 1569.
46. C. Kittel, Introduction to Solid State Physics, 6th ed. (John Wiley, New York, 1986).
47. M. Kuhn and J.A. Rodriguez, Catal. Lett. 32 (1995) 345.
48. M. Kuhn and J.A. Rodriguez, to be published.
49. F. Zaera, E.B. Kollin and J.L. Gland, Surf. Sci. 184 (1987) 75.
50. C.M. Friend and J.T. Roberts, Acc. Chem, Res. 21 (1988) 394.
51. J.P. Fulmer, F. Zaera and W.T. Tysoe, J. Phys. Chem. 92 (1988) 4147.
52. J.A. Rodriguez, Surf. Sci. 278 (1992) 326.
53. J. Stöhr and D.A. Outka, Phys. Rev. B 36 (1987) 7891.
54. J.L. Gland, E.B. Kollin and F. Zaera, Langmuir 4 (1988) 118.
55. S. Harris and R.R. Chianelli, J. Catal, 98 (1986) 17.
56. D.S. Thakur, P. Grange and B. Delmon, J. Less Common Met. 64 (1979) 201; M. Karroua, J. Ladriere, H. Matralis, P. Grange and B. Delmon, J. Catal. 138 (1992) 640; J.P.R. Vissers, C.K. Groot, E.M. van Oers, V.H.J. De Beer and R. Prins, Bull. Soc. Chim. Belg, 93 (1984) 707.
57. D.S. Thakur, P. Grange and B. Delmon, J. Less Common Met. 64 (1979) 201; M. Karroua, J. Ladriere, H. Matralis, P. Grange and B. Delmon, J. Catal. 138 (1992) 640; J.P.R. Vissers, C.K. Groot, E.M. van Oers, V.H.J. De Beer and R. Prins, Bull. Soc. Chim. Belg, 93 (1984) 707.
58. D.S. Thakur, P. Grange and B. Delmon, J. Less Common Met. 64 (1979) 201; M. Karroua, J. Ladriere, H. Matralis, P. Grange and B. Delmon, J. Catal. 138 (1992) 640; J.P.R. Vissers, C.K. Groot, E.M. van Oers, V.H.J. De Beer and R. Prins, Bull. Soc. Chim. Belg, 93 (1984) 707.
59. J.A. Rodriguez and M. Kuhn, J. Vac. Sci. Technol., to be published.