Tetrakis(dimethylamino)ethylene (TDAE) as a potent electron source for Cr-mediated allylation of aldehydes and ketones

Synlett

Volumn , Issue 12, 1999, Pages 1930-1932

  Kuroboshi, Manabu ^a   Goto, Kentaro ^a   Mochizuki, Miisato ^a   Tanaka, Hideo ^a  

^a OKAYAMA UNIVERSITY   (Japan)

Author keywords

Allylations; Chromium; Cross coupling; Nickel; Reductions

Indexed keywords

ALDEHYDE; CHROMIUM; KETONE; NICKEL;

ARTICLE; CATALYST; CHEMICAL REACTION; ELECTRON TRANSPORT; REACTION ANALYSIS; REDUCTION;

EID: 0032713579     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2995     Document Type: Article

References (20)

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19. 3 were used as an electron source and Cr source, a catalytic amount of Zn was indispensable to promote the reaction. See 4b.
20. 3 was reduced to 0.2 and 0.1 mmol, yields of the desired compound 3 gradually decreased to 58 and 50%, respectively.