Ni/Cr/Al multi-metal redox-mediated alkenylation of aldehydes

Tetrahedron Letters

Volumn 40, Issue 14, 1999, Pages 2785-2788

  Kuroboshi, Manabu ^a   Tanaka, Muneaki ^a   Kishimoto, Suguru ^a   Goto, Kentaro ^a   Tanaka, Hideo ^a   Torii, Sigeru ^a  

^a OKAYAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALUMINUM; CARBONYL DERIVATIVE; CHROMIUM; NICKEL;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; MOISTURE; OXIDATION REDUCTION REACTION; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0033515871     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(99)00294-4     Document Type: Article

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33. A part of the silyl ether was hydrolyzed to afford the corresponding alcohol during purification by silica- gel column chromatography.
34. 2 (0.3 and 0.03 mmol, 3 mol% and 0.3 mol%, respectively) promoted the alkenylation reaction without significant change of the product affording 3a in 65% yield.
35. 3) were obtained in 47.% and 20% yield, respectively.